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Received September 30, 2003
Accepted December 5, 2003
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Synthesis, Characterization, and Applications of Organic-Inorganic Hybrid Mesoporous Silica
School of Chemical Science and Engineering, Inha University, Incheon 402-751, Korea 1School of Chemistry, Inha University, Incheon 402-751, Korea
whasahn@inha.ac.kr
Korean Journal of Chemical Engineering, January 2004, 21(1), 132-139(8), 10.1007/BF02705391
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Abstract
Organic-inorganic hybrid mesoporous materials composed of homogeneously distributed ethane group in a silica framework were prepared by using 1,2 bis(trimethoxysilyl) ethane (BTME) as a precursor and alkyltrimethylammonium-chloride or -bromide surfactant as a structure directing agent with or without the presence of a swelling agent, mesitylene. Characterization of the materials was performed by XRD, TEM/SEM, 29Si-/13C-solid state NMR, and N2-adsorption. Testing of the hybrid material as a reversed phase HPLC column stationary phase after C18 surfacefunctionalization demonstrated a promising result, which closely approaches the performance of a commercial product. Mn-salen complex tethering on the hybrid material produced a catalyst with somewhat enhanced performance in liquid phase etherification with tert-butyl hydroperoxide as oxidant.
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Macquarrie DJ, Chem. Commun., 1961 (1996)
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Zhu H, Jones DJ, Zajac J, Dutartre R, Rhomari M, Roziere J, Chem. Mater., 14, 4886 (2002)
