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Received December 1, 2006
Accepted August 5, 2007
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Composite group vector space method for estimating melting and boiling point of pure organic compound
1Key Laboratory for Green Chemical Technology of State Education Ministry,School of Chemical Engineering & Technology, Tianjin University, Tianjin 300072, China 2The 718 Research Institute of CSIC, HanDan 056027, China
Korean Journal of Chemical Engineering, May 2008, 25(3), 562-567(6), 10.1007/s11814-008-0095-1
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Abstract
Composition Group Vector Space (CGVS) method for estimating melting and boiling point Tm, Tb of organic compound has been proposed, and the principle of this method has been elucidated. The models for estimating Tm, Tb have been established and the numerical values of relative parameters have been presented. The average percentage deviations of Tm, Tb estimation are 7.53 and 1.58, respectively, which show that the present method demonstrates significant improvement in applicability to predict the above properties, compared to conventional group methods.
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References
Joback KG, Reid RC, Chem. Eng. Commun., 57, 233 (1987)
Ambrose D, Correlation and estimation of vapour-liquid critical properties. 1. Critical temperatures of organic compound, NPL reports in chemistry 92, National Physical Laboratory, Teddington, U.K. (1978)
Ambrose D, Vapor-liquid critical properties: II. Critical pressure and critical volume, NPL reports in chemistry 107, National Physical Laboratory, Teddington, U.K. (1980)
Lyman WJ, Reehl WF, Rosenblatt DH, Handbook of chemical property estimation methods, American Chemical Society, Washington, DC (1990)
Marrero-Morejon J, Pardillo-Fontdevila E, AIChE J., 45(3), 615 (1999)
Constantinou L, Gani R, AIChE J., 40(10), 1697 (1994)
Hall KR, Beach LB, selected values of properties of hydrocarbons and related compounds, Thermodynamics Research Center, Texas A & M university, Texas (1981)
Poling BE, Prausnitz JM, O’Connell JP, The properties of gases and liquids, 5th ed. McGraw-Hill Book Co., New York (2001)
West RC, Astle MJ, CRC handbook of data on organic compounds, CRC Press Inc., Boca Raton, FL (1985)
Majer V, Svoboda V, Enthalpies of vaporization of organic compounds, Blackwell Scientific Publication, Oxford (1985)
Ambrose D, Correlation and estimation of vapour-liquid critical properties. 1. Critical temperatures of organic compound, NPL reports in chemistry 92, National Physical Laboratory, Teddington, U.K. (1978)
Ambrose D, Vapor-liquid critical properties: II. Critical pressure and critical volume, NPL reports in chemistry 107, National Physical Laboratory, Teddington, U.K. (1980)
Lyman WJ, Reehl WF, Rosenblatt DH, Handbook of chemical property estimation methods, American Chemical Society, Washington, DC (1990)
Marrero-Morejon J, Pardillo-Fontdevila E, AIChE J., 45(3), 615 (1999)
Constantinou L, Gani R, AIChE J., 40(10), 1697 (1994)
Hall KR, Beach LB, selected values of properties of hydrocarbons and related compounds, Thermodynamics Research Center, Texas A & M university, Texas (1981)
Poling BE, Prausnitz JM, O’Connell JP, The properties of gases and liquids, 5th ed. McGraw-Hill Book Co., New York (2001)
West RC, Astle MJ, CRC handbook of data on organic compounds, CRC Press Inc., Boca Raton, FL (1985)
Majer V, Svoboda V, Enthalpies of vaporization of organic compounds, Blackwell Scientific Publication, Oxford (1985)
