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EFFECT OF ACTIVE SITE DISTRIBUTION ON LIQUID-PHASE OLEFIN HYDROGENATION OVER POLYMER-SUPPORTED PALLADIUM COMPLEX

Jo YD Ahn JH Ihm SK

Korean Journal of Chemical Engineering, March 1997, 14(2), 125-128(4), 10.1007/BF02706071

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Abstract

Chloromethylated polystyrene beads with different distributions have been prepared and phosphinated. PdCl₂ was supported on the phosphinated supports to give polymer-supported Pd complex catalysts with different active site distributions. The effect of active site distribution on catalytic activity was investigated in the hydrogenation of olefins.

Keywords

Polymer-supported Catalyst Active Site Distribution Hydrogenation PdCl₂ Cyclohexene

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