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EXCESS MOLAR VOLUMES AT THE 308.15 K FOR CONSTITUENT BINARIES OF n-DECANE, n-DODECANE, 1-DECANOL AND 1-DODECANOL
Korean Journal of Chemical Engineering, April 1995, 12(2), 152-155(4), 10.1007/BF02705639
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Abstract
Excess molar volumes(VmE) of constituent binary mixtures of n-decane, n-dodecane, 1-decanol and 1-dodecanol which are the products of liquid phase oxidation of n-paraffins, have been measured experimentally as a function of composition x from density measurements at 308.15K. The excess molar volumes of n-decane-n-dodecane system have negative deviation from the ideality while that of n-dodecance-1-decanol system have positive deviation. In the other system, excess molar volume exhibits inversion in sign. Experimental data were successfully correlated with Redlich-Kister polynomial.
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