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Received September 2, 2004
Accepted November 15, 2004
- This is an Open-Access article distributed under the terms of the Creative Commons Attribution Non-Commercial License (http://creativecommons.org/licenses/bync/3.0) which permits unrestricted non-commercial use, distribution, and reproduction in any medium, provided the original work is properly cited.
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Multi-component Ion Exchange Kinetics with PAN-KCoFC Composite Ion Exchanger
Korea Atomic Energy Research Institute, Korea 1Dept. of Chemical Engineering, Hannam University, Daejeon 306-010, Korea 2Korean Research Institute of Chemical Technology, Daejeon 305-761, Korea
njkmoon@kaeri.re.kr
Korean Journal of Chemical Engineering, January 2005, 22(1), 127-132(6), 10.1007/BF02701474
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Abstract
An ion exchange kinetic study was performed using PAN-KCoFC for removal of cesium ion from mixed solution of Cs, Sr, Ni and Ba ions. Uptake curves were obtained for a multi-component ion exchange system as well as binary system. A PAN-KCoFC composite ion exchanger showed higher selectivity for Cs ion over the Sr, Ba, Ni ions. A homogeneous model could predict accurately the uptake curve for both the binary and multi-component systems. Solid phase effective pore diffusivities obtained by modeling ranged between 10-5 cm2/min and 10-6 cm2/min.
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John J, Sebesta F, Motl A, Radiochim. Acta, 78, 131 (1997)
Kim HT, Lee CH, Shul YG, Mon JK, Lee EH, Sep. Sci. Technol., 38(3), 695 (2003)
Kim HT, Shul YG, Moon JK, Jung CH, Lee EH, Czech. J. Phys., 53, 487 (2003)
Marageh MG, Husain SW, Khanchi AR, Appl. Radiat. Isot., 50, 459 (1999)
Mardan A, Rumana A, Mehmood A, Raza SM, Ghaffar A, Sep. Purif. Technol., 16, 147 (1999)
Mimura H, Lehto J, Harjula R, J. Nucl. Sci. Technol., 34(5), 484 (1997)
Mimura H, Letho J, Harjula R, J. Nucl. Sci. Technol., 34(6), 582 (1997)
Moon JK, Lee EH, Kim HT, Korean J. Chem. Eng., 21 (2004)
Moon JK, Kim KW, Jung CH, Lee EH, Shul YG, J. Radioanal. Nucl. Chem., 246(2), 299 (2000)
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Rao SVS, Lal KB, Narasimhan SV, Ahmed J, J. Radioanal. Nucl. Chem., 240(1), 269 (1999)
Rice RG, Do DD, Applied Mathematics and Modeling for Chemical Engineers, John Wiley & Sons, New York (1995)
Robinson SM, Arnold WD, Byers CH, AIChE J., 40(12), 2045 (1994)
Ruthven DM, Loughlin KF, Can. J. Chem. Eng., 50, 550 (1972)
Ruthven DM, Principle of Adsorption and Adsorption Processes, Wiley, New York (1984)
Sebesta F, John J, "An Overview of the Development, Testing, and Application of Composite Absorbers", LA-12875-MS (1995)
Sinha PK, Panicker PK, Amalraj RV, Krishnasamy V, Waste Manage., 15(2), 149 (1995)
Sinha PK, Lal KB, Panicker PK, Amalraj RV, Krishnasamy V, Ind. J. Chem., 33A, 924 (1994)
Tarasevich YI, Kardasheva MV, Polyakov VE, Colloid J., 59(6), 754 (1997)
Villadsen J, Michelsen ML, Solution of Differential Equation Models by Polynomial Approximation, Prentice-Hall, Englewood Cliff, NJ (1978)