Articles & Issues
- Language
- English
- Conflict of Interest
- In relation to this article, we declare that there is no conflict of interest.
-
This is an Open-Access article distributed under the terms of the Creative Commons Attribution Non-Commercial License (http://creativecommons.org/licenses/bync/3.0) which permits
unrestricted non-commercial use, distribution, and reproduction in any medium, provided the original work is properly cited.
Copyright © KIChE. All rights reserved.
All issues
Measurement of Infinite-dilution Activity Coefficients of Alcohols in Water Using Relative Gas-liquid Chromatographic Method
College of Science and Technology, Nihon University, 1-8 Surugadai, Kanda, Chiyoda-ku, Tokyo, Japan
tochigi@chem.cst.nihon-u.ac.jp
Korean Journal of Chemical Engineering, September 2000, 17(5), 502-505(4), 10.1007/BF02707156
Download PDF
Abstract
Infinite-dilution activity coefficients of n-alcohols (C-1-C-8) in water were measured by using the relative gas-liquid chromatographic method proposed by Orbey and Sandler [1991]. The temperature range of measurement was 298 to 343 K. The gamma(infinity) values at 298.15 K varied from 1.72 (methanol) to 1970 (n-heptanol). ASOG, UNIFAC, modified UNIFAC (Dortmund). modified UNIFAC (Lyngby) group contribution methods could predict gamma(infinity) to within 16.9, 28.8, 23.9 and 31.8 average percent error, respectively, for all systems and temperatures.
Keywords
References
Butler JA, Ramchandani CN, Thomson DW, J. Chem. Soc., 280 (1935)
Gmehling J, Li J, Schiller M, Ind. Eng. Chem. Res., 32, 178 (1993)
Gmehling J, Menke J, Schiller M, "Activity Coefficients at Infinite Dilution C1-C9," DECHEMA Chemistry Data Series, Vol. IX, Part 3, Frankfurt (1994)
Hansen HK, Rasmussen P, Fredenslund A, Schiller M, Gmehling, Ind. Eng. Chem. Res., 30, 2352 (1991)
Kojima K, Tochigi K, Seki H, Watase K, Kag. Kog., 32, 149 (1968)
Larsen BL, Rasmussen P, Fredenslund A, Ind. Eng. Chem. Res., 26, 2274 (1987)
Ochi K, Kojima K, J. Chem. Eng. Jpn., 20, 6 (1987)
Orbey H, Sandler SI, Ind. Eng. Chem. Res., 30, 2006 (1991)
Tochigi K, Tiegs D, Gmehling J, Kojima K, J. Chem. Eng. Jpn., 23, 453 (1990)
Tsonopoulos C, AIChE J., 33, 263 (1974)
Uchiyama M, Tochigi K, Kojima K, "Measurement of Infinite Dilution Activity Coefficients of Alcohols in Water Using Relative Gas-Liquid Chromatograph Method," Preprints of 61(st) annual meeting of SCEJ, paper no. G203, Nagoya (1996)
Gmehling J, Li J, Schiller M, Ind. Eng. Chem. Res., 32, 178 (1993)
Gmehling J, Menke J, Schiller M, "Activity Coefficients at Infinite Dilution C1-C9," DECHEMA Chemistry Data Series, Vol. IX, Part 3, Frankfurt (1994)
Hansen HK, Rasmussen P, Fredenslund A, Schiller M, Gmehling, Ind. Eng. Chem. Res., 30, 2352 (1991)
Kojima K, Tochigi K, Seki H, Watase K, Kag. Kog., 32, 149 (1968)
Larsen BL, Rasmussen P, Fredenslund A, Ind. Eng. Chem. Res., 26, 2274 (1987)
Ochi K, Kojima K, J. Chem. Eng. Jpn., 20, 6 (1987)
Orbey H, Sandler SI, Ind. Eng. Chem. Res., 30, 2006 (1991)
Tochigi K, Tiegs D, Gmehling J, Kojima K, J. Chem. Eng. Jpn., 23, 453 (1990)
Tsonopoulos C, AIChE J., 33, 263 (1974)
Uchiyama M, Tochigi K, Kojima K, "Measurement of Infinite Dilution Activity Coefficients of Alcohols in Water Using Relative Gas-Liquid Chromatograph Method," Preprints of 61(st) annual meeting of SCEJ, paper no. G203, Nagoya (1996)
