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CORRELATION OF THE VAPOR-LIQUID EQUILIBRIA OF CFC, HCFC AND FC MIXTURES : CRITICAL EVALUATION OF MIXING RULES
Korean Journal of Chemical Engineering, November 1995, 12(5), 535-539(5), 10.1007/BF02705856
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Abstract
The vapor-liquid equilibrium data of the binary CFC, HCFC, and FC mixtures were correlated with the Soave-Redlich-Kwong equation of state incorporated with some types of mixing rules; the conventional one fluid, Panagiotopoulos-Reid and modified Huron-Vidal second order mixing rules. The Panagiotopoulos-Reid mixing rule showed the superiority to the other models in predicting the VLE of freon mixtures with low errors. The modified Huron-Vidal second order model showed good convergence ability, which was due to its robustness to parameter variation.
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References
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Fransson E, Vamling L, Chem. Eng. Sci., 48, 1753 (1993)
Huron MJ, Vidal J, Fluid Phase Equilib., 3, 255 (1979)
Kubota H, Matumoto T, J. Chem. Eng. Jpn., 26, 320 (1993)
Kubota H, Nojiri N, Tanaka Y, Makita T, Noguchi M, J. Chem. Eng. Jpn., 23, 638 (1990)
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Michelson ML, Fluid Phase Equilib., 60, 213 (1990)
Mollerup J, Fredenslund A, J. Chem. Eng. Data, 21, 299 (1976)
Panagiotopoulos AZ, Reid RC, "New Mixing Rule for Cubic Equation of State for Highly Polar, Asymmetric Systems," ACS Symp. Ser., No. 300, 571 (1986)
Piacentini A, Stein FP, Chem. Eng. Prog., 63, 28 (1967)
Platzer B, Maurer G, Fluid Phase Equilib., 84, 79 (1993)
Prausnitz JM, Lichenthaler RN, deAzevedo EG, "Molecular Thermodynamics of Fluid-Phase Equilibria," 2nd ed, Prentice-Hall, Englewood, Cliffs, NJ (1986)
Proust PC, Stein FP, J. Chem. Eng. Data, 24, 341 (1979)
Renon H, Prausnitz JM, AIChE J., 14, 135 (1968)
Roth H, Peters-Gerth P, Lucas K, Fluid Phase Equilib., 73, 147 (1992)
Soave G, Chem. Eng. Sci., 27, 1197 (1972)
Stein FP, Proust PC, J. Chem. Eng. Data, 16, 389 (1971)
Yoon JH, Chun MK, Hong WH, Lee H, Ind. Eng. Chem. Res., 32, 2882 (1993)
