Articles & Issues
- Language
- English
- Conflict of Interest
- In relation to this article, we declare that there is no conflict of interest.
- Publication history
-
Received June 19, 2006
Accepted December 5, 2006
-
This is an Open-Access article distributed under the terms of the Creative Commons Attribution Non-Commercial License (http://creativecommons.org/licenses/bync/3.0) which permits
unrestricted non-commercial use, distribution, and reproduction in any medium, provided the original work is properly cited.
Copyright © KIChE. All rights reserved.
All issues
Measurement and estimation of the lower flash points for the flammable binary systems using a Tag open cup tester
Department of Occupational Health and Safety Engineering, Korea 1Department of Clinical Laboratory Science, Semyung University, Jecheon 390-711, Korea 2School of Fire and Disaster Prevention, Kangwon National University, Samcheok 245-711, Korea
Korean Journal of Chemical Engineering, July 2007, 24(4), 551-555(5), 10.1007/s11814-007-0001-2
Download PDF
Abstract
Lower flash points for flammable binary systems, ethylbenzene+n-propanol, n-propionic acid+ethylbenzene and n-propionic acid+o-xylene, were measured by Tag open cup tester. These binary solutions exhibited the minimum flash point behavior, which leads to a minimum on the flash point vs composition curve. The experimental data were compared with the values calculated by the flash point prediction models based on the van Laar and Wilson equations. As can be seen from the A.A.D., the calculated values based on the Wilson equation were found to be better than those based on the van Laar equation.
Keywords
References
Kong D, David JE, Steven JB, Neil PW, J. Hazard. Mater., 102, 155 (2003)
Crowl DA, Louvar JF, Englewood cliffs, New Jersey (1990)
Hshieh FY, Fire Mater., 21, 277 (1997)
Lees FP, Loss prevention in the process industries, 2nd ed., Butterworth-Heinemann Vol. 1, Oxford (1996)
Affens WA, McLaren GW, J. Chem. Eng. Data, 17, 482 (1972)
White D, Beyler CL, Fulper C, Leonard J, Fire Safety Journal, 38, 1 (1997)
Liaw HJ, Lee YH, Tang CL, Hsu HH, Liu JH, J. Loss Prev. Process Ind., 15, 429 (2002)
Ha DM, Mok YS, Choi JW, HWAHAK KONGHAK, 37(2), 146 (1999)
Ha DM, Lee SK, J. of Korea Institute of Fire Sci. & Eng., 15, 14 (2001)
Ha DM, Choi YC, Lee SJ, J. of Korean Institute for Industrial Sefety, 17, 140 (2002)
Lee S, Ha DM, Korean J. Chem. Eng., 20(5), 799 (2003)
Reid CR, Prausnitz JM, Poling BE, The properties of gases and liquids, 4th Edition, McGraw-Hill, New York, 102 (1998)
Wilson GM, J. Am. Chem. Soc., 86, 127 (1964)
NFPA, Fire hazard properties of flammable liquid, gases and volatile solids, NFPA 325M, National Fire Protection Association (1991)
Ha DM, Lee SJ, Song YH, J. of the Korean Society of Sefety, 19, 69 (2004)
Lance RC, Barnard AJ, Hooyman JE, J. Hazard. Mater., 3, 107 (1979)
Chatelier H, Ann. Minmes, 19, 388 (1891)
Gmehing J, Onken U, Arlt W, Vapor-liquid equilibrium data collection, Vol. I, Part1-Part7, DECHEMA (1980)
Park JC, Ha DM, Kim MG, Korean J. Chem. Eng., 13(2), 115 (1996)
Tu CH, Wu YS, Liu TL, Fluid Phase Equilib., 135(1), 97 (1997)
Crowl DA, Louvar JF, Englewood cliffs, New Jersey (1990)
Hshieh FY, Fire Mater., 21, 277 (1997)
Lees FP, Loss prevention in the process industries, 2nd ed., Butterworth-Heinemann Vol. 1, Oxford (1996)
Affens WA, McLaren GW, J. Chem. Eng. Data, 17, 482 (1972)
White D, Beyler CL, Fulper C, Leonard J, Fire Safety Journal, 38, 1 (1997)
Liaw HJ, Lee YH, Tang CL, Hsu HH, Liu JH, J. Loss Prev. Process Ind., 15, 429 (2002)
Ha DM, Mok YS, Choi JW, HWAHAK KONGHAK, 37(2), 146 (1999)
Ha DM, Lee SK, J. of Korea Institute of Fire Sci. & Eng., 15, 14 (2001)
Ha DM, Choi YC, Lee SJ, J. of Korean Institute for Industrial Sefety, 17, 140 (2002)
Lee S, Ha DM, Korean J. Chem. Eng., 20(5), 799 (2003)
Reid CR, Prausnitz JM, Poling BE, The properties of gases and liquids, 4th Edition, McGraw-Hill, New York, 102 (1998)
Wilson GM, J. Am. Chem. Soc., 86, 127 (1964)
NFPA, Fire hazard properties of flammable liquid, gases and volatile solids, NFPA 325M, National Fire Protection Association (1991)
Ha DM, Lee SJ, Song YH, J. of the Korean Society of Sefety, 19, 69 (2004)
Lance RC, Barnard AJ, Hooyman JE, J. Hazard. Mater., 3, 107 (1979)
Chatelier H, Ann. Minmes, 19, 388 (1891)
Gmehing J, Onken U, Arlt W, Vapor-liquid equilibrium data collection, Vol. I, Part1-Part7, DECHEMA (1980)
Park JC, Ha DM, Kim MG, Korean J. Chem. Eng., 13(2), 115 (1996)
Tu CH, Wu YS, Liu TL, Fluid Phase Equilib., 135(1), 97 (1997)
