Articles & Issues
- Language
- English
- Conflict of Interest
- In relation to this article, we declare that there is no conflict of interest.
- Publication history
-
Received February 20, 2003
Accepted November 7, 2003
-
This is an Open-Access article distributed under the terms of the Creative Commons Attribution Non-Commercial License (http://creativecommons.org/licenses/bync/3.0) which permits
unrestricted non-commercial use, distribution, and reproduction in any medium, provided the original work is properly cited.
Copyright © KIChE. All rights reserved.
All issues
Interaction of β-Cyclodextrin with Lipophilic Ring Compounds Deposited in a Sandy Soil Matrix during Flushing
Department of Environmental Engineering, Division of Materials and Chemical Engineering, Soonchunhyang University, Asan, Chungnam 336-745, Korea
daechul@sch.ac.kr
Korean Journal of Chemical Engineering, March 2004, 21(2), 389-397(9), 10.1007/BF02705426
Download PDF
Abstract
Chemical soil flushing in a packed sandy soil matrix using a natural surfactant, β-cyclodextrin (CD) was investigated via a fluorescence spectroscopy and a dye labeling. The contaminants are lipophilic ring compounds -phenanthrene and naphthalene. Sand type and flushing intensity (rate and concentration) are critical investigation variables. The removal efficiencies were proportional to flow rate, concentration, temperature of the flushing solution and voidity of the sand column. Initial sorption of the surfactant onto the soil matrix was found to be a key step while flow shear was more crucial in the later steps. From time delay experiments before flushing, we speculate that the complexation reaction appears to be rate-limiting in non-equilibrium washing schemes.
References
Abdul AS, Gibson TL, Ang CC, Smith JC, Sobczynski RE, Ground Water, 30(2), 219 (1992)
Brusseau ML, Wang X, Hu Q, Environ. Sci. Technol., 28, 952 (1994)
Carroll BJ, J. Colloid Interface Sci., 79(1), 126 (1981)
Chan AF, Evans DF, Cussler EL, AIChE J., 22, 1006 (1976)
Cho D, Kim HS, Korean J. Chem. Eng., 19(5), 783 (2002)
Cho D, Narsimhan G, Franses EI, Langmuir, 13(17), 4710 (1997)
Evans DF, Wennerstrom H, "The Colloidal Domain," VCH Publishers, Inc., NY (1994)
Fountain JC, Starr RC, Middleton T, Beikirch M, Taylor C, Hodge D, Ground Water, 34(5), 910 (1996)
Friberg SE, Mortensen M, Sep. Sci. Technol., 20(4), 285 (1985)
Hong JK, Youm KH, Membr. J., 8(3), 170 (1998)
Imhoff PT, Gleyzer SN, McBride JF, Vancho LA, Okuda I, Miller CT, Environ. Sci. Technol., 29(8), 1966 (1995)
Ko SO, Schlautman MA, Carraway ER, Environ. Sci. Technol., 33(16), 2765 (1999)
Ko SO, J. Korean Soc. Environ. Eng., 21(8), 1537 (1999)
Kobayashi K, Kajikawa K, Sasabe H, Knoll W, Thin Solid Films, 349(1-2), 244 (1999)
Lejeune A, Sakaguchi K, Imanaka T, Anal. Biochem., 181, 6 (1989)
Lee JK, Kim BU, Park D, Korean J. Chem. Eng., 16(5), 684 (1999)
McCray JE, Brusseau ML, Environ. Sci. Technol., 33(1), 89 (1999)
Park JA, Hur JM, Son BS, Lee JH, Korean J. Chem. Eng., 18(4), 486 (2001)
Pennell KD, Jin M, Abriola LM, Pope GA, J. Contam. Hydrol., 16(1), 35 (1994)
Pennell Kd, Abriola LM, Weber WJ, Environ. Sci. Technol., 27(12), 2332 (1993)
Rao PSC, Annable MD, Sillan RK, Dai D, Hatfield KH, Graham WD, Wood AL, Enfield CG, Water Resour. Res., 33(12), 2673 (1997)
Shiau BJ, Sabatini DA, Harwell JH, Vu DQ, Environ. Sci. Technol., 30(1), 91 (1996)
Szejtli J, "Cyclodextrin Technology," Kluwer Academic Publishers, Netherland (1988)
Wang X, Brusseau ML, Environ. Sci. Technol., 27, 2821 (1993)
Wang X, Brusseau ML, Environ. Sci. Technol., 29, 2346 (1995)
Wang X, Brusseau ML, Environ. Sci. Technol., 29, 2632 (1995)
West CC, Harwell JF, Environ. Sci. Technol., 26(12), 2324 (1992)
Brusseau ML, Wang X, Hu Q, Environ. Sci. Technol., 28, 952 (1994)
Carroll BJ, J. Colloid Interface Sci., 79(1), 126 (1981)
Chan AF, Evans DF, Cussler EL, AIChE J., 22, 1006 (1976)
Cho D, Kim HS, Korean J. Chem. Eng., 19(5), 783 (2002)
Cho D, Narsimhan G, Franses EI, Langmuir, 13(17), 4710 (1997)
Evans DF, Wennerstrom H, "The Colloidal Domain," VCH Publishers, Inc., NY (1994)
Fountain JC, Starr RC, Middleton T, Beikirch M, Taylor C, Hodge D, Ground Water, 34(5), 910 (1996)
Friberg SE, Mortensen M, Sep. Sci. Technol., 20(4), 285 (1985)
Hong JK, Youm KH, Membr. J., 8(3), 170 (1998)
Imhoff PT, Gleyzer SN, McBride JF, Vancho LA, Okuda I, Miller CT, Environ. Sci. Technol., 29(8), 1966 (1995)
Ko SO, Schlautman MA, Carraway ER, Environ. Sci. Technol., 33(16), 2765 (1999)
Ko SO, J. Korean Soc. Environ. Eng., 21(8), 1537 (1999)
Kobayashi K, Kajikawa K, Sasabe H, Knoll W, Thin Solid Films, 349(1-2), 244 (1999)
Lejeune A, Sakaguchi K, Imanaka T, Anal. Biochem., 181, 6 (1989)
Lee JK, Kim BU, Park D, Korean J. Chem. Eng., 16(5), 684 (1999)
McCray JE, Brusseau ML, Environ. Sci. Technol., 33(1), 89 (1999)
Park JA, Hur JM, Son BS, Lee JH, Korean J. Chem. Eng., 18(4), 486 (2001)
Pennell KD, Jin M, Abriola LM, Pope GA, J. Contam. Hydrol., 16(1), 35 (1994)
Pennell Kd, Abriola LM, Weber WJ, Environ. Sci. Technol., 27(12), 2332 (1993)
Rao PSC, Annable MD, Sillan RK, Dai D, Hatfield KH, Graham WD, Wood AL, Enfield CG, Water Resour. Res., 33(12), 2673 (1997)
Shiau BJ, Sabatini DA, Harwell JH, Vu DQ, Environ. Sci. Technol., 30(1), 91 (1996)
Szejtli J, "Cyclodextrin Technology," Kluwer Academic Publishers, Netherland (1988)
Wang X, Brusseau ML, Environ. Sci. Technol., 27, 2821 (1993)
Wang X, Brusseau ML, Environ. Sci. Technol., 29, 2346 (1995)
Wang X, Brusseau ML, Environ. Sci. Technol., 29, 2632 (1995)
West CC, Harwell JF, Environ. Sci. Technol., 26(12), 2324 (1992)
