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CHARACTERIZATION AND CATALYTIC PROPERTIES OF TITANIUM SILICALITE-1 CATALYST
Korean Journal of Chemical Engineering, March 1998, 15(2), 182-191(10), 10.1007/BF02707071
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Abstract
Titanium silicalite 1 (TS-1) catalyst was prepared by three different hydrothermal synthesis methods. XRD, elemental analysis, SEM, IR, 29Si MAS NMR, UV-vis DRS, physical adsorption of nitrogen, and EXAFS analysis were then performed to evaluate its physical properties. For a test of catalytic activity, liquid phase 2-butanol oxidation and 1-hexene epoxidation using hydrogen peroxide as an oxidant were conducted. The crystal size of the TS-1 catalyst was shown to have a considerable effect on the 1-hexene epoxidation, and smaller crystals resulted in higher activity.
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References
Babonneau F, Daeuff S, Leaustic A, Sanchez C, Cartier C, Verdaguer M, Inorg. Chem., 27, 3166 (1988)
Behrens P, Felsche J, Vetter S, Schults-Ekloff G, Jaeger NI, Nieman WJ, J. Chem. Soc.-Chem. Commun., 678 (1991)
Blasco T, Camblor MA, Corma A, Perez-Pariente J, J. Am. Chem. Soc., 115, 11806 (1993)
Boccuti MR, Rao KM, Zecchina A, Leofanti G, Petrini G, "Spectroscopic Characterization of Silicalite and Titanium Silicalite," Stud. Surf. Sci. Catal., 48, Morterra, C. et. al., eds., Elsevier, Amsterdam, 133 (1989)
Bordiga S, Boscherini F, Coluccia S, Genoni F, Lamberti C, Leofanti G, Marchese L, Petrini G, Vlaic G, Zecchina A, Catal. Lett., 26(1-2), 195 (1994)
Clark RJH, "Chemistry of Titanium and Vanadium," El-sevier, Amsterdam, 272 (1968)
Clerici MG, Ingallina P, J. Catal., 140, 71 (1993)
Esposito A, Neri C, Buonomo F, "Process for Oxidizing Alcohols to Aldehydes and/or Ketones," U.S. Patent, 4,480,135 (1984)
Frenkel AI, Stern EA, Voronel A, Qian M, Newville M, Phys. Rev., B, Condens. Matter, 48, 12449 (1993)
Greegor R, Lytle FW, Sandstrom DR, Wong J, Schultz P, J. Non-Cryst. Solids, 55, 27 (1983)
Huybrechts DRC, Buskens PL, Jacobs PA, J. Mol. Catal., 71, 129 (1992)
Huybrechts DRC, De Bruycker L, Jacobs PA, Nature, 345, 240 (1990)
Huybrechts DRC, Vaesen I, Li HX, Jacobs PA, Catal. Lett., 8, 237 (1991)
Kim GJ, Cho BR, HWAHAK KONGHAK, 31(6), 658 (1993)
Kim JK, Ko YS, Kim TJ, Ahn WS, HWAHAK KONGHAK, 33(4), 511 (1995)
Kim JK, Ko YS, Ann WS, J. Korean Ind. Eng. Chem., 6(4), 626 (1995)
Kraushaar B, van Hooff JHC, Catal. Lett., 1, 81 (1988)
Kraushaar B, van Hooff JHC, Catal. Lett., 2, 43 (1989)
Lee JH, Jung KT, Shul YG, HWAHAK KONGHAK, 34(6), 765 (1996)
Notari B, Catal. Today, 18, 163 (1993)
Padovan M, Genoni F, Leofanti G, Petrini G, Trezza G, Zecchina A, "Study on Titanium Silicate Synthesis," Stud. Surf. Sci. Catal., 63, Poncelet, G., Jacobs, P.A., Grange, P. and Delmon, B., Eds., Elsevier, Amsterdam, 431 (1991)
Reddy JS, Kumar R, Ratnasamy P, Appl. Catal., 58, L1 (1990)
Reddy KM, Kaliaguine S, Sayari A, Ramaswamy AV, Reddy VS, Bonneviot L, Catal. Lett., 23(1-2), 175 (1994)
Schultz E, Ferrini C, Prins R, Catal. Lett., 14, 221 (1992)
Tangaraj A, Kumar R, Mirajkar SP, Ratnasamy P, J. Catal., 130, 1 (1991)
Taramasso M, Perego G, Notari B, "Preparation of Porous Crystalline Synthetic Materials Comprised of Silicon and Titanium Oxides," U.S. Patent, 4,410,501 (1983)
Tatsumi T, Nakamura M, Negishi S, Tominaga H, J. Chem. Soc.-Chem. Commun., 476 (1990)
Trong OD, Bonneviot L, Bittar A, Sayari A, Kaliaguine S, J. Mol. Catal., 74, 233 (1992)
Tuel A, Diab J, Gelin P, Dufaux M, Dutel JF, Taarit YB, J. Mol. Catal., 63, 95 (1990)
vander Pol AJHP, Verduyn AJ, Van Hooff JHC, Appl. Catal., 92, 113 (1992)
