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Received November 16, 2005
Accepted February 11, 2006
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Reaction rate of carbon dioxide in glycidyl methacrylate solution using tricaprylylmethylammonium chloride as a catalyst
Division of Chemical Engineering, Pusan National University, Busan 609-735, Korea 1Department of Chemical Engineering, Sogang University, Seoul 121-742, Korea
swpark@pusan.ac.kr
Korean Journal of Chemical Engineering, July 2006, 23(4), 645-649(5), 10.1007/BF02706808
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Abstract
Carbon dioxide was absorbed into organic solutions of glycidyl methacrylate (GMA) in a semi-batch stirred tank with a plane gas-liquid interface at 101.3 kPa to measure absorption rates of carbon dioxide, from which the reaction kinetics between carbon dioxide and GMA were studied by using tricaprylylmethylammonium chloride catalyst. The reaction rate constants of the reaction were estimated by using the mass transfer mechanism accompanied by the pseudo-first-order reaction. An empirical correlation formula between the reaction rate constants and the solubility_x000D_
parameters of solvents such as toluene, N-methyl-2-pirrolidinone, and dimethyl sulfoxide was presented.
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Danckwerts PV, Gas-Liquid Reaction, McGraw-Hill Book Company, New York (1970)
Doraiswamy LK, Sharma MM, Heterogeneous Reaction: Analysis, Example and Reactor Design, John Wiley & Sons, New York, 17-26 (1984)
Herbrandson HF, Neufeld FR, J. Org. Chem., 31, 1140 (1966)
Inoue S, In organic and bioorganic chemistry of carbon dioxide, S. Inoue and N. Yamazaki, Eds. Kodansha Ltd., Tokyo (1982)
Kennard ML, Meisen A, J. Chem. Eng. Data, 29, 309 (1984)
Kihara N, Endo T, Macromolecules, 25, 4824 (1992)
Kihara N, Hara N, Endo T, J. Org. Chem., 58, 6198 (1993)
Morrison RT, Boyd RN, Organic Chemistry, Fourth Ed., Allyn and Bacon, Inc., Toronto, 244-246 (1983)
Nishikubo T, Kameyama A, Yamashita J, Tomoi M, Fukuda W, J. Polym. Sci. A: Polym. Chem., 31, 939 (1993)
Park SW, Cho HB, Park DW, J. Ind. Eng. Chem., 9(4), 464 (2003)
Park SW, Choi BS, Kim SS, Lee JW, Korean J. Chem. Eng., 21(6), 1205 (2004)
Peppel WJ, Ind. Eng. Chem., 50, 767 (1958)
Rokicki G, Makromol. Chem., 186, 331 (1985)
Rokicki G, Pawlicki J, Kurau W, Polym. J., 17, 509 (1985)
