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SOLVENT ACTIVITY COEFFICIENTS AT INFINITE DILUTION IN POLYSTYRENE-HYDROCARBON SYSTEMS FROM INVERSE GAS CHROMATOGRAPHY
Korean Journal of Chemical Engineering, March 1996, 13(2), 129-135(7), 10.1007/BF02705899
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Abstract
Inverse gas chromatography was used to measure activity coefficients of solvents at infinite dilution over a temperature range from 373.15K to 423.15K for monodisperse polystyrene-hydrocarbon systems. Polystyrene has average molecular weight 2.89×105. Solvents include six aliphatic hydrocarbons such as cyclohexane, methylethyl-ketone, n-hexane, carbon tetrachloride, acetonitrile and acetone and three aromatic ones as benzene, toluene and p-xylene. The measured data of activity coefficients of solvents were predicted by UNIFAC-FV model. We, also, pres-ented a modified UNIFAC-FV model by empirically assigning to it a temperature-dependent C parameter in the free volume contribution of the model. Fitted results demonstrated that the modification of the model fitted the experiments better than the original one.
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References
Beret S, Prausnitz JM, AIChE J., 21, 1123 (1975)
Bonner DC, Praustniz JM, AIChE J., 19, 943 (1973)
Chen F, Fredenslund A, Rasmussen P, Ind. Eng. Chem. Res., 29, 875 (1990)
Chen CC, Fluid Phase Equilib., 83, 301 (1993)
Chang YH, Bonner DC, J. Appl. Polym. Sci., 19, 2439 (1975)
Choi JS, Tochigi K, Kojima K, Fluid Phase Equilib., 111(1), 143 (1995)
Conder JR, Purnell JH, Trans. Faraday Soc., 64, 1505 (1968)
Conder JR, Purnell JH, Trans. Faraday Soc., 64, 3100 (1968)
Conder JR, Purnell JH, Trans. Faraday Soc., 65, 824 (1969)
Conder JR, Purnell JH, Trans. Faraday Soc., 65, 839 (1969)
Elbro HS, Fredenslund A, Rasmussen P, Macromolecules, 23, 4707 (1990)
Elbro HS, Frendenslund A, Rasmunssen P, Ind. Eng. Chem. Res., 30, 2576 (1991)
Fredenslund A, Jones RL, Prausnitz JM, AIChE J., 21, 1086 (1975)
Gmeling J, Rasmussen P, Fredenslund A, Ind. Eng. Chem. Process Des. Dev., 21, 118 (1982)
Hao W, Elbro HS, Alessi P, DECHEMA Chemistry Data Series, DECHEMA, Frankfurt, Vol. XIV, Part 2-3 (1992)
Holten-Anderson J, Rasmussen P, Fredenslund A, Ind. Eng. Chem. Res., 26, 1382 (1987)
Iwai Y, Ohzono M, Arai Y, Chem. Eng. Commun., 34, 225 (1985)
Iwai Y, Arai Y, J. Chem. Eng. Jpn., 22, 155 (1989)
Kontogeorgis GM, Fredenslund A, Tassios DP, Ind. Eng. Chem. Res., 32, 362 (1993)
Merk W, Lichtenthaler RN, Prausnitz JM, J. Phys. Chem., 84, 1694 (1980)
Newman RD, Prausnitz JM, J. Phys. Chem., 76, 1492 (1972)
Oishi T, Prausnitz JM, Ind. Eng. Chem. Process Des. Dev., 17, 333 (1978)
Patterson O, Macromolecules, 2, 672 (1969)
Reid RC, Prausnitz JM, Poling BE, "The Properties of Gases and Liquids," McGraw-Hill, 4th Ed. (1987)
Roth M, Novak J, Macromolecules, 19, 364 (1986)
Schuster RH, Grater H, Cantow HJ, Macromolecules, 17, 619 (1984)
Smidsord O, Guillet JE, Macromolecules, 2, 272 (1969)
Tsonopoulos C, AIChE J., 20, 263 (1974)
Tsonopoulos C, AIChE J., 21, 827 (1975)
Tsonopoulos C, AIChE J., 24, 1112 (1978)
Bonner DC, Praustniz JM, AIChE J., 19, 943 (1973)
Chen F, Fredenslund A, Rasmussen P, Ind. Eng. Chem. Res., 29, 875 (1990)
Chen CC, Fluid Phase Equilib., 83, 301 (1993)
Chang YH, Bonner DC, J. Appl. Polym. Sci., 19, 2439 (1975)
Choi JS, Tochigi K, Kojima K, Fluid Phase Equilib., 111(1), 143 (1995)
Conder JR, Purnell JH, Trans. Faraday Soc., 64, 1505 (1968)
Conder JR, Purnell JH, Trans. Faraday Soc., 64, 3100 (1968)
Conder JR, Purnell JH, Trans. Faraday Soc., 65, 824 (1969)
Conder JR, Purnell JH, Trans. Faraday Soc., 65, 839 (1969)
Elbro HS, Fredenslund A, Rasmussen P, Macromolecules, 23, 4707 (1990)
Elbro HS, Frendenslund A, Rasmunssen P, Ind. Eng. Chem. Res., 30, 2576 (1991)
Fredenslund A, Jones RL, Prausnitz JM, AIChE J., 21, 1086 (1975)
Gmeling J, Rasmussen P, Fredenslund A, Ind. Eng. Chem. Process Des. Dev., 21, 118 (1982)
Hao W, Elbro HS, Alessi P, DECHEMA Chemistry Data Series, DECHEMA, Frankfurt, Vol. XIV, Part 2-3 (1992)
Holten-Anderson J, Rasmussen P, Fredenslund A, Ind. Eng. Chem. Res., 26, 1382 (1987)
Iwai Y, Ohzono M, Arai Y, Chem. Eng. Commun., 34, 225 (1985)
Iwai Y, Arai Y, J. Chem. Eng. Jpn., 22, 155 (1989)
Kontogeorgis GM, Fredenslund A, Tassios DP, Ind. Eng. Chem. Res., 32, 362 (1993)
Merk W, Lichtenthaler RN, Prausnitz JM, J. Phys. Chem., 84, 1694 (1980)
Newman RD, Prausnitz JM, J. Phys. Chem., 76, 1492 (1972)
Oishi T, Prausnitz JM, Ind. Eng. Chem. Process Des. Dev., 17, 333 (1978)
Patterson O, Macromolecules, 2, 672 (1969)
Reid RC, Prausnitz JM, Poling BE, "The Properties of Gases and Liquids," McGraw-Hill, 4th Ed. (1987)
Roth M, Novak J, Macromolecules, 19, 364 (1986)
Schuster RH, Grater H, Cantow HJ, Macromolecules, 17, 619 (1984)
Smidsord O, Guillet JE, Macromolecules, 2, 272 (1969)
Tsonopoulos C, AIChE J., 20, 263 (1974)
Tsonopoulos C, AIChE J., 21, 827 (1975)
Tsonopoulos C, AIChE J., 24, 1112 (1978)
