Articles & Issues
- Language
- English
- Conflict of Interest
- In relation to this article, we declare that there is no conflict of interest.
-
This is an Open-Access article distributed under the terms of the Creative Commons Attribution Non-Commercial License (http://creativecommons.org/licenses/bync/3.0) which permits
unrestricted non-commercial use, distribution, and reproduction in any medium, provided the original work is properly cited.
Copyright © KIChE. All rights reserved.
All issues
A REACTION KINETIC STUDY ON THE GIF-TYPE BIOMIMETIC OXIDATION OF CYCLOHEXANE
Korean Journal of Chemical Engineering, April 1995, 12(2), 188-192(5), 10.1007/BF02705645
Download PDF
Abstract
Kinetics of the oxidation of cyclohexane under Gif type conditions have been studied. A kinetic model is proposed, which is in agreement with the experimental results obtained. The rate equation showed the first order with respect to cyclohexane. A temperature-dependence study of the reaction rate affords an activation energy of 14.3 kcal/mol.
Keywords
References
About-Jaudet E, Barton DHR, Csuhai E, Ozbalik N, Tetrahedron Lett., 31, 1657 (1990)
Amatsu H, Miyamoto TK, Sasaki Y, Bull. Chem. Soc. Jpn., 31, 3193 (1988)
Archakov AI, Bachmanopva GI, "Cytochrome P-450 and Active Oxygen," Taylor & Francis: London (1990)
Balch AL, Lamar GN, Latos-Grazynski L, Renner MW, Thanabal V, J. Am. Chem. Soc., 107, 3003 (1985)
Barton DHR, Biviere SD, Chavasiri W, Csuhai E, Doller D, J. Am. Chem. Soc., 114, 2147 (1992)
Barton DHR, Gastiger MJ, Motherwell WB, J. Chem. Soc.-Chem. Commun., 41, 731 (1983)
Barton DHR, Lee KW, Mehr W, Ozbalik N, Zhang L, Tetrahedron, 46, 3753 (1990)
Chin DH, Balch AL, LaMar GM, J. Am. Chem. Soc., 102, 1446 (1980)
Collman JP, Brauman JI, Meunier B, Hayashi T, Kodadek T, Raybuck SA, J. Am. Chem. Soc., 107, 2000 (1985)
Dicken CM, Woon TC, Bruice TC, J. Am. Chem. Soc., 108, 1636 (1986)
Groves JT, Nemo TE, Meyers RS, J. Am. Chem. Soc., 101, 1032 (1979)
Lee KY, Kim SB, Kim YJ, Hong SI, Bull. Korean Chem. Soc., 15, 424 (1994)
Mansuy D, Bartoli JF, Momenteau M, Tetrahedron Lett., 23, 2781 (1982)
Nolte RJM, Razenberg JASJ, Schurman R, J. Am. Chem. Soc., 108, 2751 (1986)
Ojima R, Kobayashi N, Osa T, Bull. Chem. Soc. Jpn., 63, 1374 (1990)
Sugimoto H, Tung HC, Saywer DT, J. Am. Chem. Soc., 110, 2465 (1988)
Traylor TG, Miksatal AR, J. Am. Chem. Soc., 109, 2770 (1981)
Traylor TG, Xu F, J. Am. Chem. Soc., 10, 1953 (1988)
Amatsu H, Miyamoto TK, Sasaki Y, Bull. Chem. Soc. Jpn., 31, 3193 (1988)
Archakov AI, Bachmanopva GI, "Cytochrome P-450 and Active Oxygen," Taylor & Francis: London (1990)
Balch AL, Lamar GN, Latos-Grazynski L, Renner MW, Thanabal V, J. Am. Chem. Soc., 107, 3003 (1985)
Barton DHR, Biviere SD, Chavasiri W, Csuhai E, Doller D, J. Am. Chem. Soc., 114, 2147 (1992)
Barton DHR, Gastiger MJ, Motherwell WB, J. Chem. Soc.-Chem. Commun., 41, 731 (1983)
Barton DHR, Lee KW, Mehr W, Ozbalik N, Zhang L, Tetrahedron, 46, 3753 (1990)
Chin DH, Balch AL, LaMar GM, J. Am. Chem. Soc., 102, 1446 (1980)
Collman JP, Brauman JI, Meunier B, Hayashi T, Kodadek T, Raybuck SA, J. Am. Chem. Soc., 107, 2000 (1985)
Dicken CM, Woon TC, Bruice TC, J. Am. Chem. Soc., 108, 1636 (1986)
Groves JT, Nemo TE, Meyers RS, J. Am. Chem. Soc., 101, 1032 (1979)
Lee KY, Kim SB, Kim YJ, Hong SI, Bull. Korean Chem. Soc., 15, 424 (1994)
Mansuy D, Bartoli JF, Momenteau M, Tetrahedron Lett., 23, 2781 (1982)
Nolte RJM, Razenberg JASJ, Schurman R, J. Am. Chem. Soc., 108, 2751 (1986)
Ojima R, Kobayashi N, Osa T, Bull. Chem. Soc. Jpn., 63, 1374 (1990)
Sugimoto H, Tung HC, Saywer DT, J. Am. Chem. Soc., 110, 2465 (1988)
Traylor TG, Miksatal AR, J. Am. Chem. Soc., 109, 2770 (1981)
Traylor TG, Xu F, J. Am. Chem. Soc., 10, 1953 (1988)
