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Received October 26, 2004
Accepted December 23, 2004
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Studies on the Modeling Calculations of the Unit Molten Carbonate Fuel Cell
Department. of Chemical Engineering, Hong-Ik University, Mapoku, Seoul 121-791, Korea 1Korea Electric Power Research Institute (KEPRI), 103-16 Munjidong, Yuseonggu, Daejon 305-380, Korea 2Battery & Fuel Cell Research Center, Korea Institute of Science and Technology (KIST), P.O. Box 131 Cheongryang, Seoul 130-650, Korea
Korean Journal of Chemical Engineering, March 2005, 22(2), 219-227(9), 10.1007/BF02701488
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Abstract
One parameter should be fixed in the process of simulating the performance of a unit MCFC (molten carbonate fuel cell). Distributions of temperature, conversions of hydrogen, and cell performance have been obtained in two different methods: one with a fixed value of cell voltage and the other with a fixed value of current density. Results by both methods have been compared with experimental data. The method with the fixed value of cell voltage resulted in a more reasonable fitting to experimental data.
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Appleby AJ, Foulkes FR, Fuel Cell Hand Book, 539 (1989)
Bosio B, Costamagna P, Parodi F, Chem. Eng. Sci., 54(13-14), 2907 (1999)
Cao G, Masubuchi M, J. Jap. Mech. Eng. Soc.(B), 57, 837 (1991)
Kim MH, Chung GY, Nam SW, Oh IH, Lim TH, Hong SA, J. Energy Engg., 8(1), 7 (1999)
Kim MH, Park HK, Chung GY, Lim HC, Nam SW, Lim TH, Hong SA, J. Power Sources, 103(2), 245 (2002)
Kim TJ, Ahn YJ, Ju JB, Chung GY, Nam SW, Oh IH, Lim TH, Hong SA, J. Energy Engg., 4(3), 354 (1995)
Kobayashi N, Fujimura H, Ohtsuka K, J. Jap. Mech. Eng. Soc.(B), 54, 2568 (1988)
Kobayashi N, Fujimura H, Ohtsuka K, J. Jap. Mech. Eng. Soc. (B), 57, 825 (1991)
Koh JH, Kang BS, Lim HC, J. Power Sources, 91(2), 161 (2000)
Kunz HR, Murphy LA, J. Electrochem. Soc., 135(5), 1124 (1988)
Lee CG, Kang BS, Seo HK, Lim HC, J. Electroanal. Chem., 540, 169 (2003)
Lee YR, Kim IG, Chung GY, Lee CG, Lim HC, Lim TH, Nam SW, Hong SA, J. Power Sources, 137(1), 9 (2004)
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McCabe WL, Smith JC, Harriott P, Unit Operations of Chemical Engineering, McGraw-Hill, New York, 340 (2001)
Nam SW, Seo SH, Lim TH, Oh IH, Hong SA, Lim HC, Hydrogen Energy, 3, 55 (1992)
Park NK, Lee YR, Kim MH, Chung GY, Nam SW, Hong SA, Lim TH, Lim HC, J. Power Sources, 104(1), 140 (2002)
Sampath V, Sammels AF, J. Electrochem. Soc., 127, 79 (1980)
Smith JM, vanNess HC, Introduction to Chemical Engineering Thermodynamics, McGraw-Hill, New York, 698 (1987)
Wolf TL, Wilemski G, J. Electrochem. Soc., 130, 48 (1983)
Yuh CY, Selman JR, J. Electrochem. Soc., 131(9), 2062 (1984)