Articles & Issues
- Language
- English
- Conflict of Interest
- In relation to this article, we declare that there is no conflict of interest.
-
This is an Open-Access article distributed under the terms of the Creative Commons Attribution Non-Commercial License (http://creativecommons.org/licenses/bync/3.0) which permits
unrestricted non-commercial use, distribution, and reproduction in any medium, provided the original work is properly cited.
Copyright © KIChE. All rights reserved.
All issues
CATALYTIC BEHAVIOR OF YBa2Cu3O7-x IN THE PARTIAL OXIDATION OF METHANOL TO FORMALDEHYDE
Korean Journal of Chemical Engineering, January 1995, 12(1), 36-38(3), 10.1007/BF02697704
Download PDF
Abstract
The partial oxidation of methanol to formaldehyde was studied over YBa2Cu3O7-X catalyst in a flow reactor. The structural change of YBa2Cu3O7-X before and after the reaction was measured by means of XRD and iodometric titration method. The catalytic characteristics of YBa2Cu3O7-X for the partial oxidation of methanol to formaldehyde was due to copper ions. It was found that Cu+2 was responsible for the higher selectivity for formaldehyde.
Keywords
References
Hansen S, Otamiri J, Bovin JO, Anderson A, Nature, 334, 143 (1988)
Tabata K, Fukuda H, Kochiki S, Mizuno N, Misono M, Chem. Lett., 799 (1988)
Shimada H, Miyama S, Kuroda H, Chem. Lett., 1797 (1988)
Mizuno N, Yamato M, Misono M, J. Chem. Soc.-Chem. Commun., 13, 887 (1988)
Jiang AR, Peng Y, Zhon QW, Gao PY, Yuam HQ, Deng JF, Catal. Lett., 3, 235 (1989)
Halasz I, Appl. Catal., 47, L17 (1988)
Lee I, Ng KYS, Catal. Lett., 2, 403 (1989)
Sun YK, Lee WY, Catal. Lett., 17, 263 (1993)
Arakawa T, Adachi GY, Mater. Res. Bull., 24, 529 (1989)
Kim JB, Lee WY, Rhee HK, Lee HI, HWAHAK KONGHAK, 26(5), 535 (1988)
Tak YS, Lee GD, Lee WY, Lee HI, HWAHAK KONGHAK, 26(6), 641 (1988)
Kim YH, Rhee CK, Lee WY, Rhee HK, Lee HI, HWAHAK KONGHAK, 29(5), 596 (1991)
Kim JS, Choi JH, Lee WY, Korean J. Chem. Eng., 9(1), 45 (1992)
Cava RJ, Batlogg B, Chen CH, Rietman EA, Zahurak SM, Werder D, Phys. Rev., B, Condens. Matter, 36, 5719 (1987)
Chu CT, Dunn B, J. Am. Ceram. Soc., 70, C375 (1987)
Choi JS, Sun YK, Jung SJ, Lee WY, HWAHAK KONGHAK, 28(4), 444 (1990)
Harris DC, Hewston TA, J. Solid State Chem., 69, 182 (1987)
Nakamura T, Misono M, Yoneda Y, J. Catal., 83, 151 (1983)
Huang TJ, Chren CL, Appl. Catal., 40, 43 (1988)
Wachs IE, Madix RJ, J. Catal., 53, 43 (1978)
Jorgensen JD, Beno Ma, Hinks DG, Soderholm L, Volin KJ, Grace JD, Hitterman RL, Schuller IK, Segre CU, Zhang K, Kleefisch MS, Phys. Rev., B, Condens. Matter, 36, 3608 (1987)
Dharwadkar SR, Jakkal VS, Jakhami JV, Gopalakrishnan IK, Iyer RM, Solid State Commun., 64, 1429 (1987)
Tabata K, Fukuda H, Kochiki S, Mizuno N, Misono M, Chem. Lett., 799 (1988)
Shimada H, Miyama S, Kuroda H, Chem. Lett., 1797 (1988)
Mizuno N, Yamato M, Misono M, J. Chem. Soc.-Chem. Commun., 13, 887 (1988)
Jiang AR, Peng Y, Zhon QW, Gao PY, Yuam HQ, Deng JF, Catal. Lett., 3, 235 (1989)
Halasz I, Appl. Catal., 47, L17 (1988)
Lee I, Ng KYS, Catal. Lett., 2, 403 (1989)
Sun YK, Lee WY, Catal. Lett., 17, 263 (1993)
Arakawa T, Adachi GY, Mater. Res. Bull., 24, 529 (1989)
Kim JB, Lee WY, Rhee HK, Lee HI, HWAHAK KONGHAK, 26(5), 535 (1988)
Tak YS, Lee GD, Lee WY, Lee HI, HWAHAK KONGHAK, 26(6), 641 (1988)
Kim YH, Rhee CK, Lee WY, Rhee HK, Lee HI, HWAHAK KONGHAK, 29(5), 596 (1991)
Kim JS, Choi JH, Lee WY, Korean J. Chem. Eng., 9(1), 45 (1992)
Cava RJ, Batlogg B, Chen CH, Rietman EA, Zahurak SM, Werder D, Phys. Rev., B, Condens. Matter, 36, 5719 (1987)
Chu CT, Dunn B, J. Am. Ceram. Soc., 70, C375 (1987)
Choi JS, Sun YK, Jung SJ, Lee WY, HWAHAK KONGHAK, 28(4), 444 (1990)
Harris DC, Hewston TA, J. Solid State Chem., 69, 182 (1987)
Nakamura T, Misono M, Yoneda Y, J. Catal., 83, 151 (1983)
Huang TJ, Chren CL, Appl. Catal., 40, 43 (1988)
Wachs IE, Madix RJ, J. Catal., 53, 43 (1978)
Jorgensen JD, Beno Ma, Hinks DG, Soderholm L, Volin KJ, Grace JD, Hitterman RL, Schuller IK, Segre CU, Zhang K, Kleefisch MS, Phys. Rev., B, Condens. Matter, 36, 3608 (1987)
Dharwadkar SR, Jakkal VS, Jakhami JV, Gopalakrishnan IK, Iyer RM, Solid State Commun., 64, 1429 (1987)
