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Rediscovering the Lattice-Fluid Theory for Phase Equilibria of Complex Mixtures Rediscovering the Lattice-Fluid Theory for Phase Equilibria of Complex Mixtures
Department of Chemical Engineering, Sogang University, Seoul 121-742, Korea 1Department of Chemical Engineering, Korea University, Seoul 151-742, Korea
Korean Journal of Chemical Engineering, May 2000, 17(3), 257-261(5), 10.1007/BF02699036
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Abstract
Various lattice statistical-thermodynamic theories after E.A. Guggenheim [Guggenheim, 1952] have been proposed with different assumptions on nonrandomness, the explicitness of the solution, and the model parameters. During the last decade, the present authors proposed a general approximation tool to the quasichemical solution of the nonrandom lattice-fluid combinatory and formulated a new rigorous EOS and the improved versions including the unified group contribution extensions and systems with strong association. In this study, developments of those EOSs are discussed with emphasis of on the practical utility of each model.
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References
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High MS, Danner RP, AIChE J., 36, 1625 (1990)
Kumar SK, Suter UW, Reid RC, Ind. Eng. Chem. Res., 26, 2532 (1987)
Lee CS, Yoo KP, Fluid Phase Equilib., 144(1-2), 13 (1998)
Okada M, Nose T, Polym. J., 13, 399 (1981)
Okada M, Nose T, Polym. J., 13, 591 (1981)
Panayiotou C, Sanchez IC, J. Phys. Chem., 95, 10090 (1991)
Panayiotou C, Vera JH, Polym. J., 14, 681 (1982)
Sanchez IC, Lacombe RH, J. Phys. Chem., 80, 2568 (1976)
Smirnova NA, Victorov AI, Fluid Phase Equilib., 34, 235 (1987)
Veytsman BA, J. Phys. Chem., 97, 7144 (1993)
Yoo KP, Shin HY, Lee CS, Bull. Korean Chem. Soc., 18(8), 841 (1997)
Yoo KP, Shin HY, Lee CS, Bull. Korean Chem. Soc., 18(9), 965 (1997)
Yoo KP, Shin HY, Lee CS, J. Supercrit. Fluids, 13(1), 55 (1998)
Yoo SJ, Yoo KP, Lee CS, J. Phys. Chem. B, 101(6), 1072 (1997)
You SS, Yoo KP, Lee CS, Fluid Phase Equilib., 93, 193 (1994)
You SS, Yoo KP, Lee CS, Fluid Phase Equilib., 93, 215 (1994)
