Articles & Issues
- Language
- English
- Conflict of Interest
- In relation to this article, we declare that there is no conflict of interest.
- Publication history
-
Received December 23, 2004
Accepted April 1, 2005
- This is an Open-Access article distributed under the terms of the Creative Commons Attribution Non-Commercial License (http://creativecommons.org/licenses/bync/3.0) which permits unrestricted non-commercial use, distribution, and reproduction in any medium, provided the original work is properly cited.
Copyright © KIChE. All rights reserved.
All issues
Reactivity of Bio-sorbent Prepared by Waste Shells of Shellfish in Acid Gas Cleaning Reaction
Department of Environmental Engineering,, Sorabol College, Kyungju, Kyungbuk 78-711165 Chunghyo-dong, Korea 1Department of Environmental Engineering, Kwangwoon University, 447-1 Wolge-dong, Nowon-gu, Seoul 139-701, Korea 2Energy and Environmental Research Department, Korea Institute of Energy Research, 71-2 Jang-dong, Yuseong-gu, Daejeon 305-343, Korea 3Department of Environmental Engineering, Pusan National University, 30 Changjeon-dong, Kumjeong-gu, Busan 609-735, Korea 4Department of Environmental Engineering, Hanseo University, Haemi-myun, Seosan, Chungnam 356-820, Korea
bhshon@hanseo.ac.kr
Korean Journal of Chemical Engineering, July 2005, 22(4), 566-568(3), 10.1007/BF02706644
Download PDF
Abstract
Acid gas cleaning activity of bio-adsorbent prepared by waste shell of different shellfish species was investigated in a fixed bed reactor to evaluate its feasibility as an acid gas cleaning agent. The physicochemical properties of prepared adsorbents were measured using ICP, BET, SEM-EDX and XRD. The results showed that active chemical species of bio-sorbent are comparable to that of commercial limestone and lime. SO2/NOx removal capacity of waste shell of shellfish was higher than that of commercial limestone due to the enhanced physical properties. In particular, the desulfurization activity of clam based adsorbent was the best among the tested waste shells because of both higher calcium content and more specific surface area. These lead to the conclusion that commercial limestone can be substituted for bio-sorbent prepared by waste shell of clam.
Keywords
References
Chu KJ, Yoo KS, Kim KT, Mater. Res. Bull., 32(2), 197 (1997)
Garea A, Herrera JL, Marques JA, Irabien A, Chem. Eng. Sci., 56(4), 1387 (2001)
Jung JH, Shon BH, Yoo KS, Oh KJ, Korean J. Chem. Eng., 17(5), 585 (2000)
Karlsson HT, Klingspore J, Linne M, Bjerle I, J. Air Pollution Control Association, 33(1), 23 (1983)
Keener TC, Davis WT, J. Air Pollution Control Association, 34(6), 651 (1984)
Klingspor JS, J. Air Pollution Control Association, 37(7), 801 (1987)
Nakamura H, Ueno T, Tatani A, Kotake S, "Pilot-scale Test Results of Simultaneous SO2 and NOx Removal using Powdery form of LILAC Absorbent", 1995 SO2 Control Symposium, March, Florida, U.S.A (1995)
Odowd WJ, Markussen JM, Pennline HW, Resnik KP, Ind. Eng. Chem. Res., 33(11), 2749 (1994)
Ukawa N, Takashina T, Oshima M, Oishi T, Environ. Prog., 12(4), 294 (1993)
Yoo KS, Kim SD, Park SB, Ind. Eng. Chem. Res., 33(7), 1786 (1994)
Yoon GL, Kim BT, Kim BO, Han SH, “Chemical-Mechanical Characteristics of Crushed Oyster-shell,” Waste Management 23, available online(http://www.sciencedirect.com), (2003)
Yuan CS, “Simultaneous Collection of SO2 and NOx via Spray Drying: Using Sodium-based and Calcium-based Sorbents with Select Additives,” Ph.D. Dissertation, Illinois Univ., U.S.A. (1990)
Garea A, Herrera JL, Marques JA, Irabien A, Chem. Eng. Sci., 56(4), 1387 (2001)
Jung JH, Shon BH, Yoo KS, Oh KJ, Korean J. Chem. Eng., 17(5), 585 (2000)
Karlsson HT, Klingspore J, Linne M, Bjerle I, J. Air Pollution Control Association, 33(1), 23 (1983)
Keener TC, Davis WT, J. Air Pollution Control Association, 34(6), 651 (1984)
Klingspor JS, J. Air Pollution Control Association, 37(7), 801 (1987)
Nakamura H, Ueno T, Tatani A, Kotake S, "Pilot-scale Test Results of Simultaneous SO2 and NOx Removal using Powdery form of LILAC Absorbent", 1995 SO2 Control Symposium, March, Florida, U.S.A (1995)
Odowd WJ, Markussen JM, Pennline HW, Resnik KP, Ind. Eng. Chem. Res., 33(11), 2749 (1994)
Ukawa N, Takashina T, Oshima M, Oishi T, Environ. Prog., 12(4), 294 (1993)
Yoo KS, Kim SD, Park SB, Ind. Eng. Chem. Res., 33(7), 1786 (1994)
Yoon GL, Kim BT, Kim BO, Han SH, “Chemical-Mechanical Characteristics of Crushed Oyster-shell,” Waste Management 23, available online(http://www.sciencedirect.com), (2003)
Yuan CS, “Simultaneous Collection of SO2 and NOx via Spray Drying: Using Sodium-based and Calcium-based Sorbents with Select Additives,” Ph.D. Dissertation, Illinois Univ., U.S.A. (1990)