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Received April 26, 2005
Accepted July 4, 2005
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An Extension of the Group Contribution Method for Estimating Thermodynamic and Transport Properties. Part III. Noble Gases
Chemical and Biochemical Engineering Department, Kon-Yang University, San 26, Naedong, Nonsan, Chungnam 320-711, Korea
Korean Journal of Chemical Engineering, November 2005, 22(6), 949-959(11), 10.1007/BF02705681
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Abstract
Earlier work on the group contribution method applied to the Kihara potential is extended to noble gases for the estimation of second virial coefficients, dilute gas viscosities and diffusivities with a single set of gas group parameters. Group parameters are determined when second virial coefficient and viscosity data of pure gases are satisfactorily fitted within the experimental uncertainties. Parameters for gas groups (He, Ne, Ar, Kr and Xe) are found to provide good predictions of mixture properties: second virial cross coefficients, mixture viscosities, and binary diffusion coefficients. Application of the model shows that second virial coefficient data are represented with good results comparable to the values by means of the corresponding states correlation. The reliability of the present model in viscosity predictions is proved by comparison with the Lucas method. Prediction results of diffusivity are in excellent agreement with literature data and compare well with values obtained by means of the Fuller method.
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References
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Byrne MA, Jones MR, Staveley LAK, Trans. Faraday Soc., 64, 1747 (1968)
Campbell SW, Fluid Phase Equilib., 47, 47 (1989)
Chapman S, Cowling TG, The Mathematical Theory of Nonuni form Gases, 3rd ed., Cambridge University Press, New York (1970)
Derr EL, Deal CH, Inst. Chem. Eng. Symp. Ser., 32, 44 (1969)
Dymond JH, Alder BJ, J. Chem. Phys., 51(1), 309 (1969)
Dymond JH, Smith EB, The Virial Coefficients of Pure Gases and Mixtures-A Critical Compilation, Clarendon Press, Oxford (1980)
Fredenslund A, Jones RL, Prausnitz JM, AIChE J., 21(6), 1086 (1975)
Fuller EN, Schettler PD, Giddings JC, Ind. Eng. Chem. Fundam., 58(5), 18 (1966)
Georgeton GK, Teja AS, Ind. Eng. Chem. Res., 27, 657 (1988)
Hellemans JM, Kestin J, Ro ST, J. Chem. Phys., 57(9), 4038 (1972)
Hirschfelder JO, Curtiss CF, Bird RB, Molecular Theory of Gases and Liquids, Wiley, New York (1954)
Holsen JN, Strunk MR, Ind. Eng. Chem. Fundam., 3, 143 (1964)
Humphreys AE, Mason EA, The Physics of Fluids, 13(1), 65 (1970)
IMSL, IMSL STAT/LIBRARY: Regression, IMSL, Houston (1994)
Iwasaki H, Kestin J, Physica, 29, 1345 (1963)
Jin G, Walsh JM, Donahue MD, Fluid Phase Equilib., 31, 123 (1986)
Kalelkar AS, Kestin J, J. Chem. Phys., 52(8), 4248 (1970)
Kestin J, Nagashima A, J. Chem. Phys., 40(12), 3648 (1964)
Kestin J, Kobayashi Y, Wood RT, Physica, 32, 1065 (1966)
Kestin J, Yata J, J. Chem. Phys., 49(11), 4780 (1968)
Kestin J, Wakeham W, Watanabe K, J. Chem. Phys., 53(10), 3773 (1970)
Kestin J, Paykoc EE, Sengers JV, Physica, 54, 1 (1971)
Kestin J, Ro ST, Wakeham WA, J. Chem. Phys., 56(8), 4036 (1972)
Kestin J, Ro ST, Wakeham WA, J. Chem. Phys., 56(8), 4086 (1972)
kestin J, Ro ST, Wakeham WA, J. Chem. Phys., 56(8), 4119 (1972)
Kestin J, Ro ST, Wakeham WA, J. Chem. Phys., 56(12), 5837 (1972)
Kestin J, Ro ST, Ber. Bunsen-Ges. Physik. Chem., 20, 20 (1974)
Kestin J, Ro ST, Ber. Bunsen-Ges. Phys. Chem., 86, 948 (1982)
Kestin J, Knierim K, Mason EA, Najafi B, Ro ST, Waldman M, J. Phys. Chem. Ref Data, 13(1), 229 (1984)
Kihara T, Intermolecular Forces, Wiley, New York (1978)
Lide DR, Handbook of Chemistry and Physics, 76th Ed,. CRC Press (1995)
Lucas K, Phase Equilibria and Fluid Properties in the Chemical Industry, Dechema, Frankfurt (1980)
O'Connell JP, Prausnitz JM, Advances in Thermophysical Properties at Extreme Temperatures and Pressures, 3rd Symposium of Thermophysical Properties, ASME, New York (1965)
O'Connell, J.P., Personal Communication (1988)
Oh SK, A Group Interaction Model for Second Virial Coefficients of Pure Gases and Mixtures, M.S. Thesis, University of S. Florida, Tampa (1989)
Oh SK, Campbell SW, Fluid Phase Equilib., 129(1-2), 69 (1997)
Oh SK, Sim CH, Korean J. Chem. Eng., 19(5), 843 (2002)
Oh SK, Park KH, Korean J. Chem. Eng., 22(2), 268 (2005)
Poling BE, Prausnitz JM, O'Connell JP, The Properties of Gases and Liquids, 5th ed, McGraw-Hill, NY (2000)
Prausnitz JM, Lichtenthaler RN, de Azevedo EG, Molecular Thermodynamics of Fluid-Phase Equilibria, 3rd ed,. Prentice Hall (1999)
Rietveld AO, Van Itterbeek A, Van Den Berg GJ, Physica, 19, 517 (1953)
Rietveld AO, Van Itterbeek A, Van Den Berg GJ, Physica, 22, 785 (1956)
Rietveld AO, Van Itterbeek A, Velds CA, Physica, 25, 205 (1959)
Seager SL, Geertson LR, Giddings JC, J. Chem. Eng. Data, 8, 168 (1963)
Strehlow RA, J. Chem. Eng. Data, 21, 2101 (1953)
Strehlow RA, J. Chem. Eng. Data, 31, 519 (1959)
Saxena SC, Mason EA, "Thermal Diffusion and the Approach to the State in Gases: II:, Mol. Phys., 2, 379 (1959)
Stephan K, Lucas K, Viscosity of Dense Fluids, Plenum Press, New York (1979)
Tee LS, Gotoh S, Stewart WE, Ind. Eng. Chem. Fundam., 5, 363 (1966)
Thornton E, Baker WAD, Proc. Phys. Soc., 80, 1171 (1962)
Thornton E, Proc. Phys. Soc., 77, 1166 (1960)
Thornton E, Proc. Phys. Soc., 76, 104 (1960)
Tsonopoulos C, Dymond JM, Szafranski AM, Pure Appl. Chem., 61(6), 1387 (1989)
Tsonopoulos C, Dymond JH, Fluid Phase Equilib., 133(1-2), 11 (1997)
Tsonopoulos C, AIChE J., 20(2), 263 (1974)
van Heijningen RJJ, Harpe JP, Beenakker JJM, Physica, 38, 1 (1968)