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Received April 25, 2002
Accepted July 29, 2002
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Steam Gasification of an Australian Bituminous Coal in a Fluidized Bed
Energy/Coal and Chemical Process Research Team, Research Institute of Industrial Science and Technology, Pohang 790-330, Korea 1Department of Chemical Engineering and Energy & Environment Research Center, Korea Advanced Institute of Science and Technology, Daejeon 305-701, Korea 2Department of Chemical Engineering, Kunsan National University, Kunsan 573-701, Korea
wjlee@risnet.rist.re.kr
Korean Journal of Chemical Engineering, November 2002, 19(6), 1091-1096(6), 10.1007/BF02707238
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Abstract
To produce low calorific value gas, Australian coal has been gasified with air and steam in a fluidized bed reactor (0.1 m-I.D×1.6 m-high) at atmospheric pressure. The effects of fluidizing gas velocity (2-5 Uf/Umf), reaction temperature (750-900 ℃), air/coal ratio (1.6-3.2), and steam/coal ratio (0.63-1.26) on gas composition, gas yield, gas calorific value of the product gas and carbon conversion have been determined. The calorific value and yield of the product gas, cold gas efficiency, and carbon conversion increase with increasing fluidization gas velocity and reaction temperature. With increasing air/coal ratio, carbon conversion, cold gas efficiency and yield of the product gas increase, but the calorific value of the product gas decreases. When steam/coal ratio is increased, cold gas efficiency, yield and calorific value of the product gas increase, but carbon conversion is little changed. Unburned carbon fraction of cyclone fine decreases with increasing fluidization gas velocity, reaction temperature and air/coal ratio, but is nearly constant with increasing steam/coal ratio. Overall carbon conversion decreases with increasing fluidization velocity and air/coal ratio, but increases with increasing reaction temperature. The particle entrainment rate increases with increasing fluidization velocity, but decreases with increasing reaction temperature.
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References
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Geldart D, "Gas Fluidization Technology," Chap. 6, John Wiley & Sons (1986)
Gutierrez LA, Watkinson AP, Fuel, 61, 133 (1982)
Herguido J, Corella J, Gonzalez-Saiz J, Ind. Eng. Chem. Res., 31, 1274 (1992)
Kim YJ, Lee JM, Kim SD, Fuel, 79(1), 69 (2000)
Lee IC, Korean J. Chem. Eng., 4(2), 194 (1987)
Lee WJ, Kim SD, Fuel, 74, 1387 (1995)
Lee WJ, Kim SD, "Fluidization VII," ed. Potter, O.E. and Nicklin, D.J., Engineering Foundation, New York, 479 (1992)
Lee WJ, Kim SD, Song BH, Korean J. Chem. Eng., 18(5), 640 (2001)
Purdy MS, Felder RM, Ferrell JK, Ind. Eng. Chem. Process Des. Dev., 20, 675 (1981)
Riley RK, Judd MR, Chem. Eng. Commun., 62, 151 (1987)
Saffer MOA, Ferrell JK, Int. Chem. Eng., 28, 46 (1988)
Song BH, Kim SD, Fuel, 72(6), 797 (1993)
Sue-A-Quan TA, Watkinson AP, Gaikward RP, Ferris BR, Fuel Process. Technol., 27, 67 (1991)
Watkinson AP, Cheng G, Lim CJ, Can. J. Chem. Eng., 65, 791 (1987)
Watkinson AP, Cheng G, Prakash CB, Can. J. Chem. Eng., 61, 468 (1983)