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Received January 12, 2002
Accepted March 27, 2002
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Partial Oxidation of Methane over Nickel Catalysts Supported on Various Aluminas
Chemical Technology Division, Korea Research Institute of Chemical Technology, P. O. Box 107, Yuseong, Daejeon 305-600, Korea 1LNG Technology Research Center, Korea Gas Corporation, Dongchun-Dong, Yeonsu-Ku, Incheon 406-130, Korea
kwjun@pado.krict.re.kr
Korean Journal of Chemical Engineering, September 2002, 19(5), 735-741(7), 10.1007/BF02706961
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Abstract
Partial oxidation of methane (POM) was systematically investigated in a fixed bed reactor over 12 wt% Ni catalysts supported on α-Al2O3, γ-Al2O3 and θ-Al2O3 which were prepared at different conditions. Results indicate that the catalytic activity toward POM strongly depends on the BET surface area of the support. All the Ni/θ-Al2O3 catalysts showed high activity toward POM due to the less formation of inactive NiAl2O4 species, the existence of NiOx species and stable θ-Al2O3 phase. Although Ni/γ-Al2O3 showed the highest activity toward POM, long-time stability cannot be expected as a result of the deterioration of the support at higher temperature, which is revealed from BET results. From the reaction and characterization results, it is inferred that the optimal conditions for the preparation of θ-Al2O3 are 1,173 K and 12 h.
References
Ashcroft AT, Cheetham AK, Green MLH, Vernon PDF, Nature, 352, 225 (1991)
Au CT, Wang HY, Wan HL, J. Catal., 158(1), 343 (1996)
Chang JS, Park SE, Roh HS, Park YK, Bull. Korean Chem. Soc., 19, 809 (1998)
Choudhary VR, Rajput AM, Probhaker B, J. Catal., 139, 326 (1993)
Diskin AM, Cunningham RH, Ormerod RMZ, Catal. Today, 46(2-3), 147 (1998)
Dong WS, Roh HS, Liu ZW, Jun KW, Park SE, Bull. Korean Chem. Soc., 22, 1323 (2001)
Hickman DA, Schmidt LD, Science, 259, 343 (1993)
Hu YH, Ruckenstein E, J. Catal., 158(1), 260 (1996)
Jung K, Coh BY, Lee HI, Bull. Korean Chem. Soc., 20, 89 (1999)
Vanlooij F, Geus JW, J. Catal., 168(2), 154 (1997)
Lu Y, Liu Y, Shen SK, J. Catal., 177(2), 386 (1998)
Lu Y, Xue JZ, Yu CC, Liu Y, Shen SK, Appl. Catal. A: Gen., 174(1-2), 121 (1998)
Miao Q, Xiong GX, Sheng SS, Cui W, Xu L, Guo XX, Appl. Catal. A: Gen., 154(1-2), 17 (1997)
Nakagawa K, Anzai K, Matsui N, Ikenaga N, Suzuki T, Teng YH, Kobayashi T, Haruta M, Catal. Lett., 51(3-4), 163 (1998)
Nam SW, Yoon SP, Ha HY, Hong SA, Maganyuk AP, Korean J. Chem. Eng., 17(3), 288 (2000)
Pena MA, Gomez JP, Fierro JL, Appl. Catal. A: Gen., 144(1-2), 7 (1996)
Roh HS, Dong WS, Jun KW, Park SE, Chem. Lett., 88 (2001)
Roh HS, Jun KW, Dong WS, Park SE, Baek YS, Catal. Lett., 74(1-2), 31 (2001)
Roh HS, Jun KW, Dong WS, Park SE, Joe YI, Chem. Lett., 666 (2001)
Roh HS, "Catalytic Behavior of Supported Nickel Catalysts for Methane Reforming Reactions," Ph.D. Dissertation, Yonsei University (2001)
Ruckenstein E, Hul YH, Appl. Catal. A: Gen., 183(1), 85 (1999)
Takeguchi T, Furukawa SN, Inoue M, J. Catal., 202(1), 14 (2001)
Tang S, Lin J, Tan KL, Catal. Lett., 51(3-4), 169 (1998)
Tsang SC, Claridge JB, Green ML, Catal. Today, 23(1), 3 (1995)
Wang HY, Ruckenstein E, J. Catal., 186(1), 181 (1999)
Zhu J, Zhang D, King KD, Fuel, 80, 899 (2001)
Au CT, Wang HY, Wan HL, J. Catal., 158(1), 343 (1996)
Chang JS, Park SE, Roh HS, Park YK, Bull. Korean Chem. Soc., 19, 809 (1998)
Choudhary VR, Rajput AM, Probhaker B, J. Catal., 139, 326 (1993)
Diskin AM, Cunningham RH, Ormerod RMZ, Catal. Today, 46(2-3), 147 (1998)
Dong WS, Roh HS, Liu ZW, Jun KW, Park SE, Bull. Korean Chem. Soc., 22, 1323 (2001)
Hickman DA, Schmidt LD, Science, 259, 343 (1993)
Hu YH, Ruckenstein E, J. Catal., 158(1), 260 (1996)
Jung K, Coh BY, Lee HI, Bull. Korean Chem. Soc., 20, 89 (1999)
Vanlooij F, Geus JW, J. Catal., 168(2), 154 (1997)
Lu Y, Liu Y, Shen SK, J. Catal., 177(2), 386 (1998)
Lu Y, Xue JZ, Yu CC, Liu Y, Shen SK, Appl. Catal. A: Gen., 174(1-2), 121 (1998)
Miao Q, Xiong GX, Sheng SS, Cui W, Xu L, Guo XX, Appl. Catal. A: Gen., 154(1-2), 17 (1997)
Nakagawa K, Anzai K, Matsui N, Ikenaga N, Suzuki T, Teng YH, Kobayashi T, Haruta M, Catal. Lett., 51(3-4), 163 (1998)
Nam SW, Yoon SP, Ha HY, Hong SA, Maganyuk AP, Korean J. Chem. Eng., 17(3), 288 (2000)
Pena MA, Gomez JP, Fierro JL, Appl. Catal. A: Gen., 144(1-2), 7 (1996)
Roh HS, Dong WS, Jun KW, Park SE, Chem. Lett., 88 (2001)
Roh HS, Jun KW, Dong WS, Park SE, Baek YS, Catal. Lett., 74(1-2), 31 (2001)
Roh HS, Jun KW, Dong WS, Park SE, Joe YI, Chem. Lett., 666 (2001)
Roh HS, "Catalytic Behavior of Supported Nickel Catalysts for Methane Reforming Reactions," Ph.D. Dissertation, Yonsei University (2001)
Ruckenstein E, Hul YH, Appl. Catal. A: Gen., 183(1), 85 (1999)
Takeguchi T, Furukawa SN, Inoue M, J. Catal., 202(1), 14 (2001)
Tang S, Lin J, Tan KL, Catal. Lett., 51(3-4), 169 (1998)
Tsang SC, Claridge JB, Green ML, Catal. Today, 23(1), 3 (1995)
Wang HY, Ruckenstein E, J. Catal., 186(1), 181 (1999)
Zhu J, Zhang D, King KD, Fuel, 80, 899 (2001)
