Articles & Issues
- Language
- English
- Conflict of Interest
- In relation to this article, we declare that there is no conflict of interest.
-
This is an Open-Access article distributed under the terms of the Creative Commons Attribution Non-Commercial License (http://creativecommons.org/licenses/bync/3.0) which permits
unrestricted non-commercial use, distribution, and reproduction in any medium, provided the original work is properly cited.
Copyright © KIChE. All rights reserved.
All issues
SOLVATION PRESSURE OF SIMPLE FLUIDS IN SPHERICAL PORES
Korean Journal of Chemical Engineering, September 1995, 12(4), 491-493(3), 10.1007/BF02705818
Download PDF
Abstract
Computer simulations via the grand canonical ensemble Monte Carlo method have been carried out to investigate the equilibrium properties of simple fluids distributed between the external bulk phase and the pore phase. Solvation pressures and pore density profiles are computed for the system of hard-sphere fluids inside a spherical hard-wall model pore. For dilute concentrations, the resulting solvation pressures are approximately equal to those in the bulk phase. However, at a moderately dense concentration of nB*=0.4, a weakly oscillatory behavior of the solvation pressure starts to emerge. The apparent maximum and minmum peaks are exhibited in the case of nB*=0.6 due to the local density inhomogeneities in the pore phase.
References
Adams DJ, Mol. Phys., 28, 1241 (1974)
Adams DJ, Mol. Phys., 29, 307 (1975)
Balbuena PB, Berry D, Gubbins KE, J. Phys. Chem., 7, 937 (1993)
Deen WM, AIChE J., 33, 1409 (1987)
Israelachvili JN, Adv. Colloid Interface Sci., 16, 31 (1982)
Israelachvili JN, Adams GE, J. Chem. Soc.-Faraday Trans., 74, 975 (1978)
Kim SC, Suh JK, Suh SH, Mol. Phys., 79, 1369 (1993)
Marcelja S, "Liquids at Interfaces," Charvolin, J., Joanny, J.F. and Zinn-Justin, J. eds., North-Holland, Amsterdam (1990)
MacElroy JMD, Suh SH, AIChE Symp. Ser., 82, 133 (1986)
MacElroy JMD, Suh SH, Mol. Phys., 60, 475 (1987)
MacElroy JMD, Suh SH, Mol. Simul., 2, 313 (1989)
Magda J, Tirrell JM, Davis HT, J. Chem. Phys., 83, 1888 (1985)
Nicholson D, Parsonage NG, "Computer Simulation and the Statistical Mechanics of Adsorption," Academic Press, New York (1982)
Reed TM, Gubbins KE, "Applied Statistical Mechanics," McGraw-Hill, New York (1973)
Snook IK, vanMegen W, J. Chem. Phys., 72, 2907 (1980)
Suh SH, MacElroy JMD, Mol. Phys., 58, 445 (1986)
Suh SH, Kim JS, Park CY, HWAHAK KONGHAK, 29(6), 742 (1991)
Suh SH, Park HK, Korean J. Chem. Eng., 11(3), 198 (1994)
Tabor D, Winterton RHS, Proc. Roy. Soc. A, 312, 435 (1969)
Adams DJ, Mol. Phys., 29, 307 (1975)
Balbuena PB, Berry D, Gubbins KE, J. Phys. Chem., 7, 937 (1993)
Deen WM, AIChE J., 33, 1409 (1987)
Israelachvili JN, Adv. Colloid Interface Sci., 16, 31 (1982)
Israelachvili JN, Adams GE, J. Chem. Soc.-Faraday Trans., 74, 975 (1978)
Kim SC, Suh JK, Suh SH, Mol. Phys., 79, 1369 (1993)
Marcelja S, "Liquids at Interfaces," Charvolin, J., Joanny, J.F. and Zinn-Justin, J. eds., North-Holland, Amsterdam (1990)
MacElroy JMD, Suh SH, AIChE Symp. Ser., 82, 133 (1986)
MacElroy JMD, Suh SH, Mol. Phys., 60, 475 (1987)
MacElroy JMD, Suh SH, Mol. Simul., 2, 313 (1989)
Magda J, Tirrell JM, Davis HT, J. Chem. Phys., 83, 1888 (1985)
Nicholson D, Parsonage NG, "Computer Simulation and the Statistical Mechanics of Adsorption," Academic Press, New York (1982)
Reed TM, Gubbins KE, "Applied Statistical Mechanics," McGraw-Hill, New York (1973)
Snook IK, vanMegen W, J. Chem. Phys., 72, 2907 (1980)
Suh SH, MacElroy JMD, Mol. Phys., 58, 445 (1986)
Suh SH, Kim JS, Park CY, HWAHAK KONGHAK, 29(6), 742 (1991)
Suh SH, Park HK, Korean J. Chem. Eng., 11(3), 198 (1994)
Tabor D, Winterton RHS, Proc. Roy. Soc. A, 312, 435 (1969)
