Articles & Issues
- Language
- English
- Conflict of Interest
- In relation to this article, we declare that there is no conflict of interest.
- Publication history
-
Received December 29, 2008
Accepted January 21, 2009
-
This is an Open-Access article distributed under the terms of the Creative Commons Attribution Non-Commercial License (http://creativecommons.org/licenses/bync/3.0) which permits
unrestricted non-commercial use, distribution, and reproduction in any medium, provided the original work is properly cited.
Copyright © KIChE. All rights reserved.
All issues
Solvent effect on particle morphology in recrystallization of HMX (cyclotetramethylenetetranitramine) using supercritical carbon dioxide as antisolvent
Department of Chemical Engineering, Hannam University, 461-6 Jeonmin-dong, Yuseong-gu, Daejeon 305-811, Korea 1School of Chemical and Biological Engineering, Seoul National University, San 56-1, Sillim-dong, Gwanak-gu, Seoul 151-742, Korea 2Agency for Defense Development, Jochiwongil 462, Yuseong-gu, Daejeon 305-152, Korea
bclee@hnu.kr
Korean Journal of Chemical Engineering, July 2009, 26(4), 1125-1129(5), 10.1007/s11814-009-0187-6
Download PDF
Abstract
Supercritical fluid processes have gained great attention as a new and environmentally benign method of preparing the microparticles of energetic materials like explosives and propellants. In this work, HMX (cyclotetramethylenetetranitramine) was selected as a target explosive. The microparticle formation of HMX using supercritical antisolvent (SAS) recrystallization process was performed and the effect of organic solvent on the size and morphology of prepared particles was observed. The organic solvents used in this work were dimethylsulfoxide (DMSO), N,N-dimethylformamide (DMF), cyclohexanone, acetone, and N-methyl pyrrolidone (NMP).
Keywords
References
Teipel U, PROPELLANT-EXPLOS-PYROTECH, 24(3), 134 (1999)
Teipel U, Mikonsaari I, Propellants, Explosives, Pyrotechnics, 27, 168 (2002)
Teipel U, Forter-Barth U, Gerber P, Krause HH, Propellants, Explosives, Pyrotechnics, 22, 165 (1997)
Pourmortazavi SM, Hajimirsadeghi SS, Ind. Eng. Chem. Res., 44(17), 6523 (2005)
Teipel U, Krober H, Krause HH, Propellants, Explosives, Pyrotechnics, 26, 168 (2001)
Beckman EJ, J. Supercrit. Fluids, 28(2-3), 121 (2004)
Teipel U, Forter-Barth U, Krause HH, PROPELLANT-EXPLOS-PYROTECH, 24(3), 195 (1999)
Lee S, Kim MS, Kim JS, Park HJ, Woo JS, Lee BC, Hwang SJ, J. Microencap., 23, 741 (2006)
Park CI, Shin MS, Kim H, Korean J. Chem. Eng., 25(3), 581 (2008)
Park SJ, Yeo SD, Korean J. Chem. Eng., 25(3), 575 (2008)
Kim MY, Yoo KP, Lim JS, Korean J. Chem. Eng., 24(5), 860 (2007)
Li G, Chu J, Song ES, Row KH, Lee KH, Lee YW, Korean J. Chem. Eng., 23(3), 482 (2006)
Stepanov V, Krasnoperov LN, Elkina IB, Zhang X, Propellants, Explosives, Pyrotechnics, 30, 178 (2005)
Thakur R, Gupta RB, Int. J. Pharm., 308, 190 (2006)
Achuthan CP, Jose CI, Propellants, Explosives, Pyrotechnics, 15, 271 (1990)
van der Heijden AEDM, Bouma RHB, Crystal Growth & Design, 4, 999 (2004)
Teipel U, Forter-Barth U, Krause HH, PROPELLANT-EXPLOS-PYROTECH, 24(3), 195 (1999)
Teipel U, Mikonsaari I, Propellants, Explosives, Pyrotechnics, 27, 168 (2002)
Teipel U, Forter-Barth U, Gerber P, Krause HH, Propellants, Explosives, Pyrotechnics, 22, 165 (1997)
Pourmortazavi SM, Hajimirsadeghi SS, Ind. Eng. Chem. Res., 44(17), 6523 (2005)
Teipel U, Krober H, Krause HH, Propellants, Explosives, Pyrotechnics, 26, 168 (2001)
Beckman EJ, J. Supercrit. Fluids, 28(2-3), 121 (2004)
Teipel U, Forter-Barth U, Krause HH, PROPELLANT-EXPLOS-PYROTECH, 24(3), 195 (1999)
Lee S, Kim MS, Kim JS, Park HJ, Woo JS, Lee BC, Hwang SJ, J. Microencap., 23, 741 (2006)
Park CI, Shin MS, Kim H, Korean J. Chem. Eng., 25(3), 581 (2008)
Park SJ, Yeo SD, Korean J. Chem. Eng., 25(3), 575 (2008)
Kim MY, Yoo KP, Lim JS, Korean J. Chem. Eng., 24(5), 860 (2007)
Li G, Chu J, Song ES, Row KH, Lee KH, Lee YW, Korean J. Chem. Eng., 23(3), 482 (2006)
Stepanov V, Krasnoperov LN, Elkina IB, Zhang X, Propellants, Explosives, Pyrotechnics, 30, 178 (2005)
Thakur R, Gupta RB, Int. J. Pharm., 308, 190 (2006)
Achuthan CP, Jose CI, Propellants, Explosives, Pyrotechnics, 15, 271 (1990)
van der Heijden AEDM, Bouma RHB, Crystal Growth & Design, 4, 999 (2004)
Teipel U, Forter-Barth U, Krause HH, PROPELLANT-EXPLOS-PYROTECH, 24(3), 195 (1999)
