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Received November 24, 2001
Accepted March 18, 2002
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Fabrication of a Graded-index Polymer Optical Fiber Preform by Using a Centrifugal Force
Center for Advanced Functional Polymers, Department of Chemical Engineering, Korea Advanced Institute of Science and Technology, 373-1, Kusong-Dong, Yusong-Gu,Daejeon 305-701, Korea 1E-Polymer Laboratory, Samsung Advanced Institute of Technology, 103-6, Moonji-Dong, Yusong-Gu, Daejeon 305-380, Korea
oopark@kaist.ac.kr
Korean Journal of Chemical Engineering, May 2002, 19(3), 505-509(5), 10.1007/BF02697164
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Abstract
We have investigated a fabricating method for a graded index polymer optical fiber preform using a centrifugal force. When two monomers with different densities and refractive indices are polymerized under a centrifugal force, a concentration gradient is generated due to their density difference. Therefore, a graded refractive index can be obtained according to the concentration gradient. When a monomer is polymerized under a centrifugal force, a preform with a hollow is obtained because of volume shrinkage. To compensate for this practically, additional monomer_x000D_
should be filled into the hollow. Monomer should be fed to obtain a continuous gradient of refractive index at the interface before the first polymerized product is perfectly glassified. Two different types of feeding additional monomer were experimented with: monomer-monomer pair (case I) and monomer-polymer pair (case II). The graded index profile with a proper Δn (about 0.01) was successfully obtained in either case.
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