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Received September 26, 2003
Accepted December 29, 2003
- This is an Open-Access article distributed under the terms of the Creative Commons Attribution Non-Commercial License (http://creativecommons.org/licenses/bync/3.0) which permits unrestricted non-commercial use, distribution, and reproduction in any medium, provided the original work is properly cited.
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Thermal and Chemical Desulfurization of Low Sulfur Coals
Department of Chemical and Envionmental Engineering, Soongsil University, Seoul 156-743, Korea
Korean Journal of Chemical Engineering, March 2004, 21(2), 370-377(8), 10.1007/BF02705422
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Abstract
This paper describes desulfurization characteristics of low sulfur coals prior to combustion and optimum conditions of three different desulfurization processes. These processes include two thermal treatment processes (mild pyrolysis and air oxidation) and an H2O2 leaching process. Dual processes composed of thermal and leaching processes were also evaluated. Low sulfur coals employed were two imported bituminous coals and two domestic anthracite coals. The optimum reaction temperatures and times of the thermal processes were 500-550 ℃ and 15-20 minutes, respectively. The optimum condition for the leaching process was obtained when the experiment carried out for 60 min at 90 ℃ using 30% H2O2. The dual process showed the best sulfur removal efficiency as expected among the evaluated processes.
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Wheelock TD, "Coal Desulfurization, Chemical and Physical Methods," American Chemical Society (1977)
Yaman S, Kucukbayrak S, Fuel Process. Technol., 47(2), 195 (1996)
Borah D, Baruha MK, Fuel Process. Technol., 72, 83 (2001)
Borah D, Baruah MK, Haque I, Fuel, 80(4), 501 (2001)
Borah D, Baruha MK, Haque I, Fuel, 80, 1475 (2001)
Chen HK, Li BQ, Zhang BJ, Fuel, 79, 1627 (2000)
Friedman S, Warzinski RP, J. Eng. Power, 361 (1977)
Garcia-Labiano F, Adanez J, Hampartsoumian E, Wiliaams A, Fuel, 75, 585 (1996)
Garcia-Labiano F, Hampartsoumian E, Wiliaams A, Fuel, 74, 1072 (1995)
Juszczak A, Domka F, Kozlowski M, Wachowska H, Fuel, 74, 725 (1995)
Ibarra JV, Palacios JM, Gracai M, Gancedo JR, Fuel Process. Technol., 21, 63 (1989)
Karaca H, Ceylan K, Fuel Process. Technol., 50(1), 19 (1997)
Karr C, "Analytical Methods for Coal and Coal Products," Academic Press (1978)
Lin L, Khang SJ, Keener TC, Fuel Process. Technol., 53(1), 15 (1997)
Lolja SA, Fuel, 74, 1834 (1995)
Moran A, Aller A, Cara J, Martinez O, Encinas JP, Gomez E, Fuel Process. Technol., 52(1), 155 (1997)
Park KS, Ph.D. Dissertations, Soongsil Univ., Seoul, Korea (2003)
Ryu HW, Chang YK, Kim SD, HWAHAK KONGHAK, 31(3), 325 (1993)
Song YK, Lee KB, Lee HS, Rhee YW, Korean J. Chem. Eng., 17(6), 691 (2000)
Sydorovych Y, Yo E, Gaivanovych VI, Martynets EV, Fuel, 75, 78 (1996)
Wen CY, Lee ES, "Coal Conversion Technology," Addison-Wesley Publishing Company (1979)
Wheelock TD, "Coal Desulfurization, Chemical and Physical Methods," American Chemical Society (1977)
Yaman S, Kucukbayrak S, Fuel Process. Technol., 47(2), 195 (1996)