vander Pol AJHP, van Hooff JHC, Appl. Catal. A: Gen., 106, 97 (1993)
Yarker CA, Johnson PAV, Wright AC, Wong J, Greegor RB, Lytle FW, Sinclair RN, J. Non-Cryst. Solids, 79, 117 (1986)
Zecchina A, Spoto G, Bordiga S, Ferrero A, Petrini G, Leofanti G, Padovan M, "Framework and Extraframework Ti in Titanium-Silicalite: Investigation by Means of Physical Methods," Zeolite Chemistry and Catalysis, Jacobs, P.A., Jaeger, N.I., Kubelkova, L. and Wichterlova, B., eds., Elsevier, Amsterdam, 251 (1991)
Behrens P, Felsche J, Vetter S, Schults-Ekloff G, Jaeger NI, Nieman WJ, J. Chem. Soc.-Chem. Commun., 678 (1991)
Blasco T, Camblor MA, Corma A, Perez-Pariente J, J. Am. Chem. Soc., 115, 11806 (1993)
Boccuti MR, Rao KM, Zecchina A, Leofanti G, Petrini G, "Spectroscopic Characterization of Silicalite and Titanium Silicalite," Stud. Surf. Sci. Catal., 48, Morterra, C. et. al., eds., Elsevier, Amsterdam, 133 (1989)
Bordiga S, Boscherini F, Coluccia S, Genoni F, Lamberti C, Leofanti G, Marchese L, Petrini G, Vlaic G, Zecchina A, Catal. Lett., 26(1-2), 195 (1994)
Clark RJH, "Chemistry of Titanium and Vanadium," El-sevier, Amsterdam, 272 (1968)
Clerici MG, Ingallina P, J. Catal., 140, 71 (1993)
Esposito A, Neri C, Buonomo F, "Process for Oxidizing Alcohols to Aldehydes and/or Ketones," U.S. Patent, 4,480,135 (1984)
Frenkel AI, Stern EA, Voronel A, Qian M, Newville M, Phys. Rev., B, Condens. Matter, 48, 12449 (1993)
Greegor R, Lytle FW, Sandstrom DR, Wong J, Schultz P, J. Non-Cryst. Solids, 55, 27 (1983)
Huybrechts DRC, Buskens PL, Jacobs PA, J. Mol. Catal., 71, 129 (1992)
Huybrechts DRC, De Bruycker L, Jacobs PA, Nature, 345, 240 (1990)
Huybrechts DRC, Vaesen I, Li HX, Jacobs PA, Catal. Lett., 8, 237 (1991)
Kim GJ, Cho BR, HWAHAK KONGHAK, 31(6), 658 (1993)
Kim JK, Ko YS, Kim TJ, Ahn WS, HWAHAK KONGHAK, 33(4), 511 (1995)
Kim JK, Ko YS, Ann WS, J. Korean Ind. Eng. Chem., 6(4), 626 (1995)
Kraushaar B, van Hooff JHC, Catal. Lett., 1, 81 (1988)
Kraushaar B, van Hooff JHC, Catal. Lett., 2, 43 (1989)
Lee JH, Jung KT, Shul YG, HWAHAK KONGHAK, 34(6), 765 (1996)
Notari B, Catal. Today, 18, 163 (1993)
Padovan M, Genoni F, Leofanti G, Petrini G, Trezza G, Zecchina A, "Study on Titanium Silicate Synthesis," Stud. Surf. Sci. Catal., 63, Poncelet, G., Jacobs, P.A., Grange, P. and Delmon, B., Eds., Elsevier, Amsterdam, 431 (1991)
Reddy JS, Kumar R, Ratnasamy P, Appl. Catal., 58, L1 (1990)
Reddy KM, Kaliaguine S, Sayari A, Ramaswamy AV, Reddy VS, Bonneviot L, Catal. Lett., 23(1-2), 175 (1994)
Schultz E, Ferrini C, Prins R, Catal. Lett., 14, 221 (1992)
Tangaraj A, Kumar R, Mirajkar SP, Ratnasamy P, J. Catal., 130, 1 (1991)
Taramasso M, Perego G, Notari B, "Preparation of Porous Crystalline Synthetic Materials Comprised of Silicon and Titanium Oxides," U.S. Patent, 4,410,501 (1983)
Tatsumi T, Nakamura M, Negishi S, Tominaga H, J. Chem. Soc.-Chem. Commun., 476 (1990)
Trong OD, Bonneviot L, Bittar A, Sayari A, Kaliaguine S, J. Mol. Catal., 74, 233 (1992)
Tuel A, Diab J, Gelin P, Dufaux M, Dutel JF, Taarit YB, J. Mol. Catal., 63, 95 (1990)
vander Pol AJHP, Verduyn AJ, Van Hooff JHC, Appl. Catal., 92, 113 (1992)
vander Pol AJHP, van Hooff JHC, Appl. Catal. A: Gen., 106, 97 (1993)
Yarker CA, Johnson PAV, Wright AC, Wong J, Greegor RB, Lytle FW, Sinclair RN, J. Non-Cryst. Solids, 79, 117 (1986)
Zecchina A, Spoto G, Bordiga S, Ferrero A, Petrini G, Leofanti G, Padovan M, "Framework and Extraframework Ti in Titanium-Silicalite: Investigation by Means of Physical Methods," Zeolite Chemistry and Catalysis, Jacobs, P.A., Jaeger, N.I., Kubelkova, L. and Wichterlova, B., eds., Elsevier, Amsterdam, 251 (1991)
