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SELECTIVE MOLECULAR OXYGEN TRANSPORT THROUGH A CELLULOSE ACETATE MEMBRANE CONTAINING AN ELECTRON-POOR IRON(II) PORPHYRIN COMPLEXES
Korean Journal of Chemical Engineering, October 1993, 10(4), 207-210(4), 10.1007/BF02705269
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Abstract
Molecular oxygen diffusion in the cellulose acetate membranes containing the 5,10,15,20-tetrakis
(pentafluorophenyl)-21H,23H-porphine iron(II) was studied. Both the permeability coefficient and the separation factor for oxygen in the membrane containing the iron(II) porphyrin complex were increased with decreasing the upstream gas pressure which correspond to a dual-mode oxygen transport. The effects of the axial ligands of the iron(II) porphyrin on oxygen permeation was also examined in the same cellulose acetate membrane. The fluoride and 2-methyl imidazole ligands coordination to the iron(II) porphyrin induce to increase the oxygen permeability coefficient and the value of ideal separation factor.
(pentafluorophenyl)-21H,23H-porphine iron(II) was studied. Both the permeability coefficient and the separation factor for oxygen in the membrane containing the iron(II) porphyrin complex were increased with decreasing the upstream gas pressure which correspond to a dual-mode oxygen transport. The effects of the axial ligands of the iron(II) porphyrin on oxygen permeation was also examined in the same cellulose acetate membrane. The fluoride and 2-methyl imidazole ligands coordination to the iron(II) porphyrin induce to increase the oxygen permeability coefficient and the value of ideal separation factor.
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Kemena LL, Noble RD, Kemp NJ, J. Membr. Sci., 15, 259 (1983)
Johnson BM, Baker RW, Matson SL, Smith KL, Roman IC, Tuttle ME, Lonsdale HK, J. Membr. Sci., 31, 31 (1987)
Kawakami H, Tsuda K, Nishide H, Tsuchida E, Macromolecules, 24, 3310 (1991)
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Cohen IA, Caugey WS, Biochemistry, 7, 636 (1968)
Chang CK, Powell D, Traylor TG, Croat. Chem. Acta, 49, 295 (1977)
Chen DG, DelGaudio J, LaMar GN, Balch AL, J. Am. Chem. Soc., 99, 5486 (1977)
Almog J, Baldwin JE, Huff J, J. Am. Chem. Soc., 97, 227 (1975)
Chang CK, J. Am. Chem. Soc., 99, 2819 (1977)
Collman JP, Accounts Chem. Res., 10, 265 (1977)
Collman JP, Gagne RR, Halbert TR, Marchen JC, Reed CA, J. Am. Chem. Soc., 95, 7868 (1973)
Nishide H, Ohyanagi M, Okada O, Macromolecules, 19, 494 (1986)
Nishide H, Ohyanagi M, Tsuchida E, Macromolecules, 20, 417 (1987)
Ohyanagi M, Nishide H, Suenaga K, Tsuchida E, Macromolecules, 21, 1950 (1988)
Nishide H, Ohyanagi M, Okada O, Tsuchida E, Macromolecules, 21, 910 (1980)
Tsuchida E, Nishide H, Ohyanagi M, Okada O, J. Phys. Chem., 92, 6461 (1988)
Yu BS, Goff HM, J. Am. Chem. Soc., 111, 6558 (1989)
Yu BS, Ph.D. Dissertation, University of Iowa, Iowa City (1989)
Perrin DD, Armarego WLF, Perrin DR, "The Purification of Laboratory Chemicals," 2nd ed., Pergamon Press, New York (1980)
Furniss BS, Hannaford AJ, Rogers V, Smith PWG, Tatchell AR, "Vogel's Textbook of Practical Organic Chemistry," 4th ed., The Chaucer Press, Ltd., Suffolk, p. 278 (1978)
Eaton SS, Eaton GR, J. Am. Chem. Soc., 97, 3660 (1975)
Woon TC, Shirazi A, Bruice TC, Inorg. Chem., 25, 3845 (1986)
Landrum JT, Atano K, Scheidt WR, Reed CA, J. Am. Chem. Soc., 102, 6729 (1980)
Brandrup J, Immergut EH, "Polymer Handbook," 3rd ed., John Wiley & Sons, New York, VI 435 (1989)
Kawakami H, Tsuda K, Nishide H, Tsuchida E, Macromolecules, 24, 3310 (1991)
