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Received February 2, 2004
Accepted April 21, 2004
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Preparation and Characterization of Immobilized Ion Exchange Polyurethanes (IEPU) and Their Applications for Continuous Electrodeionization (CEDI)
Department of Environmental Science and Engineering, Gwangju Institute of Science & Technology (GIST), 1 Oryong-dong, Buk-gu, Gwangju 500-712, Korea
shmoon@gist.ac.kr
Korean Journal of Chemical Engineering, July 2004, 21(4), 867-873(7), 10.1007/BF02705532
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Abstract
Immobilized ion-exchange polyurethanes (IEPU) were prepared as ion conducting spacers in continuous electrodeionization (CEDI) for the treatment of a synthetic primary coolant. Ion exchange resins were immobilized by using allophanate/biuret cross-linking in preparation of polyurethane. Synthesized IEPU was characterized in terms of mechanical strength, ion exchange capacity (IEC), electrical conductivity and the porous plug model, which schematically represents the transport pattern through the IEPU. CEDI was carried out in a laboratory scale with an effective area of 20 cm2. The CEDI operation with a layered bed configuration showed the main removal mechanism of cobalt ion was dependent on the active surface area between ion conducting materials. The performance of the CEDI operation showed over 98% removal of cobalt ions, suggesting the feasibility of IEPU as ion conducting spacers in a CEDI system.
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References
Battacharya AK, Venkobachar C, J. Environ. Eng. Division, 110, 110 (1984)
Choi KH, Jeoung TY, Korean J. Chem. Eng., 19(1), 107 (2002)
Ganzi GC, Egozy Y, Giuffrida AJ, Ultrapure Water, Apr., 43 (1987)
Ganzi GC, Wood JH, Griffin CS, Environ. Prog., 11(1), 49 (1992)
Giuffrida AJ, Iha AD, Ganzi GC, U.S. Patent, 4,632,745 (1986)
Giuffrida AJ, Iha AD, Ganzi GC, U.S. Patent, 4,925,541 (1990)
Goffin C, Calay JC, Desalination, 132(1-3), 249 (2000)
Helfferich F, "Ion Exchange," McGraw-Hill Book Company, The United States of America, 489 (1962)
Hernon BP, Zanapalidou RH, Zhang L, Sims KJ, Siwak LR, Ultrapure Water, July, 33 (1994)
Kim IH, HWAHAK KONGHAK, 33(4), 471 (1995)
Kim YS, Kwon OJ, Kim EH, Myung SW, Choi HS, HWAHAK KONGHAK, 41(2), 224 (2003)
Korngold E, Aronov L, Kedem O, J. Membr. Sci., 138(2), 165 (1998)
Laktionov E, Dejean E, Sandeaux J, Sandeaux R, Gavach C, Pourcelly G, Sep. Sci. Technol., 34(1), 69 (1999)
Lee HJ, Park JS, Kang MS, Moon SH, Korean J. Chem. Eng., 20(5), 889 (2003)
Lee HJ, Park JS, Moon SH, Korean J. Chem. Eng., 19(5), 880 (2002)
Lee JW, Master Thesis, Dept. of Materials Science & Engineering, Kwangju Institute of Science & Technology, South Korea (2001)
Mulder M, "Basic Principles of Membrane Technology," Kluwer Academic Publishers: Netherlands, 210 (1996)
Namasivayam C, Renganathan K, Water Res., 29, 1737 (1995)
Rengaraj S, Moon SH, Water Res., 36(7), 1783 (2002)
Thate S, Specogna N, Eigenberger G, Ultrapure Water, Oct., 42 (1999)
Walters WR, Weiser DW, Marek LJ, Ind. Eng. Chem., 47(1), 61 (1955)
Winston HWS, Sirkar KK, "Membrane Handbook," Van Nostrand Reinhold, New York, 506 (1992)
Wyllie MRJ, Sauer MC, Southwick PF, Spiegler KS, Ind. Eng. Chem., 47, 2187 (1955)
Yeon KH, Lee JW, Lee JS, Moon SH, J. Appl. Polym. Sci., 86(7), 1773 (2002)
Yeon KH, Moon SH, Sep. Sci. Technol., 38, 2347 (2003)
Yeon KH, Seong JH, Rengaraj S, Moon SH, Sep. Sci. Technol., 38(2), 443 (2003)
Yeon KH, Song JH, Moon SH, Water Res., 38(7), 1911 (2004)
Yim TJ, Kim SY, Yoo KP, Korean J. Chem. Eng., 19(1), 159 (2002)
Choi KH, Jeoung TY, Korean J. Chem. Eng., 19(1), 107 (2002)
Ganzi GC, Egozy Y, Giuffrida AJ, Ultrapure Water, Apr., 43 (1987)
Ganzi GC, Wood JH, Griffin CS, Environ. Prog., 11(1), 49 (1992)
Giuffrida AJ, Iha AD, Ganzi GC, U.S. Patent, 4,632,745 (1986)
Giuffrida AJ, Iha AD, Ganzi GC, U.S. Patent, 4,925,541 (1990)
Goffin C, Calay JC, Desalination, 132(1-3), 249 (2000)
Helfferich F, "Ion Exchange," McGraw-Hill Book Company, The United States of America, 489 (1962)
Hernon BP, Zanapalidou RH, Zhang L, Sims KJ, Siwak LR, Ultrapure Water, July, 33 (1994)
Kim IH, HWAHAK KONGHAK, 33(4), 471 (1995)
Kim YS, Kwon OJ, Kim EH, Myung SW, Choi HS, HWAHAK KONGHAK, 41(2), 224 (2003)
Korngold E, Aronov L, Kedem O, J. Membr. Sci., 138(2), 165 (1998)
Laktionov E, Dejean E, Sandeaux J, Sandeaux R, Gavach C, Pourcelly G, Sep. Sci. Technol., 34(1), 69 (1999)
Lee HJ, Park JS, Kang MS, Moon SH, Korean J. Chem. Eng., 20(5), 889 (2003)
Lee HJ, Park JS, Moon SH, Korean J. Chem. Eng., 19(5), 880 (2002)
Lee JW, Master Thesis, Dept. of Materials Science & Engineering, Kwangju Institute of Science & Technology, South Korea (2001)
Mulder M, "Basic Principles of Membrane Technology," Kluwer Academic Publishers: Netherlands, 210 (1996)
Namasivayam C, Renganathan K, Water Res., 29, 1737 (1995)
Rengaraj S, Moon SH, Water Res., 36(7), 1783 (2002)
Thate S, Specogna N, Eigenberger G, Ultrapure Water, Oct., 42 (1999)
Walters WR, Weiser DW, Marek LJ, Ind. Eng. Chem., 47(1), 61 (1955)
Winston HWS, Sirkar KK, "Membrane Handbook," Van Nostrand Reinhold, New York, 506 (1992)
Wyllie MRJ, Sauer MC, Southwick PF, Spiegler KS, Ind. Eng. Chem., 47, 2187 (1955)
Yeon KH, Lee JW, Lee JS, Moon SH, J. Appl. Polym. Sci., 86(7), 1773 (2002)
Yeon KH, Moon SH, Sep. Sci. Technol., 38, 2347 (2003)
Yeon KH, Seong JH, Rengaraj S, Moon SH, Sep. Sci. Technol., 38(2), 443 (2003)
Yeon KH, Song JH, Moon SH, Water Res., 38(7), 1911 (2004)
Yim TJ, Kim SY, Yoo KP, Korean J. Chem. Eng., 19(1), 159 (2002)
