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Received August 27, 2008
Accepted September 30, 2008
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Metal recovery by aged beads prepared using cell-suspension from the waste of beer fermentation broth
Department of Chemical Engineering, Kyungpook National University, Daegu 702-701, Korea
parkjk@knu.ac.kr
Korean Journal of Chemical Engineering, March 2009, 26(2), 457-461(5), 10.1007/s11814-009-0078-x
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Abstract
Lead, copper, and cadmium were adsorbed onto aged calcium alginate beads containing cell-suspension from the waste of beer fermentation broth. Beads prepared by adding 0.6% (w/v) sodium alginate into the cell suspension from the waste of beer fermentation broth and making the cell suspension drop into the 1% (w/v) calcium alginate solution were stored in the 1% (w/v) calcium chloride solution for 1 year. The specific metal uptake of the aged cell-suspension immobilized bead was 312 mg Pb^(2+), 158 mg Cu^(2+), and 112 mg Cd^(2+)/g bead dry weight at pH 7.5 of the metal solution, respectively. The relation between the specific metal uptake by the aged cell-suspension immobilized beads and the equilibrium metal concentration was nonlinearly regressed and well described by the Freundlich isotherm. The specific cadmium uptake capacity of aged cell-suspension immobilized beads was between the specific cadmium uptake capacities of commercial beads Duolite GT-73 and Amberite IRA-400 and higher than those of the fresh Saccharomyces cerevisiae ATCC 834 and Saccharomyces cerevisiae ATCC 24858 immobilized beads.
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References
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Quintelas C, Fernandes B, Castro J, Figueiredo H, Tavares T, Chem. Eng. J., 136, 195 (2008)
Ahn KH, Suh KH, Korean J. Biotechnol. Bioeng., 11, 173 (1996)
Stoll A, Duncan JR, Process Biochem., 32(6), 467 (1997)
Volesky B, May H, Holan GR, Biotechnol. Bioeng., 41, 826 (1993)
Park JK, Lee JW, Jung JY, Enzyme Microb. Technol., 33(4), 371 (2003)
Park JK, Choi SB, Korean J. Chem. Eng., 19(1), 68 (2002)
Mowll JL, Gadd GM, J. Gen. Microbiol., 129, 3421 (1983)
Park JK, Lee KD, Korean J. Chem. Eng., 18(3), 363 (2001)
Holan ZR, Volesky B, Prasetyo I, Biotechnol. Bioeng., 41, 819 (1993)
Schiewer J, Volesky B, Env. Sci. Tech., 29, 3049 (1995)
Zhou JL, Kiff RJ, J. Chem. Tech. Biotech., 52, 317 (1991)
Yu Q, Kaewsarn P, Korean J. Chem. Eng., 16(6), 753 (1999)
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Puranik PR, Paknikar KM, Biotechnol. Prog., 15(2), 228 (1999)