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Received July 30, 2007
Accepted September 17, 2007
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Catalytic performance of pyridinium salt ionic liquid in the synthesis of cyclic carbonate from carbon dioxide and butyl glycidyl ether
Division of Chemical Engineering, Pusan National University, Busan 609-735, Korea
dwpark@pusan.ac.kr
Korean Journal of Chemical Engineering, May 2008, 25(3), 471-473(3), 10.1007/s11814-008-0080-8
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Abstract
The catalytic performance of pyridinium salt ionic liquids in the reaction of butyl glycidyl ether and carbon dioxide was investigated in this study. The catalytic activity was studied in a batch reactor with different 1-alkylpyridinium salt ionic liquids at 60-140 ℃. The conversion of butyl glycidyl ether was affected by the structure of the ionic liquid; the one with the cation of bulkier alkyl chain length showed better reactivity. The effect of carbon dioxide pressure, reaction temperature and zinc bromide co-catalyst on this reaction was also discussed.
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Kihara N, Endo T, Makromol. Chem., 193, 1482 (1992)
Nishikubo T, Kameyama A, Sasano M, J. Polym. Sci. A: Polym. Chem., 32(2), 301 (1994)
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Mun NY, Kim KH, Park DW, Choe Y, Kim I, Korean J. Chem. Eng., 22(4), 556 (2005)
Lee EH, Cha SW, Dharma MM, Choe Y, Ahn JY, Park DW, Korean J. Chem. Eng., 24(3), 547 (2007)
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Seddon KR, Kinet. Catal., 37, 693 (1996)
Larsen AS, Holbrey JD, Tham FS, Reed CA, J. Am. Chem. Soc., 122(30), 7264 (2000)
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Olivier-Bourbigou H, Magna L, J. Mol. Catal. A-Chem., 182(1), 419 (2002)
Sun JM, Fujita SI, Zhao FY, Arai M, Appl. Catal. A: Gen., 287(2), 221 (2005)
Sun J, Fujita SI, Zhao F, Arai M, Green Chem., 6, 613 (2004)
