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Received May 11, 2001
Accepted July 10, 2001
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Influence of Stoichiometry and Alkalinity on Barium Hexaferrite Formation via the Supercritical Water Crystallization Method
Energy and Environment Research Department, Korea Institute of Energy Research, P.O. Box 103, Yoosung, Daejeon 305-600, Korea
sdopark@kier.re.kr
Korean Journal of Chemical Engineering, January 2002, 19(1), 120-125(6), 10.1007/BF02706884
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Abstract
Fine particles of barium hexaferrite were prepared from aqueous solutions of iron nitrate, barium nitrate and potassium hydroxide by utilizing a continuous flow type supercritical water crystallization method. The influence of stoichiometry (Fe/Ba mole ratio) and alkalinity (R) on the product composition and morphology was studied under fixed temperature, pressure and residence time. Experiments were performed with varying Fe/Ba mole ratios and alkali mole ratio (R). Within mole ratio ranges of 0.5
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Kiyama M, Bull. Chem. Soc. Jpn., 49(7), 1855 (1976)
Kubo O, Ido T, Yokoyama H, IEEE Trans. Magn., 18(5), 1122 (1982)
Nam SC, Lee JH, Kim JG, Kim KJ, Park SD, Theor. Appl. Chem. Eng., 5(2), 4149 (1999)
Sada E, Kumazawa H, Cho HM, Ind. Eng. Chem. Res., 30(6), 1319 (1991)
Sakai H, Hanawa K, Aoyagi K, IEEE Trans. Magn., 28(6), 3355 (1992)
Wang ML, Shih ZW, Lin CH, J. Cryst. Growth, 139, 47 (1994)
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