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Received December 14, 2006
Accepted April 2, 2007
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Kinetic parameters using an immobilized tetrahexylammonium chloride catalyst in glycidyl methacrylate reaction with carbon dioxide
Division of Chemical Engineering, Pusan National University, Busan 609-735, Korea 1School of Environmental Science, Catholic University, Busan 609-757, Korea 2Department of Chemical Engineering, Sogang University, Seoul 121-742, Korea
swpark@pusan.ac.kr
Korean Journal of Chemical Engineering, November 2007, 24(6), 953-959(7), 10.1007/s11814-007-0104-9
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Abstract
A soluble copolymer-supported catalyst containing pendant tetrahexylammonium chloride was synthesized by the radical copolymerization of p-chloromethylated styrene with styrene followed by the addition reaction of the resulting copolymer with trihexylamine. Initial absorption rate of carbon dioxide into glycidyl methacrylate (GMA) solutions containing the catalyst was measured in a semi-batch stirred tank with a plane gas-liquid interface at 101.3 kPa. The reaction rate constants of the elementary reaction between carbon dioxide and GMA were evaluated from analysis of the mass transfer mechanism accompanied by the elementary reactions based on film theory. Solvents such as toluene, N-methyl-2-pirrolidinone, and dimethyl sulfoxide influenced the reaction rate constants. Furthermore, this catalyst was compared to monomeric tetrahexylammonium chloride under the same reaction conditions.
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Aida T, Inoue S, J. Am. Chem. Soc., 105, 1304 (1983)
Nishikubo Y, Kato T, Sugimoto S, Tomoi M, Ishigaki S, Macromolecules, 23, 3406 (1990)
Kihara N, Endo T, Macromolecules, 25, 4824 (1992)
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Daraiswany LK, Sharma MM, Heterogeneous reaction: analysis, example and reactor design, John Wiley & Sons, New York (1980)
Park SW, Park DW, Kim TY, Park MY, Oh KJ, Catal. Today, 98(4), 493 (2004)
Park SW, Choi BS, Park DW, Kim SS, J. Ind. Eng. Chem., 11(4), 527 (2005)
Park SW, Lee JW, Stud. Surf. Sci. Catal., 159, 345 (2006)
Park SW, Choi BS, Lee BD, Park DW, Kim SS, Sep. Sci. Technol., 41(5), 829 (2006)
Gomez-Diaz D, Mejuto JC, Navaza JM, Chem. Eng. Sci., 61(8), 2330 (2006)
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Morrison RT, Boyd RN, Organic chemistry, Fourth Ed, Allyn and Bacon, Inc, Toronto (1983)