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Received November 3, 2004
Accepted January 4, 2005
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This is an Open-Access article distributed under the terms of the Creative Commons Attribution Non-Commercial License (http://creativecommons.org/licenses/bync/3.0) which permits
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New Method for the Preparation of Solid Polymer Electrolyte Based on Poly(vinylidene fluoride-co-hexafluoropropylene)
Department of Chemical Engineering, Sunchon National University, 315 Maegok, Suncheon, Jeonnam 540-742, Korea 1Department of Chemical and Bio Engineering, Kyungwon University, Sungnam 461-701, Korea
parkkp@sunchon.ac.kr
Korean Journal of Chemical Engineering, March 2005, 22(2), 234-237(4), 10.1007/BF02701490
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Abstract
A novel solid polymer electrolyte (pore-gel SPE) has been found to provide superior SPE having a high conductivity, good mechanical strength and low solution leakage. This pore-gel SPE was prepared from gelation in pores of polymer membrane with electrolyte solution including solvent. The conductivity of pore-gel type PVDF-HFP/TEABF4 (Tetraethylammomium tetrafluoroborate) membrane can reach 1.6×10.1 Scm.1. The tensile strength of this membrane was 4,000 kPa, which is about 23 times larger than that of gel-type SPE with the same composition. Poregel SPE reduced solution leakage to 0%, compared with 2% of hybrid-type SPE after 2.0 hr leakage test in PVDFHFP/TEABF4 membrane.
References
Armand MB, Chabagno JM, Duclot M, "Fast Ion Transport in Solids", Edited by Vashisha, P., Mundy, J. N. and Shenoy, G. K., New York, 131 (1979)
Bohnke O, Frand G, Rezrazzi M, Rousselot C, Truche C, Solid State Ion., 66, 105 (1993)
Boudin F, Andrieu X, Jehoulet C, Olsen II, J. Power Sources, 81-82, 804 (1999)
Christie AM, Christie L, Vincent CA, J. Power Sources, 74(1), 77 (1998)
Chung NK, Kwon YD, Kim D, J. Power Sources, 124(1), 148 (2003)
Fenton DE, Park JM, Wright PV, Polymer, 14, 589 (1973)
Kim KS, Shin BK, Lee H, Korean J. Chem. Eng., 21, 1011 (2004)
Murata K, Izuchi S, Yoshihisa Y, Electrochim. Acta, 45(8-9), 1501 (2000)
Osaka T, Liu XJ, Nojima M, Momma T, J. Electrochem. Soc., 146(5), 1724 (1999)
Saito Y, Stephan AM, Kataoka H, Solid State Ion., 160(1-2), 149 (2003)
Shi Q, Yu MX, Zhou X, Yan YS, Wan CR, J. Power Sources, 103(2), 286 (2002)
Stephan AM, Teeters D, Electrochim. Acta, 48(14-16), 2143 (2003)
Bohnke O, Frand G, Rezrazzi M, Rousselot C, Truche C, Solid State Ion., 66, 105 (1993)
Boudin F, Andrieu X, Jehoulet C, Olsen II, J. Power Sources, 81-82, 804 (1999)
Christie AM, Christie L, Vincent CA, J. Power Sources, 74(1), 77 (1998)
Chung NK, Kwon YD, Kim D, J. Power Sources, 124(1), 148 (2003)
Fenton DE, Park JM, Wright PV, Polymer, 14, 589 (1973)
Kim KS, Shin BK, Lee H, Korean J. Chem. Eng., 21, 1011 (2004)
Murata K, Izuchi S, Yoshihisa Y, Electrochim. Acta, 45(8-9), 1501 (2000)
Osaka T, Liu XJ, Nojima M, Momma T, J. Electrochem. Soc., 146(5), 1724 (1999)
Saito Y, Stephan AM, Kataoka H, Solid State Ion., 160(1-2), 149 (2003)
Shi Q, Yu MX, Zhou X, Yan YS, Wan CR, J. Power Sources, 103(2), 286 (2002)
Stephan AM, Teeters D, Electrochim. Acta, 48(14-16), 2143 (2003)
