Articles & Issues
- Language
- English
- Conflict of Interest
- In relation to this article, we declare that there is no conflict of interest.
- Publication history
-
Received April 4, 2002
Accepted May 20, 2002
-
This is an Open-Access article distributed under the terms of the Creative Commons Attribution Non-Commercial License (http://creativecommons.org/licenses/bync/3.0) which permits
unrestricted non-commercial use, distribution, and reproduction in any medium, provided the original work is properly cited.
Copyright © KIChE. All rights reserved.
All issues
A Study of Adsorption Behavior of 2,4-Dichlorophenoxyacetic Acid onto Various GACs
Department of Environmental Engineering, Chonnam National University, Gwangju 500-757, Korea 1RRC for Photonics Materials and Devices, Chonnam National University, Gwangju 500-757, Korea
sjkim@chonnam.ac.kr
Korean Journal of Chemical Engineering, November 2002, 19(6), 1050-1058(9), 10.1007/BF02707232
Download PDF
Abstract
Adsorption and desorption of 2,4-dichlorophenoxyacetic acid (2,4-D) onto granular activated carbon (GAC) were studied to get basic information on their removal from aqueous solution. Single species adsorption equilibria of 2,4-D dissolved in water have been measured using F400, SLS103, and WWL. Equilibrium capacity increased with decreasing pH. The magnitude of adsorption capacity of 2,4-D was the order of F400>SLS103>WWL. Kinetic parameters were measured in a batch adsorber to analyze the adsorption rate of 2,4-D. The internal diffusion_x000D_
coefficients were determined by comparing the experimental concentration curve with that predicted from the surface diffusion model (SDM) and Pore diffusion model (PDM). The linear driving force approximation (LDFA) model was used to simulate isothermal adsorption behaviors in a fixed bed adsorber and successfully simulated experimental adsorption breakthrough behavior under various operation conditions.
Keywords
References
Buckingham J, "Dictionary of Organic Compounds," 5th Ed. and Supplements, Chapman and Hall, New York, 2, 2275 (1988)
Chen JP, Wang X, Sep. Purif. Methods, 19, 157 (2000)
Hornsby AG, Wauchope RD, Herner AE, "Pesticide Properties in the Environment," Springer-Verlag New York, Inc. (1996)
Khan AR, Ataullah R, Alhaddad A, J. Colloid Interface Sci., 194(1), 154 (1997)
Kim TY, Kim SJ, Cho SY, Korean J. Chem. Eng., 18(5), 755 (2001)
Kim YM, Suh SS, Korean J. Chem. Eng., 16(3), 401 (1999)
Lee JW, "Separation of Cephalosporin C in Nonionic Polymeric Resin Columns," Ph.D. Thesis, Department of Chemical Technology, Chonnam National University (1996)
Markovska L, Meshko V, Noveski V, Korean J. Chem. Eng., 18(2), 190 (2001)
Misic DM, Sudo Y, Suzuki M, Kawazoe K, J. Chem. Eng. Jpn., 15, 490 (1977)
Moon H, Lee WK, J. Colloid Interface Sci., 96, 162 (1983)
Reid RC, Prausnitz JM, Pokung BE, "The Properties of Gases and Liquids," McGraw-Hill Co., New York (1994)
Wakao N, Chem. Eng. Sci., 33, 1375 (1978)
Zumriye A, Julide Y, Waste Manage., 21, 695 (2001)
Chen JP, Wang X, Sep. Purif. Methods, 19, 157 (2000)
Hornsby AG, Wauchope RD, Herner AE, "Pesticide Properties in the Environment," Springer-Verlag New York, Inc. (1996)
Khan AR, Ataullah R, Alhaddad A, J. Colloid Interface Sci., 194(1), 154 (1997)
Kim TY, Kim SJ, Cho SY, Korean J. Chem. Eng., 18(5), 755 (2001)
Kim YM, Suh SS, Korean J. Chem. Eng., 16(3), 401 (1999)
Lee JW, "Separation of Cephalosporin C in Nonionic Polymeric Resin Columns," Ph.D. Thesis, Department of Chemical Technology, Chonnam National University (1996)
Markovska L, Meshko V, Noveski V, Korean J. Chem. Eng., 18(2), 190 (2001)
Misic DM, Sudo Y, Suzuki M, Kawazoe K, J. Chem. Eng. Jpn., 15, 490 (1977)
Moon H, Lee WK, J. Colloid Interface Sci., 96, 162 (1983)
Reid RC, Prausnitz JM, Pokung BE, "The Properties of Gases and Liquids," McGraw-Hill Co., New York (1994)
Wakao N, Chem. Eng. Sci., 33, 1375 (1978)
Zumriye A, Julide Y, Waste Manage., 21, 695 (2001)
