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Received February 11, 2008
Accepted March 6, 2008
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Effect of reaction conditions on the catalytic performance of H3PW12O40 heteropolyacid catalyst in the direct preparation of dichloropropanol from glycerol in a liquid-phase batch reactor
Sang Hee Lee
Dong Ryul Park
Heesoo Kim
Joohyung Lee
Ji Chul Jung
Sung Yul Woo1
Won Seob Song1
Myong Suk Kwon1
In Kyu Song†
School of Chemical and Biological Engineering, Institute of Chemical Processes, Seoul National University, Shinlim-dong, Gwanak-gu, Seoul 151-744, Korea 1Samsung Fine Chemicals Corporation, Nam-gu, Ulsan 680-090, Korea
inksong@snu.ac.kr
Korean Journal of Chemical Engineering, September 2008, 25(5), 1018-1021(4), 10.1007/s11814-008-0165-4
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Abstract
Direct chlorination of glycerol to dichloropropanol (DCP) was conducted in a liquid-phase batch rector using homogeneous H3PW12O40 heteropolyacid (HPA) catalyst. The effect of reaction conditions (reaction time, reaction pressure, reaction temperature, and catalyst amount) on the catalytic performance of H3PW12O40 in the direct preparation of DCP from glycerol was examined. The optimum reaction pressure and reaction temperature were found to be 10 bar and 130 oC, respectively. The reaction temperature was more crucial than the reaction pressure in improving the selectivity to DCP. Selectivity to DCP increased with increasing reaction time and with increasing catalyst amount. Acid sites of H3PW12O40 catalyst favorably devoted to the chlorination of glycerol. H3PW12O40 served as an efficient catalyst in the direct preparation of DCP from glycerol under the mild reaction conditions.
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Lee KW, Yu JX, Mei JH, Yan L, Kim YW, Chung KW, J. Ind. Eng. Chem., 13(5), 799 (2007)
Park YM, Lee DW, Kim DK, Lee JS, Lee KY, Catal. Today, 131, 238 (2008)
MacLeod CS, Harvey AP, Lee AF, Wilson K, Chem. Eng. J., 135(1-2), 63 (2008)
Rashid U, Anwar F, Fuel, 87, 265 (2008)
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HWANG CY, KWAK JW, LEE WY, LEE HI, Korean J. Chem. Eng., 3(1), 31 (1986)
SONG IK, MOON SH, LEE WY, Korean J. Chem. Eng., 8(1), 33 (1991)
Kozhevnikov IV, Catal. Rev.-Sci. Eng., 37(2), 311 (1995)
Hill CL, Prosser-McCartha CM, Coord. Chem. Rev., 143, 407 (1995)
Okuhara T, Mizuno N, Misono M, Adv. Catal., 41, 113 (1996)
Misono M, Korean J. Chem. Eng., 14(6), 427 (1997)
Lee WY, Song IK, Lee JK, Park GI, Lim SS, Korean J. Chem. Eng., 14(6), 432 (1997)
Choi JS, Song IK, Lee WY, Korean J. Chem. Eng., 17(3), 280 (2000)
Wang R, Korean J. Chem. Eng., 20(4), 659 (2003)
LEE JS, WOO JW, LEE CW, HONG KS, YEO JK, Korean J. Chem. Eng., 7(2), 145 (1990)
Kim HC, Moon SH, Lee WY, Chem. Lett., 20, 447 (1991)
Song IK, Barteau MA, Korean J. Chem. Eng., 19(4), 567 (2002)
Lim SS, Park GI, Song IK, Lee WY, J. Mol. Catal. A-Chem., 182(1), 175 (2002)
Barteau MA, Lyons JE, Song IK, J. Catal., 216(1-2), 236 (2003)
Song IK, Kim HS, Chun MS, Korean J. Chem. Eng., 20(5), 844 (2003)
Song IK, Barteau MA, J. Mol. Catal. A-Chem., 212(1-2), 229 (2004)
Youn MH, Park DR, Jung JC, Kim H, Barteau MA, Song IK, Korean J. Chem. Eng., 24(1), 51 (2007)
Lee SH, Park DR, Kim H, Lee J, Jung JC, Woo SY, Song WS, Kwon MS, Song IK, Catal. Commun., 9, 1920 (2008)
