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Received March 30, 2007
Accepted July 23, 2007
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Electrochemical properties of gel polymer electrolyte based on poly(acrylonitrile)-poly(ethylene glycol diacrylate) blend
Battery Research Center, KIST, Seoul 136-791, Korea 1Department of Chemical Engineering, Sogang University, Seoul 121-742, Korea 2School of Chemical Engineering, Chungbuk National University, Chungbuk 361-763, Korea
nabk@chungbuk.ac.kr
Korean Journal of Chemical Engineering, November 2007, 24(6), 1037-1041(5), 10.1007/s11814-007-0117-4
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Abstract
Gel type electrolyte was formulated by blending of PEDGA and PAN. PEDGA is a UV curable polymer which forms a chemical crosslink by UV or heat. Gel type electrolyte is very stable in ionic conductivity and interfacial resistance for a long storage time. It has the advantage of manufacturing the battery in a continuous process because oligomer crosslinking occurs in few seconds without heating. Discharge capacity and cycle life were increased by using LiPF6/LiCF3SO3 mixed lithium salt and adding inorganic filler such as TiO2.
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Scrosati B, J. Electrochem. Soc., 139, 2776 (1992)
Kim T, Kang IJ, Cho G, Park KP, Korean J. Chem. Eng., 22(2), 234 (2005)
Yeon SH, Kim KS, Choi S, Cha JH, Lee H, Oh J, Lee BB, Korean J. Chem. Eng., 23(6), 940 (2006)
Armand MB, Chabagno JM, Duchot M, Second international meeting on solid electrolyte, St Andrews, Scotland, Sept., 20-22 1978, Extended Abstract
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Koto Y, Watanabe M, Sanui K, Ogata N, Solid State Ion., 40/41, 632 (1990)
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Feuillade G, J. Appl. Electrochem., 5, 63 (1975)
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Abraham KM, Alamgir M, J. Electrochem. Soc., 137, 1657 (1990)
Digar ML, Hung SL, Wen TC, Gopalan A, Polymer, 43(5), 1615 (2002)
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Fauteux D, Massucco A, Mclin M, Vanburen M, Shi J, Electrochim. Acta, 40(13-14), 2185 (1995)
Quartarone E, Mustarelli P, Magistris A, Solid State Ion., 110(1-2), 1 (1998)
Best AS, Ferry A, MacFarlane DR, Forsyth M, Solid State Ion., 126(3-4), 269 (1999)
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Wen ZY, Wu MM, Itoh T, Kubo M, Lin ZX, Yamamoto O, Solid State Ion., 148(1-2), 185 (2002)
