Articles & Issues
- Language
- English
- Conflict of Interest
- In relation to this article, we declare that there is no conflict of interest.
-
This is an Open-Access article distributed under the terms of the Creative Commons Attribution Non-Commercial License (http://creativecommons.org/licenses/bync/3.0) which permits
unrestricted non-commercial use, distribution, and reproduction in any medium, provided the original work is properly cited.
Copyright © KIChE. All rights reserved.
All issues
The Adhesion Properties of Stearic Acid-Loaded Rubber Compounds to Brass-Plated Steel Cords
1Department of Chemical Technology, Provincial College of Damyang, Chonnam, Korea 2R&D Center, Kumho Tire Co. and Inc., Ltd., Kwangju, Korea 3Department of Chemical Technology, Chonnam National University, Kwangju, Korea
gseo@chonnam.chonnam.ac.kr
Korean Journal of Chemical Engineering, July 1999, 16(4), 434-440(7), 10.1007/BF02698265
Download PDF
Abstract
The effect of stearic acid loading in rubber on the adhesion between rubber compounds and brass-plated steel cords was examined in respect to aging treatments and cure conditions. The adhesion interphase of a thin brass film/rubber compound containing stearic acid was investigated using an Auger electron spectrometer. The loading of stearic acid to rubber was not effective in the improvement of adhesion of rubber stock cured under optimum conditions, whereas it improved the adhesion property of premature cured samples by enhancing the physical property. High loading of stearic acid severely deteriorated the adhesion property, even at an unaged state due to the excessive formation of zinc sulfide. The loading of stearic acid did not affect the sensitivity of the rubber compound to humidity and thermal aging, but amplified the deterioration of adhesion when the rubber compound was subjected to salt solution aging, resulting in extremely poor adhesion. The effects of other ingredients and the aging treatment were also thoroughly examined.
References
Beniska J, Dogadkin B, Rubber Chem. Technol., 32, 780 (1959)
Dogadkin B, Beniska J, Rubber Chem. Technol., 31, 329 (1958)
Hammer GE, Shemenski RM, Hunt JD, J. Vac. Sci. Technol. A, 12(4), 2388 (1994)
Ishikawa Y, Rubber Chem. Technol., 57, 855 (1984)
Jeon GS, Kim YM, Seo G, HWAHAK KONGHAK, 36(2), 179 (1998)
Jeon GS, Han MH, Seo G, Korean J. Chem. Eng., 15(3), 317 (1998)
Jeon GS, Han MH, Seo G, J. Adhes., 69(1), 39 (1999)
Jeon GS, Han MH, Seo G, J. Adhes. Sci. Technol., 13(2), 153 (1999)
Jeon GS, Han MH, Seo G, Korean J. Chem. Eng., 16(2), 248 (1999)
Kurbatov GG, Beshenkov VG, Zaporozchenko VI, Surf. Interface Anal., 17, 779 (1991)
Lievens H, Kautsch. Gummi Kunstst., 39, 122 (1986)
Luyt AS, J. Appl. Polym. Sci., 47, 2177 (1993)
Seo G, J. Adhes. Sci. Technol., 11(11), 1433 (1997)
van Ooij WJ, Rubber Chem. Technol., 52, 665 (1979)
van Ooij WJ, Weening WE, Murray PF, Rubber Chem. Technol., 54, 227 (1981)
van Ooij WJ, Rubber Chem. Technol., 57, 421 (1984)
Dogadkin B, Beniska J, Rubber Chem. Technol., 31, 329 (1958)
Hammer GE, Shemenski RM, Hunt JD, J. Vac. Sci. Technol. A, 12(4), 2388 (1994)
Ishikawa Y, Rubber Chem. Technol., 57, 855 (1984)
Jeon GS, Kim YM, Seo G, HWAHAK KONGHAK, 36(2), 179 (1998)
Jeon GS, Han MH, Seo G, Korean J. Chem. Eng., 15(3), 317 (1998)
Jeon GS, Han MH, Seo G, J. Adhes., 69(1), 39 (1999)
Jeon GS, Han MH, Seo G, J. Adhes. Sci. Technol., 13(2), 153 (1999)
Jeon GS, Han MH, Seo G, Korean J. Chem. Eng., 16(2), 248 (1999)
Kurbatov GG, Beshenkov VG, Zaporozchenko VI, Surf. Interface Anal., 17, 779 (1991)
Lievens H, Kautsch. Gummi Kunstst., 39, 122 (1986)
Luyt AS, J. Appl. Polym. Sci., 47, 2177 (1993)
Seo G, J. Adhes. Sci. Technol., 11(11), 1433 (1997)
van Ooij WJ, Rubber Chem. Technol., 52, 665 (1979)
van Ooij WJ, Weening WE, Murray PF, Rubber Chem. Technol., 54, 227 (1981)
van Ooij WJ, Rubber Chem. Technol., 57, 421 (1984)
