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Received May 4, 2002
Accepted July 5, 2002
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A Study on Fouling Mitigation Using Pulsing Electric Fields in Electrodialysis of Lactate Containing BSA
1Department of Environmental Science and Engineering, Kwangju Institute of Science and Technology (K-JIST), 1 Oryong-Dong, Buk-Gu, Gwangju 500-712, Korea 2Radiation & Environment Group, Nuclear Power Laboratory, Korea Electric Power Research Institute (KEPRI), 103-16 Munji-Dong, Yusung-Gu, Daejeon 305-380
shmoon@kjist.ac.kr
Korean Journal of Chemical Engineering, September 2002, 19(5), 880-887(8), 10.1007/BF02706984
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Abstract
Fouling tendency in electrodialysis was investigated using the electrochemical and physical properties of the foulants and ion exchange membranes. It was found that bovine serum albumin (BSA), a large molecular weight protein, fouled the AMX membrane irreversibly by deposition on the membrane surface. Electrodialysis experiments of lactate with 1.0 wt% of BSA were performed using the square wave powers at different frequencies to examine the pulsing power influences as a fouling mitigation method, and the results were compared with the data obtained using the DC power. Reduced fouling potentials were observed when the square wave powers were used in the electrodialysis of lactate and confirmed the membrane fouling index for electrodialysis (EDMFI). The pulsing electric fields enhanced the mobility of the charged particles in the fouling layer and decreased the electric resistance of the electrodialysis cell. It was clearly observed that the pulsing electric fields with different frequencies reduced the fouling potentials, and consequently the power consumption was reduced significantly as a fouling mitigation_x000D_
method.
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References
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Yoshida N, Ishisaki T, Watakabe A, Yoshitake M, Electrochim. Acta, 43(24), 3749 (1998)
Zhang W, Wahlgren M, Sivik B, Desalination, 72, 263 (1989)
Zhu H, Nystrom M, Colloids Surf. A: Physicochem. Eng. Asp., 138, 309 (1998)
von Zumbusch P, Kulcke W, Brunner G, J. Membr. Sci., 142(1), 75 (1998)
Benavente J, Jonsson G, Colloids Surf. A: Physicochem. Eng. Asp., 138, 255 (1998)
Bowen WR, Ahmad AL, AIChE J., 43(4), 959 (1997)
Bowen WR, Sabuni HAM, Ind. Eng. Chem. Res., 31, 515 (1992)
Bowen WR, "Electrochemical Aspects of Microfiltration and Ultrafiltration," Membranes in Bioprocessing: Theory and Applications, Howell, J.A., Sanchez, V. and Field, R.W., eds., Chapman & Hall, London, UK (1993)
Bowen WR, Kingdom RS, Sabuni HAM, J. Membr. Sci., 40, 219 (1989)
Chang JD, Chun MS, Chung GY, Kim JJ, HWAHAK KONGHAK, 38(4), 485 (2000)
Choi KH, Jeoung TY, Korean J. Chem. Eng., 19(1), 107 (2002)
Choi SW, Yoon JY, Haam SJ, Jung JK, Kim WS, HWAHAK KONGHAK, 38(1), 26 (2000)
Czekaj P, Mores W, Davis RH, Guell C, J. Membr. Sci., 180(1), 157 (2000)
Do DD, Elhassadi AA, J. Membr. Sci., 25, 113 (1985)
Guizard C, Rios G, "Transport and Fouling Phenomena in Liquid Phase Separation with Inorganic and Hybrid Membranes," Fundamentals of Inorganic Membrane Science and Technology, Burggraaf, A.J. and Cot, L., eds., Elsevier (1996)
Huotari HM, Tragarda G, Huisman IH, Trans IChemE Part A, 77, 461 (1999)
Jonsson AS, Jonsson B, Sep. Sci. Technol., 31(19), 2611 (1996)
Kelly ST, Zydney AL, J. Membr. Sci., 107(1-2), 115 (1995)
Kang MS, Tanioka A, Moon SH, Korean J. Chem. Eng., 19(1), 99 (2002)
Kim YH, Moon SH, J. Chem. Technol. Biotechnol., 76(2), 169 (2001)
Lee HJ, Moon SH, "Use of Electrical Pulses for Mitigation of Membrane Fouling in Electrodialysis," 12th Electrosynthesis Forum, Clearwater Beach, Florida (1998)
Lee HJ, Moon SH, Tsai SP, Sep. Purif. Methods, 27, 89 (2002)
Lindstrand V, Sundstrom G, Jonsson AS, Desalination, 128(1), 91 (2000)
Marshall AD, Munro PA, Tragardh, Desalination, 91, 65 (1993)
Mockel D, Staude E, Dal-Cin M, Darcovich K, Guiver M, J. Membr. Sci., 145(2), 211 (1998)
Oka KK, Frusawa K, "Electrophoresis," Electrical Phenomena at Interface Fundamentals, Measurements, and Applications, 2nd ed., Ohshima, H. and Furusawa, K., eds., Marcel Dekker, New York (1998)
Oussedik S, Belhocine D, Grib H, Lounici H, Piron DL, Mameri N, Desalination, 127(1), 59 (2000)
Pieracci J, Crivello JV, Belfort G, J. Membr. Sci., 156(2), 223 (1999)
Rodgers VGJ, Sparks RE, J. Membr. Sci., 68, 149 (1992)
Schoeman JJ, Thompson MA, "Electrodialysis," Water Treatment Membrane Processes, Mallevialle, J., Odendaal, P.E. and Wiesner, M.R., eds., McGraw-Hill, New York (1996)
Scott K, "Handbook of Industrial Membranes," Elsevier, Oxford, UK (1995)
Sheikholeslami R, Desalination, 123, 45 (1999)
Tokuyama Corp., Bulletin of NEOSEPTA-Ion Exchange Membranes (1995)
Yoshida N, Ishisaki T, Watakabe A, Yoshitake M, Electrochim. Acta, 43(24), 3749 (1998)
Zhang W, Wahlgren M, Sivik B, Desalination, 72, 263 (1989)
Zhu H, Nystrom M, Colloids Surf. A: Physicochem. Eng. Asp., 138, 309 (1998)
von Zumbusch P, Kulcke W, Brunner G, J. Membr. Sci., 142(1), 75 (1998)
