Articles & Issues
- Language
- English
- Conflict of Interest
- In relation to this article, we declare that there is no conflict of interest.
- Publication history
-
Received October 31, 2005
Accepted December 23, 2005
-
This is an Open-Access article distributed under the terms of the Creative Commons Attribution Non-Commercial License (http://creativecommons.org/licenses/bync/3.0) which permits
unrestricted non-commercial use, distribution, and reproduction in any medium, provided the original work is properly cited.
Copyright © KIChE. All rights reserved.
All issues
Estimation of kinetic triplet of cellulose pyrolysis reaction from isothermal kinetic results
Dept. of Environmental System Engineering, Hallym University, 1, Okchon-dong, Chuncheon, Gangwon-do 200-702, Korea
Korean Journal of Chemical Engineering, May 2006, 23(3), 409-414(6), 10.1007/BF02706742
Download PDF
Abstract
This paper presents a new approach to estimate the Arrhenius parameters as well as the reaction model function of cellulose pyrolysis reaction. Reduced time plot (RTP) was employed to choose a proper form of reaction model function for cellulose pyrolysis reaction. A state-of-the-art thermobalance (TB) that is able to form real isothermal reaction conditions was introduced to construct RTPs from isothermal decomposition kinetic data. The reaction model function of cellulose pyrolysis reaction would be accounted for by Avrami-Erofeev function, n(1-α){-ln(1-a)}1-1/n where n is determined to be 3.69.
References
Agrawal R, Can. J. Chem. Eng., 66, 403 (1988)
Agrawal R, Can. J. Chem. Eng., 66, 413 (1988)
Antal MJ, Varhegyi G, Ind. Eng. Chem. Res., 34(3), 703 (1995)
Antal MJ, Varheyi G, Jakab M, Ind. Eng. Chem. Res., 7, 1267 (1998)
Bigger S, Scheirs J, Camino G, Polym. Degrad. Stabil., 62, 33 (1998)
DIBLASI C, Biomass Bioenerg., 7(1-6), 87 (1994)
Diblasi C, Ind. Eng. Chem. Res., 35(1), 37 (1996)
Bradbury A, Sakai Y, Shafizadeh F, J. Appl. Polym. Sci., 23, 3271 (1979)
Broido A, Kinetics of solid-phase cellulose pyrolysis, Thermal uses and properties of carbohydrates and lignins, Shafizadeh, F., Sarkanen, K. and Tillman, D., eds., Academic Press, New York (1976)
Conesa JA, Caballero JA, Marcilla A, Font R, Thermochim. Acta, 254, 175 (1995)
DIEBOLD JP, Biomass Bioenerg., 7(1-6), 75 (1994)
Gronli M, Antal MJ, Varhegyi G, Ind. Eng. Chem. Res., 38(6), 2238 (1999)
Eom Y, Kim S, Kim SS, Chung SH, “Using the peak property method to estimate apparent kinetic parameters of cellulose pyrolysis reaction,” Submitted for possible publication to Chem. Eng. J. (2005)
Kwon TW, Kim SD, Fung DPC, Fuel, 67, 530 (1988)
Halikia I, Neou-Syngouna P, Kolitsa D, Thermochim. Acta, 320(1-2), 75 (1998)
Liliedahl T, Sjostrom K, Biomass Bioenerg., 15(6), 503 (1998)
Maciejewski M, Computational aspects of kinetic analysis. Part B: The ICTAC Kinetic Project - the decomposition kinetics of calcium carbonate revisited, or some tips on survival in the kinetic minefield (2000)
Pyle DL, Zaror CA, Chem. Eng. Sci., 39, 147 (1984)
Reactions in the Solid State. Comprehensive Chemical Kinetics, Bamford, C.H. and Tipper, C. F.H., eds., Vol. 22. Elsevier, Amsterdam (1980)
Reynolds JG, Burnham AK, Energy Fuels, 11(1), 88 (1997)
Rodante F, Vecchio S, Tomassetti M, J. Pharm. Biomed. Anal., 29, 1031 (2002)
Tanaka H, Thermochim. Acta, 267, 29 (1995)
Varhegyi G, Antal M, Energy Fuels, 3, 329 (1989)
Varhegyi G, Antal M, Jakab E, Szabo P, J. Anal. Appl. Pyrolysis, 42, 73 (1997)
Varhegyi G, Jakab E, Antal MJ, Energy Fuels, 8(6), 1345 (1994)
Vyazovkin S, Wight SA, Thermochim. Acta, 340, 53 (1999)
Agrawal R, Can. J. Chem. Eng., 66, 413 (1988)
Antal MJ, Varhegyi G, Ind. Eng. Chem. Res., 34(3), 703 (1995)
Antal MJ, Varheyi G, Jakab M, Ind. Eng. Chem. Res., 7, 1267 (1998)
Bigger S, Scheirs J, Camino G, Polym. Degrad. Stabil., 62, 33 (1998)
DIBLASI C, Biomass Bioenerg., 7(1-6), 87 (1994)
Diblasi C, Ind. Eng. Chem. Res., 35(1), 37 (1996)
Bradbury A, Sakai Y, Shafizadeh F, J. Appl. Polym. Sci., 23, 3271 (1979)
Broido A, Kinetics of solid-phase cellulose pyrolysis, Thermal uses and properties of carbohydrates and lignins, Shafizadeh, F., Sarkanen, K. and Tillman, D., eds., Academic Press, New York (1976)
Conesa JA, Caballero JA, Marcilla A, Font R, Thermochim. Acta, 254, 175 (1995)
DIEBOLD JP, Biomass Bioenerg., 7(1-6), 75 (1994)
Gronli M, Antal MJ, Varhegyi G, Ind. Eng. Chem. Res., 38(6), 2238 (1999)
Eom Y, Kim S, Kim SS, Chung SH, “Using the peak property method to estimate apparent kinetic parameters of cellulose pyrolysis reaction,” Submitted for possible publication to Chem. Eng. J. (2005)
Kwon TW, Kim SD, Fung DPC, Fuel, 67, 530 (1988)
Halikia I, Neou-Syngouna P, Kolitsa D, Thermochim. Acta, 320(1-2), 75 (1998)
Liliedahl T, Sjostrom K, Biomass Bioenerg., 15(6), 503 (1998)
Maciejewski M, Computational aspects of kinetic analysis. Part B: The ICTAC Kinetic Project - the decomposition kinetics of calcium carbonate revisited, or some tips on survival in the kinetic minefield (2000)
Pyle DL, Zaror CA, Chem. Eng. Sci., 39, 147 (1984)
Reactions in the Solid State. Comprehensive Chemical Kinetics, Bamford, C.H. and Tipper, C. F.H., eds., Vol. 22. Elsevier, Amsterdam (1980)
Reynolds JG, Burnham AK, Energy Fuels, 11(1), 88 (1997)
Rodante F, Vecchio S, Tomassetti M, J. Pharm. Biomed. Anal., 29, 1031 (2002)
Tanaka H, Thermochim. Acta, 267, 29 (1995)
Varhegyi G, Antal M, Energy Fuels, 3, 329 (1989)
Varhegyi G, Antal M, Jakab E, Szabo P, J. Anal. Appl. Pyrolysis, 42, 73 (1997)
Varhegyi G, Jakab E, Antal MJ, Energy Fuels, 8(6), 1345 (1994)
Vyazovkin S, Wight SA, Thermochim. Acta, 340, 53 (1999)
