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Prediction of Equilibrium Solubility of Carbon Dioxide in Aqueous 2-Amino-2-methyl-1,3-propanediol Solutions

Power Generation Research Laboratory, Korea Electric Power Research Institute, 103-16 Munji-dong, Yusong-ku, Taejon 305-380, Korea
Korean Journal of Chemical Engineering, July 2000, 17(4), 484-487(4), 10.1007/BF02706866
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Abstract

The modified Kent-Eisenberg model was used to predict the solubility of carbon dioxide in aqueous 2-amino-2-methyl-1,3-propanediol (AMPO) solutions over a wide range of solvent concentration (10-30 mass %), temperature of (30-60℃), and partial pressure of carbon dioxide (5-1,100 kPa). For more accurate prediction, a new set of experimental data of this system was also presented and used in model calculation. The predicted results by the modified Kent-Eisenberg model were found to be in good agreement with the experimental data. The equilibrium constant, K1, which represented the deprotonation reaction of AMPD, was expressed as a function of not only temperature but also loading capacity and amine concentration.

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