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Received June 14, 2001
Accepted July 13, 2001
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Determination of Decomposition Rate Constants of Volatile Organic Compounds and Nitric Oxide in a Pulsed Corona Discharge Reactor
Department of Chemical Engineering, Cheju National University, Ara, Cheju 690-756, Korea 1Department of Chemical Engineering, Kyungil University, Hayang, Kyungbuk 712-701, Korea 2Department of Chemical Engineering, Pohang University of Science & Technology, Kyungbuk 790-784, Korea
smokie@cheju.cheju.ac.kr
Korean Journal of Chemical Engineering, September 2001, 18(5), 711-718(8), 10.1007/BF02706391
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Abstract
The decomposition of toluene, propylene and nitric oxide by using a pulsed corona discharge process was investigated. The performance equation of the pulsed corona reactor was derived with the assumption that the decomposition reaction rate is directly proportional to the concentration of the pollutant and the discharge power. From this model equation and the experimental data, the apparent decomposition rate constants of various gaseous organic compounds and nitric oxide were determined. Alkene and substituted alkene were found to have much larger decomposition rate constants than aromatic compounds and substituted alkane, which indicates that the derivatives of aromatics and alkane cannot readily be decomposed in this system. To verify the validity of the model derived, the experimental data in the present study and in the literature were compared with the calculation results using the decomposition rate constants. Despite the different reactor geometry and experimental condition, good agreement between the experimental data and the calculation results was shown.
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Choi YS, Song YH, Kim SJ, Kim BU, HWAHAK KONGHAK, 38(3), 423 (2000)
Civitano L, "Industrial Application of Pulsed Corona Processing to Flue Gas," Non-Thermal Plasma Techniques for Pollution Control: Part B, Penetrante, B. M. and Schultheis, S.E., eds., Springer-Verlag, Berlin, 103 (1993)
Dinelli G, Civitano L, Rea M, IEEE Trans. Ind. Appl., 26, 535 (1990)
Futamura S, Zhang A, Prieto G, Yamamoto T, IEEE Trans. Ind. Appl., 34, 967 (1998)
Futamura S, Zhang A, Yamamoto T, IEEE Trans. Ind. Appl., 35, 760 (1999)
Hart H, Craine LE, Hart DJ, "Organic Chemistry," Houghton Mifflin Company, Boston (2000)
Jeong HK, Kim SC, Han C, Lee H, Song HK, Na BK, Korean J. Chem. Eng., 18(2), 196 (2001)
Kim JH, "Simultaneous Removal of SO2 and NOx by Pulsed Corona Discharge Process," MS Thesis, Chem. Eng. Dept., Pohang Univ. of Science and Technol. (2000)
Krasnoperov LN, Krishtopa LG, Bozzelli JW, J. Adv. Oxid. Technol., 2, 248 (1997)
Lowke JJ, Morrow R, IEEE Trans. Plasma Sci., 23, 661 (1995)
Mizuno A, Shimizu K, Chakrabarti A, Dascalescu L, Furuta S, IEEE Trans. Ind. Appl., 31, 957 (1995)
Mok YS, Ham SW, Nam I, IEEE Trans. Plasma Sci., 26, 1566 (1998)
Mok YS, Kim JH, Nam IS, Ham SW, Ind. Eng. Chem. Res., 39(10), 3938 (2000)
Mok YS, Lee HW, Hyun YJ, J. Environ. Res. Cheju National Univ., 8, 81 (2000)
Mok YS, Lee HW, Hyun YJ, Ham SW, Kim JH, Nam IS, Korean J. Chem. Eng., 18(3), 308 (2001)
Oda T, Kato T, Takahashi T, Shimizu K, IEEE Trans. Ind. Appl., 34, 268 (1998)
Ogata A, Shintani N, Mizuno K, Kushiyama S, Yamamoto T, IEEE Trans. Ind. Appl., 35, 753 (1999)
Penetrante BM, Hsiao MC, Bardsley JN, Merritt BT, Vogtlin GE, Wallman PH, Kuthi A, Burkhart CP, Bayless JR, "Comparison of Non-Thermal Plasma Techniques for Abatement of Volatile Organic Compounds and Nitrogen Oxides," Emerging Solutions to VOC & Air Toxics Conference, Clearwater Beach, Florida (1996)
Roush RA, Hutcherson RK, Ingram MW, Grothaus MG, "Effects of Pulse Risetime and Pulse Width on the Destruction of Toluene and NOx in a Coaxial Pulsed Corona Reactor," Proc. Twenty-Second International Power Modulator Symposium, Boca Raton, Florida, June 25-27, 78 (1996)
Seinfeld JH, "Air Pollution," McGraw Hill, New York (1975)
Shimizu K, Kinoshita K, Yanagihara K, Rajanikanth BS, Katsura S, Mizuno A, IEEE Trans. Ind. Appl., 33, 1373 (1997)
Snyder HR, Anderson GK, IEEE Trans. Plasma Sci., 26, 1695 (1998)
Son BH, "Effect of Additive and Pulse Forming Capacitor for the Oxidation of NO in Pulsed Corona Discharge Process," MS Thesis, School of Environ. Eng., Pohang Univ. of Science and Technol. (1998)
Song Y, Shin D, Shin W, Kim K, Choi Y, Choi YS, Lee W, Kim S, J. Korean Soc. Atmospheric Environ., 16, 247 (2000)
Sun W, Pashaie B, Dhali SK, J. Appl. Phys., 79, 3438 (1996)
Tas MA, Vanhardeveld R, Vanveldhuizen EM, Plasma Chem. Plasma Process., 17(4), 371 (1997)
Urashima K, Chang JS, Park JY, Lee DC, Chakrabarti A, Ito T, IEEE Trans. Ind. Appl., 34, 934 (1998)
van Veldhuizen EM, Zhou LM, Rutgers WR, Plasma Chem. Plasma Process., 18(1), 91 (1998)
Yamamoto T, Lawless PA, Owen MK, Ensor DS, "Decomposition of Volatile Organic Compounds by a Packed-Bed Reactor and a Pulsed-Corona Plasma Reactors," Non-Thermal Plasma Techniques for Pollution Control: Part B, Springer-Verlag, Berlin, Germany, 223 (1993)
