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Received July 21, 2008
Accepted December 17, 2008
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Absorption of carbon dioxide into glycidyl methacrylate solution containing the triethylamine immobilized ionic liquid on MCM-41 catalyst
Division of Chemical Engineering, Pusan National University, Busan 609-735, Korea 1School of Environmental Science, Catholic University of Pusan, Busan 609-757, Korea
swpark@pusan.ac.kr
Korean Journal of Chemical Engineering, May 2009, 26(3), 783-790(8), 10.1007/s11814-009-0131-9
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Abstract
An ionic liquid (TEA-MS41), triethylamine-immobilized on chloropropyl-functionalized MCM-41, was synthesized by a grafting technique through a co-condensation method and used as a catalyst in the reaction of carbon dioxide with glycidyl methacrylate (GMA). CO2 was absorbed into the heterogeneous system of the GMA solution and dispersed with solid particles of the catalyst in a batch stirred tank with a plane gas-liquid interface at 101.3 kPa. The absorption of CO2 was analyzed by using mass transfer accompanied by chemical reactions based on film theory. The proposed model fits the measured data of the enhancement factor to obtain the reaction rate constants. Solvents such as N,N-dimethylacetamide, N-methyl-2-pyrrolidinone, and dimethyl sulfoxide influenced the reaction rate constants.
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Park SW, Choi BS, Park DW, Kim SS, J. Ind. Eng. Chem., 11(4), 527 (2005)
Park SW, Lee JW, Stud. Surface Sci. Catal., 159, 345 (2006)
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Alper E, Al-Hamed A, Shaikh AA, Proc. Int. Chem. React. Eng. Conf., 2, 17 (1987)
Kennard ML, Meisen A, J. Chem. Eng. Data, 29, 309 (1984)
Reid RC, Prausnitz JM, Sherwood TK, The properties of gases and liquids, McGraw-Hill, New York (1977)
Cussler EL, Diffusion, Cambridge University Press, New York (1984)
Park SW, Kim KW, Sohn IJ, Kaseger CF, Sep. Purif. Technol., 19(1-2), 43 (2000)
Carta G, Pigford RL, Ind. Eng. Chem. Fundam., 22, 329 (1983)
Herbrandson HF, Neufeld FB, J. Org. Chem., 31, 1140 (1966)
Brandrup J, Immergut EH, Polymer handbook, Second ed., John Wiley & Sons, New York (1975)
Morrison RT, Boyd RN, Organic chemistry, Fourth ed, Allyn and Bacon, Inc, Toronto (1983)
