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Received May 21, 2004
Accepted September 30, 2004
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Mass Transfer of Carbon Dioxide in Aqueous Polyacrylamide Solution with Methyldiethanolamine
Division of Chemical Engineering, Pusan National University, Busan 609-735, Korea 1School of Environmental Science, Catholic University of Pusan, Busan 609-757, Korea 2Department of Chemical Engineering, Sogang University, Seoul 121-742, Korea
swpark@pusan.ac.kr
Korean Journal of Chemical Engineering, November 2004, 21(6), 1205-1211(7), 10.1007/BF02719495
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Abstract
Carbon dioxide was absorbed into aqueous polyacrylamide (PAA) solution containing methyl-diethanolamine (MDEA) in a flat-stirred vessel to investigate the effect of non-Newtonian rheological behavior of PAA on the rate of chemical absorption of CO2, where the reaction between CO2 and MDEA was assumed to be a first-order reaction with respect to the molar concentration of CO2 and MDEA, respectively. The liquid-side mass transfer coefficient (kL), which was obtained from the dimensionless empirical equation containing the viscoelasticity properties of a non-Newtonian liquid, was used to estimate the enhancement factor due to chemical reaction. PAA with elastic property of non-Newtonian liquid made the rate of chemical absorption of CO2 accelerate compared with a Newtonian liquid.
References
Danckwerts PV, Sharma MM, Chem. Eng., 44, 244 (1966)
Higbie R, Trans. Am. Inst. Chem. Eng., 31, 365 (1935)
Hikita H, Asai S, Takatsuka T, Chem. Eng. J., 11, 131 (1976)
Kennard ML, Meisen A, J. Chem. Eng. Data, 29, 309 (1984)
Ko JJ, Li MH, Chem. Eng. Sci., 55(19), 4139 (2000)
Lohse M, Quicker G, Deckwer DW, AIChE J., 27(4), 626 (1981)
Metzner AB, Otter RE, AIChE J., 3, 3 (1957)
Nakanoh M, Yoshida F, Ind. Eng. Chem. Process Des. Dev., 19(1), 190 (1980)
Nijing RATO, Hendriksz RH, Kramers H, Chem. Eng. Sci., 10, 88 (1959)
Park SW, Sohn IJ, Park DW, Oh KJ, Sep. Sci. Technol., 38(6), 1361 (2003)
Park SW, Sohn IJ, Sohn SG, Kumazawa H, Sep. Sci. Technol., 38(6), 3983 (2003)
Park SW, Sohn IJ, "Absorption of Carbon Dioxide into NonNewtonian Liquid. III. Effect of Chemical Reaction," Sep. Sci. Technol. in press (2004)
Ranade VR, Ulbrecht JJ, AIChE J., 24(5), 796 (1978)
Sandall OC, Patel KG, Ind. Eng. Chem. Process Des. Dev., 9(1), 139 (1970)
Yagi H, Yoshida F, Ind. Eng. Chem. Process Des. Dev., 14(4), 488 (1975)
Higbie R, Trans. Am. Inst. Chem. Eng., 31, 365 (1935)
Hikita H, Asai S, Takatsuka T, Chem. Eng. J., 11, 131 (1976)
Kennard ML, Meisen A, J. Chem. Eng. Data, 29, 309 (1984)
Ko JJ, Li MH, Chem. Eng. Sci., 55(19), 4139 (2000)
Lohse M, Quicker G, Deckwer DW, AIChE J., 27(4), 626 (1981)
Metzner AB, Otter RE, AIChE J., 3, 3 (1957)
Nakanoh M, Yoshida F, Ind. Eng. Chem. Process Des. Dev., 19(1), 190 (1980)
Nijing RATO, Hendriksz RH, Kramers H, Chem. Eng. Sci., 10, 88 (1959)
Park SW, Sohn IJ, Park DW, Oh KJ, Sep. Sci. Technol., 38(6), 1361 (2003)
Park SW, Sohn IJ, Sohn SG, Kumazawa H, Sep. Sci. Technol., 38(6), 3983 (2003)
Park SW, Sohn IJ, "Absorption of Carbon Dioxide into NonNewtonian Liquid. III. Effect of Chemical Reaction," Sep. Sci. Technol. in press (2004)
Ranade VR, Ulbrecht JJ, AIChE J., 24(5), 796 (1978)
Sandall OC, Patel KG, Ind. Eng. Chem. Process Des. Dev., 9(1), 139 (1970)
Yagi H, Yoshida F, Ind. Eng. Chem. Process Des. Dev., 14(4), 488 (1975)
