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Received July 15, 2008
Accepted December 23, 2008
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Kinetic modeling of non-hydrocarbon/nitric oxide interactions in a flow reactor above 1,400K
Combustion Engineering Research Institute, School of Energy Science and Engineering, Harbin Institute of Technology, 92, West Dazhi Street, Harbin 150001, P. R. China
Korean Journal of Chemical Engineering, May 2009, 26(3), 840-844(5), 10.1007/s11814-009-0140-8
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Abstract
The reduction of nitric oxide by reaction with non-hydrocarbon fuels under reducing conditions at comparatively higher temperature has been studied with a detailed chemical kinetic model. The reaction mechanism consists of 337 elementary reactions between 65 chemical species based on the newest rate coefficients. The experimental data were adopted from previous work. Analyses by comparing existing experimental data with the modeling predictions of this kinetic mechanism indicate that, at comparatively high temperature, apart from the reaction path NO→_x000D_
HNO→NH→N2, NO+N→N2 is also prominent. In the presence of CO, NO is partly converted to N by reaction with CO. Based on present model, the reduction of NO at high temperature, which was usually underestimated by previous work, can be improved to some extent.
References
Bromly JH, Barnes FJ, Muris S, You X, Haynes BS, Combust. Sci. Technol., 115(4-6), 259 (1996)
Bilbao R, Alzueta MU, Millera A, Ind. Eng. Chem. Res., 34(12), 4531 (1995)
Bilbao R, Millera A, Alzueta MU, Prada L, Fuel, 76(14), 1401 (1997)
Alzueta MU, Glarborg P, DamJohansen K, Combust. Flame, 109(1-2), 25 (1997)
Glarborg P, Alzueta MU, Dam-Johansen K, Miller JA, Combust. Flame, 115(1-2), 1 (1998)
Giral I, Alzueta MU, Fuel, 81, 2263 (2002)
Qiu P, Wu S, Sun S, Liu H, Yang L, Wang G, Korean J. Chem. Eng., 24(4), 683 (2007)
Chen SL, McCarthy JM, Clark WD, Heap MP, Seeker WR, Pershing DW, Twenty-first symposium (international) on combustion, The Combustion Institute, 1159 (1986)
Glarborg P, Kristensen PG, Dam-Johansen K, Alzueta MU, Millera A, Bilbao R, Energy Fuels, 14(4), 828 (2000)
Sun S, Qian L, Wang Z, Cao H, Qin Y, Power Engineering, 28, 265 (2008)
Kristensen PG, Glarborg P, DamJohansen K, Combust. Flame, 107(3), 211 (1996)
Bilbao R, Millera A, Alzueta MU, Ind. Eng. Chem. Res., 33(11), 2846 (1994)
Skreiberg O, Kilpinen P, Glarborg P, Combust. Flame, 136(4), 501 (2004)
Kee RJ, Rupley F, Miller JA, Technical Report SAND87-8215, Sandia National Laboratories (1991)
Miller JA, Bowman CT, Prog. Energy Combust. Sci., 15, 287 (1989)
Kilmer K, Vicente T, Ellis A, NIST standard reference database, Gaithersburg, MD (2007)
Diau EW, Lin MC, He Y, Melius CF, Prog. Energy Combust. Sci., 21(1), 1 (1995)
Tang W, Herron JT, J. Phys. Chem. Ref. Data, 20, 609 (1991)
Miller JA, Melilus CF, Symp. Int. Combust. Proc., 24, 719 (1992)
Cohen N, Westberg KR, J. Phys. Chem. Ref. Data, 20, 1211 (1991)
Nguyen HMT, Zhang SW, Peeters J, Truong TN, Nguyen MT, Chem. Phys. Lett., 388(1-3), 94 (2004)
Soto MR, Page M, J. Chem. Phys., 97, 7287 (1992)
Bilbao R, Alzueta MU, Millera A, Ind. Eng. Chem. Res., 34(12), 4531 (1995)
Bilbao R, Millera A, Alzueta MU, Prada L, Fuel, 76(14), 1401 (1997)
Alzueta MU, Glarborg P, DamJohansen K, Combust. Flame, 109(1-2), 25 (1997)
Glarborg P, Alzueta MU, Dam-Johansen K, Miller JA, Combust. Flame, 115(1-2), 1 (1998)
Giral I, Alzueta MU, Fuel, 81, 2263 (2002)
Qiu P, Wu S, Sun S, Liu H, Yang L, Wang G, Korean J. Chem. Eng., 24(4), 683 (2007)
Chen SL, McCarthy JM, Clark WD, Heap MP, Seeker WR, Pershing DW, Twenty-first symposium (international) on combustion, The Combustion Institute, 1159 (1986)
Glarborg P, Kristensen PG, Dam-Johansen K, Alzueta MU, Millera A, Bilbao R, Energy Fuels, 14(4), 828 (2000)
Sun S, Qian L, Wang Z, Cao H, Qin Y, Power Engineering, 28, 265 (2008)
Kristensen PG, Glarborg P, DamJohansen K, Combust. Flame, 107(3), 211 (1996)
Bilbao R, Millera A, Alzueta MU, Ind. Eng. Chem. Res., 33(11), 2846 (1994)
Skreiberg O, Kilpinen P, Glarborg P, Combust. Flame, 136(4), 501 (2004)
Kee RJ, Rupley F, Miller JA, Technical Report SAND87-8215, Sandia National Laboratories (1991)
Miller JA, Bowman CT, Prog. Energy Combust. Sci., 15, 287 (1989)
Kilmer K, Vicente T, Ellis A, NIST standard reference database, Gaithersburg, MD (2007)
Diau EW, Lin MC, He Y, Melius CF, Prog. Energy Combust. Sci., 21(1), 1 (1995)
Tang W, Herron JT, J. Phys. Chem. Ref. Data, 20, 609 (1991)
Miller JA, Melilus CF, Symp. Int. Combust. Proc., 24, 719 (1992)
Cohen N, Westberg KR, J. Phys. Chem. Ref. Data, 20, 1211 (1991)
Nguyen HMT, Zhang SW, Peeters J, Truong TN, Nguyen MT, Chem. Phys. Lett., 388(1-3), 94 (2004)
Soto MR, Page M, J. Chem. Phys., 97, 7287 (1992)
