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Received June 28, 2004
Accepted November 8, 2004
- This is an Open-Access article distributed under the terms of the Creative Commons Attribution Non-Commercial License (http://creativecommons.org/licenses/bync/3.0) which permits unrestricted non-commercial use, distribution, and reproduction in any medium, provided the original work is properly cited.
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Numerical Methodology for Proton Exchange Membrane Fuel Cell Simulation using Computational Fluid Dynamics Technique
Department of Chemical Engineering, Hanyang University, Seoul 133-791, Korea
Korean Journal of Chemical Engineering, November 2004, 21(6), 1153-1160(8), 10.1007/BF02719487
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Abstract
To analyze the physical phenomena occurring in the Proton Exchange Membrane Fuel Cell (PEMFC) using Computational Fluid Dynamics (CFD) technique under an isothermal operating condition, four major governing equations such as continuity equation, momentum conservation equation, species transport equation and charge conservation equation should be solved. Among these governing equations, using the interfacial boundary condition is necessary for solving the water transport equation properly since the concept of water concentration in membrane/electrode assembly (MEA) and other regions is totally different. It was first attempted to solve the water transport equation directly in the MEA region by using interfacial boundary condition; and physically-meaningful data such as water content, proton conductivity, etc. were successfully obtained. A detailed problem-solving methodology for PEMFC is presented and result comparison with experimental data is also implemented in this paper.
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Bird RB, Stewart WE, Lightfoot EN, "Transport Phenomena," John Wiley & Sons, Inc. (1960)
Carrette L, Friedrich KA, Stimming U, FUEL CELLS, 1, 5 (2001)
Carrette L, ChemphysChem, 1, 162 (2000)
Center for Fuel Cell Research at USC : http://www.che.sc.edu/centers/PEMFC
CFD Online : http://www.cfd-onlife.com
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Davis CW, "A Dictionary of Electrochemistry," THE MACMILLAN PRESS Ltd. (1976)
DuPont's Web Site : http://www.dupont.com
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Electrochemical Engine Center at Penn State University : http://mtrl1.me.psu.edu
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Himmelblau DM, "Basic Principles and Calculations in Chemical Engineering," Prentice-Hall International, Inc. (1996)
IESVic Integrated Energy Systems : http://www.iesvic.uvic.ca
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Kordesch K, Simader G, "Fuel Cells and Their Applications," VCH (1996)
Korea Fuel Cell Community : http://www.freechal.com/fuelcell
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Springer TE, Zawodzinski TA, Gottesfeld S, J. Electrochem. Soc., 138(8), 2334 (1991)
Srinivasan S, Manko DJ, Koch H, Enayetullah MA, Appleby AJ, J. Power Sources, 29, 367 (1990)
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Gu WB, Wang CY, Liaw BY, J. Electrochem. Soc., 145(10), 3418 (1998)
Weber AZ, Newman J, J. Electrochem. Soc., 150(7), A1008 (2003)
White RE, Lorimer SE, Darby R, J. Electrochem. Soc., 130, 1123 (1983)