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In relation to this article, we declare that there is no conflict of interest.
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Received June 12, 2003
Accepted August 1, 2003
articles This is an Open-Access article distributed under the terms of the Creative Commons Attribution Non-Commercial License (http://creativecommons.org/licenses/bync/3.0) which permits unrestricted non-commercial use, distribution, and reproduction in any medium, provided the original work is properly cited.
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Effects of Adding B2O3 as a Flux on Phosphorescent Properties in Synthesis of SrAl2O4 : (Eu2+, Dy3+) Phosphor

Minerals and Materials Processing Division, Korea Institute of Geoscience and Mineral Resources, 30 Gajeong, Yuseong, Daejeon 305-350, Korea
Korean Journal of Chemical Engineering, September 2003, 20(5), 973-976(4), 10.1007/BF02697308
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Abstract

SrAl2O4 : (Eu2+, Dy3+) phosphor was prepared by solid state reaction. B2O5 as a flux was added in SrAl2O4 : (Eu2+, Dy3+) in order to accelerate a solid state reaction. In this paper, the effects of B2O3 on the crystal structure and the phosphorescent properties of the material have been evaluated. The synthesized phosphor exhibited a broad band emission spectrum peaking at 520 nm, and the spectrum peak showed little effect by the B2O3 contents. The maximum afterglow intensity of the SrAl2O4 : (Eu2+, Dy3+) phosphor was obtained at the B2O3 content of 5%. Adding the B2O3 caused uniform distortion to the crystal structure of the phosphor and resulted in reducing the lengths of a and c axes and β angle of the SrAl2O4 crystal. The uniform distortion was accompanied with crystal defects which can trap the holes generated by the excitation of Eu2+ ions. The afterglow characteristic of the SrAl2O4 : (Eu2+, Dy3+) phosphor was thus enhanced.

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