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Received October 31, 2002
Accepted December 6, 2002
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Ammoxidation of Isomeric Picolines on Molybdenum Phosphate Catalyst
Chemical Technology Research Division, Korea Research Institute of Chemical Technology, Daejeon 305-600, Korea 1Division of Chemical Engineering, Hanbat National University, Daejeon 305-719, Korea 2Department of Chemical Engineering, Chungbuk National University, Cheongju, Chungbuk 361-763, Korea
chshin@chungbuk.ac.kr
Korean Journal of Chemical Engineering, March 2003, 20(2), 279-283(5), 10.1007/BF02697241
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Abstract
Ammoxidation of 2-, 3-, and 4-picolines to their nitrile compounds has been studied on an amorphous molybdenum phosphate (MoPO) catalyst with P/Mo=1.0. The overall catalytic results of this study reveal that the conversion is in the order 2-picoline>4-picoline>3-picoline, which can be rationalized neither by the steric effects nor by the thermodynamic point of view. However, the MoPO catalyst prepared here was found to be very effective for the ammoxidation reaction of picolines. Even at almost 100% conversion levels of all three picoline isomers, selectivities to their nitrile compounds on this MoPO catalyst were higher than 90% or so.
References
Anderson A, Lundin ST, J. Catal., 65, 9 (1980)
Anderson A, Lundin ST, J. Catal., 58, 383 (1979)
Chary KVR, Kishan G, Bhaskar T, Chem. Commun., 1399 (1999)
Chary KVR, Kishan G, Lakshmi K, Ramesh K, Langmuir, 16(18), 7192 (2000)
Chary KVR, Kishan G, Narayana KV, Bhaskar T, J. Chem. Res., 314 (1998)
Martin A, Lucke B, Seeboth H, Appl. Catal., 49, 205 (1989)
Martin A, Zhang Y, Zanthoff HW, Meisel M, Baerns M, Appl. Catal. A: Gen., 139(1-2), L11 (1996)
Narayana KV, Venugopal A, Rao KSR, Masthan SK, Rao VV, Rao PK, Appl. Catal. A: Gen., 167(1), 11 (1998)
Paustian JE, Puzio JF, Stavropoulos N, Sze MC, Chemtech., March, 174 (1981)
Prasad R, Kar AK, Ind. Eng. Chem. Process Des. Dev., 15, 1 (1976)
Rao RR, Kulkarni M, Subrahmanyam M, Rao AVR, Zeolites, 16, 254 (1996)
Rao PK, Rao KS, Masthan SK, Narayana KV, Rajiah T, Rao VV, Appl. Catal. A: Gen., 163(1-2), 123 (1997)
Rizayev RG, Mamedov EA, Vislovskii VP, Sheinin VE, Appl. Catal. A: Gen., 83, 103 (1992)
Shin CH, Chang TS, Cho DH, Lee DK, Lee YK, HWAHAK KONGHAK, 35(2), 270 (1997)
Shin CH, Chang TS, Cho DH, Lee DK, Lee YK, HWAHAK KONGHAK, 35(4), 490 (1997)
Shin CH, Chang TS, Cho DH, Lee DK, Lee YK, J. Korean Ind. Eng. Chem., 8(5), 749 (1997)
Srinvias N, Kishan RM, Kulkarni SJ, Raghavan KV, Microporous Mesoporous Mater., 39, 125 (2000)
Suvorov BV, Int. Chem. Eng., 8, 588 (1968)
Anderson A, Lundin ST, J. Catal., 58, 383 (1979)
Chary KVR, Kishan G, Bhaskar T, Chem. Commun., 1399 (1999)
Chary KVR, Kishan G, Lakshmi K, Ramesh K, Langmuir, 16(18), 7192 (2000)
Chary KVR, Kishan G, Narayana KV, Bhaskar T, J. Chem. Res., 314 (1998)
Martin A, Lucke B, Seeboth H, Appl. Catal., 49, 205 (1989)
Martin A, Zhang Y, Zanthoff HW, Meisel M, Baerns M, Appl. Catal. A: Gen., 139(1-2), L11 (1996)
Narayana KV, Venugopal A, Rao KSR, Masthan SK, Rao VV, Rao PK, Appl. Catal. A: Gen., 167(1), 11 (1998)
Paustian JE, Puzio JF, Stavropoulos N, Sze MC, Chemtech., March, 174 (1981)
Prasad R, Kar AK, Ind. Eng. Chem. Process Des. Dev., 15, 1 (1976)
Rao RR, Kulkarni M, Subrahmanyam M, Rao AVR, Zeolites, 16, 254 (1996)
Rao PK, Rao KS, Masthan SK, Narayana KV, Rajiah T, Rao VV, Appl. Catal. A: Gen., 163(1-2), 123 (1997)
Rizayev RG, Mamedov EA, Vislovskii VP, Sheinin VE, Appl. Catal. A: Gen., 83, 103 (1992)
Shin CH, Chang TS, Cho DH, Lee DK, Lee YK, HWAHAK KONGHAK, 35(2), 270 (1997)
Shin CH, Chang TS, Cho DH, Lee DK, Lee YK, HWAHAK KONGHAK, 35(4), 490 (1997)
Shin CH, Chang TS, Cho DH, Lee DK, Lee YK, J. Korean Ind. Eng. Chem., 8(5), 749 (1997)
Srinvias N, Kishan RM, Kulkarni SJ, Raghavan KV, Microporous Mesoporous Mater., 39, 125 (2000)
Suvorov BV, Int. Chem. Eng., 8, 588 (1968)
