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Received April 13, 2007
Accepted September 13, 2007
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Adiabatic runaway studies for methyl ethyl ketone peroxide with inorganic acids by vent sizing package 2
Doctoral Program, Graduate School of Engineering Science and Technology, National Yunlin University of Science and Technology, 123, University Rd., Sec. 3, Douliu, Yunlin, 64002, ROC, Taiwan 1Department of Chemistry, National Chung Hsing University, 250, Kuo-Kwang Rd., Taichung, 40227, ROC, Taiwan 2Department of Environmental Resources Management, Overseas Chinese Institute of Technology, 100, Chiao-Kwang Rd., Taichung, 40721, ROC, Taiwan
Korean Journal of Chemical Engineering, May 2008, 25(3), 419-422(4), 10.1007/s11814-008-0070-x
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Abstract
Methyl ethyl ketone peroxide (MEKPO) is an unstable material that is classified as an explosive substance. We evaluated MEKPO 10 mass% under mixing with three inorganic acids (6 N HNO3, 6 N H3PO4, and 6 N H2SO4) by adiabatic system of vent sizing package 2 (VSP2). Results from evaluation and testing indicated that these three inorganic acids could increase the degree of hazard while combined with pure MEKPO. Therefore, information on the hazards and phenomena of runaway reaction should be provided in order to lessen the degree of hazard.
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References
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Jiang PY, Katsumura Y, Domae M, Ishikawa K, Nagaishi R, Ishigure K, Yoshida Y, J. Chem. Soc.-Faraday Trans., 88, 3319 (1992)
