Articles & Issues
- Language
- English
- Conflict of Interest
- In relation to this article, we declare that there is no conflict of interest.
- Publication history
-
Received April 30, 2001
Accepted April 30, 2002
-
This is an Open-Access article distributed under the terms of the Creative Commons Attribution Non-Commercial License (http://creativecommons.org/licenses/bync/3.0) which permits
unrestricted non-commercial use, distribution, and reproduction in any medium, provided the original work is properly cited.
Copyright © KIChE. All rights reserved.
All issues
Use of Cascade Reduction Potential for Selective Precipitation of Au, Cu, and Pb in Hydrochloric Acid Solution
Department of Environmental Science and Engineering, Kwangju Institute of Science and Technology (K-JIST), 1 Oryong-dong, Buk-gu, Gwangju 500-712, Korea
shmoon@kjist.ac.kr
Korean Journal of Chemical Engineering, September 2002, 19(5), 797-802(6), 10.1007/BF02706970
Download PDF
Abstract
Optimization of reduction potential for electroseparation was studied for the recovery of gold, copper, and lead from acidic solution. A linear sweep voltammetric method enabled us to determine characteristic reduction potentials for each metal and the kinetics of the metal deposition indicated by current-voltage curves. In order to precipitate the metal species sequentially, reduction potentials were examined for the individual and mixed solutions of Au(III), Cu(II), and Pb(II). The three metals were reasonably well isolated from the mixed solutions such as Cu(II)/Pb(II) and Au(III)/Cu(II)/Pb(II) in the order of the corresponding reduction potentials, in particular, the mass transfer controlled reduction potentials, obtained from linear sweep voltammetry (LSV) measurement.
Keywords
References
Armstrong RD, Todd M, Atkinson JW, Scott K, J. Appl. Electrochem., 27(8), 965 (1997)
Armstrong RD, Todd M, Atkinson JW, Scott K, J. Appl. Electrochem., 26(4), 379 (1996)
Bard AJ, Faulkner LR, "Electrochemical Methods Fundamentals and Applications," John Wiley & Sons, Inc., New York (1980)
Bemardes A, Bohlinger I, Rodriguez D, Milbrandt H, Wuth W, "Recycling of Printed Circuit Boards by Smelting with Oxidizing/Reducing Top Blowing Process," Proceedings of the EPD Congress, Orlando, FL, Feb. 9-13 (1997)
Chang JS, Huang JC, Biotechnol. Prog., 14(5), 735 (1998)
Dean JA, "Langes Handbook of Chemistry, 40th Ed.," McGraw-Hill, Inc., New York (1992)
Fresner J, Schnitzer H, "Lessons from 13 Waste Minimization Case Studies in Styria," Proceedings of the 7th ISWA International Congress and Exhibition-Volume 2, Yokohama, Japan, Oct. 27, Nov. 1 (1996)
Fu J, Nakamura S, Akiba K, Anal. Sci., 11, 149 (1995)
Juang RS, Wang SW, Lin LC, J. Membr. Sci., 160(2), 225 (1999)
Kim K, Cho JW, Korean J. Chem. Eng., 14(3), 162 (1997)
Kim SJ, Jeung SY, Moon H, Korean J. Chem. Eng., 15(6), 637 (1998)
Pesic B, Zhou T, "Recovery and Separation of Nickel and Cobalt from Cobaltite and Siegenite Leach Solutions with a Pyridine-based Extractant Mixture," Proceedings of the EPD Congress, Orlando, FL, Feb. 9-13 (1997)
Pletcher D, Walsh FC, "Industnal Electrochemistry 2nd Ed.," Champman and Hall, London (1990)
Raubenheimer HG, Cronje S, "Gold: Progress in Chemistry, Biochemistry, and Technology," John Wiley & Sons, Inc., New York (1999)
Ringborn, "Complexation in Analytical Chemistry," Interscience Publishers (1963)
Scott K, "Electrochemical Processes for Clean Technology," The Royal Society of Chemistry, Cambridge (1995)
Snoeyink VL, Jenkins D, "Water Chemistry," John Wiley & Sons, Inc., New York (1980)
Voropanova LA, Velichko LN, Russian J. Appl. Chem., 72, 469 (1999)
Walsh FC, Gabe DR, Surf. Technol., 12, 25 (1981)
Armstrong RD, Todd M, Atkinson JW, Scott K, J. Appl. Electrochem., 26(4), 379 (1996)
Bard AJ, Faulkner LR, "Electrochemical Methods Fundamentals and Applications," John Wiley & Sons, Inc., New York (1980)
Bemardes A, Bohlinger I, Rodriguez D, Milbrandt H, Wuth W, "Recycling of Printed Circuit Boards by Smelting with Oxidizing/Reducing Top Blowing Process," Proceedings of the EPD Congress, Orlando, FL, Feb. 9-13 (1997)
Chang JS, Huang JC, Biotechnol. Prog., 14(5), 735 (1998)
Dean JA, "Langes Handbook of Chemistry, 40th Ed.," McGraw-Hill, Inc., New York (1992)
Fresner J, Schnitzer H, "Lessons from 13 Waste Minimization Case Studies in Styria," Proceedings of the 7th ISWA International Congress and Exhibition-Volume 2, Yokohama, Japan, Oct. 27, Nov. 1 (1996)
Fu J, Nakamura S, Akiba K, Anal. Sci., 11, 149 (1995)
Juang RS, Wang SW, Lin LC, J. Membr. Sci., 160(2), 225 (1999)
Kim K, Cho JW, Korean J. Chem. Eng., 14(3), 162 (1997)
Kim SJ, Jeung SY, Moon H, Korean J. Chem. Eng., 15(6), 637 (1998)
Pesic B, Zhou T, "Recovery and Separation of Nickel and Cobalt from Cobaltite and Siegenite Leach Solutions with a Pyridine-based Extractant Mixture," Proceedings of the EPD Congress, Orlando, FL, Feb. 9-13 (1997)
Pletcher D, Walsh FC, "Industnal Electrochemistry 2nd Ed.," Champman and Hall, London (1990)
Raubenheimer HG, Cronje S, "Gold: Progress in Chemistry, Biochemistry, and Technology," John Wiley & Sons, Inc., New York (1999)
Ringborn, "Complexation in Analytical Chemistry," Interscience Publishers (1963)
Scott K, "Electrochemical Processes for Clean Technology," The Royal Society of Chemistry, Cambridge (1995)
Snoeyink VL, Jenkins D, "Water Chemistry," John Wiley & Sons, Inc., New York (1980)
Voropanova LA, Velichko LN, Russian J. Appl. Chem., 72, 469 (1999)
Walsh FC, Gabe DR, Surf. Technol., 12, 25 (1981)
