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Received April 21, 2004
Accepted November 16, 2004
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Adsorption of Heavy Metals by Brewery Biomass
Department of Environmental Engineering, Chonnam National University, 300 Yongbong-dong, Buk-ku, Gwang-ju 500-757, Korea 1Jeollanam-Do Institute of Health and Environment, Nongseong 2-dong, Seo-ku, Gwang-ju 502-202, Korea 2Department of Chemical Engineering, Chungnam National University, Daejeon 305-764, Korea 3Department of Chemical Engineering, Korea Advanced Institute of Science and Technology, Daejeon 305-701, Korea
sjkim@chonnam.ac.kr
Korean Journal of Chemical Engineering, January 2005, 22(1), 91-98(8), 10.1007/BF02701468
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Abstract
In this work, biosorption of lead, copper and cadmium by waste brewery yeast has been studied. The adsorption capacity for lead, copper and cadmium on the biomass increased with the increasing temperature and the maximum uptakes were 0.465 mmolPb/g (96.4 mg/g), 0.769 mmolCu/g (48.9 mg/g) and 0.127 mmolCd/g (14.3 mg/g) at 308 K. The Langmuir isotherm, favorable type, and the pseudo second-order kinetic model represent our experimental data very well. The heat of biosorption was evaluated from the Langmuir isotherm equation, and the biosorption of lead, copper and cadmium was endothermic reaction.
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Esposito A, Pagnanelli F, Veglio F, Chem. Eng. Sci., 57(3), 307 (2002)
Ho YS, McKay G, Chem. Eng. J., 70(2), 115 (1998)
Jeon C, Park JY, Yoo YJ, Korean J. Chem. Eng., 18(6), 955 (2001)
Jianlon W, Process Biochem., 37, 847 (2002)
Kapoor A, Viraraghavan T, Bioresour. Technol., 53(3), 195 (1995)
Lagergren S, Handlingar, 24, 1 (1898)
Lee HS, Suh JH, Korean J. Chem. Eng., 17(4), 477 (2000)
Low KS, Lee CK, Liew SC, Process Biochem., 36, 59 (2000)
Marques PA, Pinheiro HM, Teixeira JA, Rosa MF, Desalination, 124(1-3), 137 (1999)
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Sag Y, Kutsal T, Biotechnol. Bioprocess Eng., 6, 376 (2001)
Smith JM, Chemical Engineering Kinetic, 3rd Edition., McGraw-Hill, New-York (1981)
Bai S, Abraham TE, Bioresour. Technol., 79(1), 73 (2001)
Veglio F, Beolchini F, Hydrometallurgy, 44, 301 (1997)
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Volesky B, Fems Microbiol. Rev., 14, 291 (1994)
Yan GY, Viraraghavan T, Bioresour. Technol., 78(3), 243 (2001)
Yang J, Volesky B, Environ. Sci. Technol., 33, 4079 (1999)
Yesim S, "Selection of the Best Biosorbent for Removal and Recovery of the Heavy Metal Ions from Wastewater and Mathematical Investigation of the Adsorption in the Different Reactor Systems", Ph.D. Thesis, Hacettepe University, Ankara, Turkey (1993)
Yu Q, Kaewsarn P, Korean J. Chem. Eng., 16(6), 753 (1999)