Articles & Issues
- Language
- English
- Conflict of Interest
- In relation to this article, we declare that there is no conflict of interest.
- This is an Open-Access article distributed under the terms of the Creative Commons Attribution Non-Commercial License (http://creativecommons.org/licenses/bync/3.0) which permits unrestricted non-commercial use, distribution, and reproduction in any medium, provided the original work is properly cited.
Copyright © KIChE. All rights reserved.
All issues
DEHYDROGENATION OF CYCLOHEXANOL TO CYCLOHEXANONE OVER Cu/SiO2 CATALYSTS:DISPERSION AND CATALYTIC ACTIVITY
Korean Journal of Chemical Engineering, July 1996, 13(4), 412-414(3), 10.1007/BF02705971
Download PDF
Abstract
Copper catalysts supported on silica (Cu/SiO2) were prepared by three different methods; incipient wetness, precipitation, and ion exchange. Catalytic properties in the dehyd- rogenation of cyclohexanol over these catalysts were examined. Copper surface area increased in the order of incipient wetness<precipitation<ion-exchange method for the catalysts with the same loading of copper. Conversion was mainly dependent on the copper surface area regardless of preparation methods, and selectivity to cyclohexanone was very high for all Cu/SiO2 catalysts.
Keywords
References
Chang HF, Saleque MA, J. Mol. Catal., 88, 223 (1994)
Chang HF, Saleque MA, Appl. Catal. A: Gen., 103, 233 (1993)
Chinchen GC, Hay CM, Vandervell HD, Waugh KC, J. Catal., 103, 79 (1987)
Cubberley AH, Mueller MB, J. Am. Chem. Soc., June, 1535 (1947)
Jeon GS, Chung JS, Appl. Catal. A: Gen., 115(1), 29 (1994)
Kobayashi H, Takezawa N, Minochi C, Takahashi K, Chem. Lett., 1197 (1980)
Minochi C, Kobayashi H, Takezawa N, Chem. Lett., 507 (1979)
Monti DM, Wainwright MS, Trimm DL, Cant NW, Ind. Eng. Chem. Prod. Res. Dev., 24, 397 (1985)
Sivaraj C, Reddy BM, Rao PK, Appl. Catal., 45, L11 (1988)
Sodesawa T, React. Kinet. Catal. Lett., 24, 259 (1984)
Sodesawa T, Nagacho M, Onodera A, Nozaki F, J. Catal., 102, 460 (1986)
Chang HF, Saleque MA, Appl. Catal. A: Gen., 103, 233 (1993)
Chinchen GC, Hay CM, Vandervell HD, Waugh KC, J. Catal., 103, 79 (1987)
Cubberley AH, Mueller MB, J. Am. Chem. Soc., June, 1535 (1947)
Jeon GS, Chung JS, Appl. Catal. A: Gen., 115(1), 29 (1994)
Kobayashi H, Takezawa N, Minochi C, Takahashi K, Chem. Lett., 1197 (1980)
Minochi C, Kobayashi H, Takezawa N, Chem. Lett., 507 (1979)
Monti DM, Wainwright MS, Trimm DL, Cant NW, Ind. Eng. Chem. Prod. Res. Dev., 24, 397 (1985)
Sivaraj C, Reddy BM, Rao PK, Appl. Catal., 45, L11 (1988)
Sodesawa T, React. Kinet. Catal. Lett., 24, 259 (1984)
Sodesawa T, Nagacho M, Onodera A, Nozaki F, J. Catal., 102, 460 (1986)