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Received March 10, 2004
Accepted June 24, 2004
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Effect of Powdered Activated Carbon Type on the Performance of an Adsorption-Microfiltration Submerged Hollow Fiber Membrane Hybrid System
Faculty of Applied Chemistry, Chonnam National University, Gwangju 500-757, Korea 1Department of Chemical Engineering, Seonam University, Namwon 590-711, Korea
hmoon@chonnam.ac.kr
Korean Journal of Chemical Engineering, September 2004, 21(5), 1044-1052(9), 10.1007/BF02705591
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Abstract
This study highlights the importance of the type of powdered activated carbon (PAC) on the performance of an adsorption-MF hollow fiber membrane hybrid system. Submerged UF hollow fiber membrane with pore size of 0.4 μm was used along with the PAC in a single reaction thank to treat the wastewater. This procedure is different from the commonly adopted practice of having adsorption with PAC as a pretreatment step to membrane operation. This system is helpful in containing the PAC within one system, allows certain vaiation in feed characteristics and improves the effciency of the hybrid system. The overall performance of the membrane hybrid system was evaluted based on TOC removal, UV254 absorbance, turbidity removal and flux development. It is important to select a right PAC type to be used in the hybrid system in order to minimize the PAC dose and to enhance the performance. The adsorption capacity of the activated carbon had a greater influence on overall performance of the hybrid system than other physical properties of the PACs and must be given greater consideration when selecting the PAC for the membrane hybrid system. Scanning electron micrograph (SEM) analysis of the cake deposit over the membrane helps to support the reason for moderate retention of organics.
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Kim IH, Chang HN, Korean J. Chem. Eng., 1(1), 21 (1984)
Kim JS, Lee SJ, Yoon SH, Lee CH, Water Sci. Technol., 34, 223 (1996)
Konieczny K, Klomfas G, Desalination, 147(1-3), 109 (2002)
Laine JM, Hagstrom JP, Clark MM, Mallevialle J, J. AWWA, 81, 61 (1989)
Laine JM, Vial D, Moulart P, Desalination, 131(1-3), 17 (2000)
Lin CF, Liu SH, Hao OJ, Water Res., 35, 2395 (2001)
Lin CF, Huang YJ, Hao OJ, Water Res., 33, 1252 (1999)
McKay G, "Use of Adsorbents for the Removal of Pollutants from Wastewater," CRC Press, Ind., USA (1996)
Nystrom M, Ruohomaki K, Kaipia L, Desalination, 106, 79 (1996)
Schafer A, "Natural Organics Removal Using Membranes," Doctoral Dissertation, University of New South Wales, Australia (1999)
Thiruvenkatachari R, Shim WG, Lee JW, Moon H, "Application of Membrane Hybrid System for the Treatment of Domestic Wastewater in South Korea," Water Environment-Membrane Technology [WEMT2004], IWA Specialty Conference, Korea, 1199 (2004)
Tien C, "Adsorption Calculations and Modelling," Butterworth-Heinemann Publishers, USA (1994)
Tomaszewska M, Mozia S, Water Res., 36, 4137 (2002)
Turcaud LV, Wiesner MR, Bottero JY, J. Membr. Sci., 52, 173 (1990)
Vickers JC, Thompson MA, Kelkar UG, Desalination, 102, 57 (1995)
Wiesner MR, Hackney J, Sethi S, Jacangelo JG, Laine JM, J. AWWA, 86, 33 (1994)
Yiantsios SG, Karabelas A, Desalination, 140(2), 195 (2001)